The values of V areandN(2N + 3)/(2N + 1)(N + 1)(N + 1)(2N - l)/tf(2N + 1)for the transitions N, N+l and N, N-l respectively, where the magnetic dipole moment is2 Bohr magnetons [2: equation 7-6 in which the direction of the arrows indicate emission].The resonant frequencies of oxygen are given by»(N, J = N*-N, J = N ± 1) = K Q + fi 0/2 - 6^/2' + n + 2)+[(2n + 1)/B0 + 2B 1 (n 2 -f n6n3 + 13n 2 + lOn + 4) - f(n)whereI) 2 ,[f(n)] 2 = [(2n + 1){(B0 -+B9 (3n4 + 6n3 + 13n 2 + lOn + 4)} - l!tl* J 22n + 12 9 25n + 2)1 f2\n + 2x 1 (n^ + n + 1)]——————Jn = N + 1,and the parameters are given in the molecular constant table under reference number 1958.( The s's in the published expression for f(n) should be entered as 5 f s as above.)55
Oxygen 1.2074 1--©IsotopicMolecularSpecieso 2160»0 16 0 170 160 18ReferencesAv/pMe/mm2.00 a2.00 a2.00 a2.00 a*•M-Deb yeBOMe/sec43100.5 m48488.2 c44406.5 c45794.8 c1958wecm"115809900eqQMe/ sec2.70736BlMe/ sec-0.1.4701958B2Me/sec0±10"51958X 0Me/ sec59501.3321958x iMe/ sec0.05858a: Rough average of several experimental values. See material below on line width parameter.1958»J*Me/ sec-126.29301958IsotopicMolecularSpecieso^ 60»0 160"o 16 o 18u^/2Me/ sec-0.000117Magnetic hfs constantsMe/secb c-102 140^cos2 x-]y 2 r3) av10 24 cnT3-8.9(l/r 3)av10 25 em-34.45¥ 2(o)10 24 cm-31.26AdditionalMicrowaveReferences0172, 0273, 0293,0381,0385, 0409, 0422,0507,0539, 0545, 0650,0736,0752, 0972, 0973,1077,1078, 1120, 1144,1411,1499, 1713, 1744.References19580737073807380738Footnotes: Miscellaneous references on absorption coefficients, high pressure line widths, foreign gasbroadening and line shapes include: 0036, 0049, 0105, 0138, 0139, 0246, 0797, 1036, 1094,1511, 1682, and 1684.** Rough averages of discordant results, where g g , g|, g^, g^ are the splitting factors forthe free electron, the electron spin in the molecule, the molecular electronic orbital moment, and the molecular rotational moment, respectively.Two lines were observed in the range 60,170-60,180 Me/sec and theoretical computation gave60,172 and 60,179 for the respective lines.Frequency reported 60240-250 Me/sec, while theory gave 60250, 60251 for the respective lines.Line width parameter is a weighted average from 0500, 0797, and 1958.56
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Microwave Spectral TablesVolume I:
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