12.07.2015 Views

An Exercise in Freezing Point Depression

An Exercise in Freezing Point Depression

An Exercise in Freezing Point Depression

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B. The Corrosive Effects of Deicers on Concrete and Iron Surfaces Dur<strong>in</strong>g RepeatedFreeze - Thaw CyclesConcrete scal<strong>in</strong>g refers to damage done to concrete surfaces under various conditions. Theamount of scal<strong>in</strong>g is rated from 1 to 5, with 1 be<strong>in</strong>g no surface damage dur<strong>in</strong>g the studyand 5 be<strong>in</strong>g the most significant damage.Two sets of concrete samples were prepared <strong>in</strong> plastic conta<strong>in</strong>ers. One set consists ofconcrete <strong>in</strong> 1300 mL beakers. In the second set, the concrete samples were placed <strong>in</strong> 800mL conta<strong>in</strong>ers and a U – shaped iron bar was imbedded <strong>in</strong> the concrete. Each concretesample was covered with one of 9 different solutions and was then subjected to 10 freezethawcycles between about -17°C and room temperature. Because of the time required toprepare the concrete samples and to put them through a number of freeze – thaw cycles,the samples were prepared and treated outside of the regular laboratory and over aperiod of several weeks. The result<strong>in</strong>g concrete samples will be on display dur<strong>in</strong>g the twoweeks spent on Experiment 10.1. Exam<strong>in</strong>e the concrete samples which have no iron bars present, estimate theamount of scal<strong>in</strong>g on each sample and report the results, which will be subjective,on Data Sheet IIB.Do not touch the concrete surfaces!2. Also describe the extent of corrosion on the U – shaped bars on a scale of 1 to 5 andreport the results on Data Sheet IIB. Once aga<strong>in</strong> the results, while reported to thebest of your ability, are qualitative. For a given deicer, did the presence of the ironbar affect the amount of scal<strong>in</strong>g on the concrete surface?3. Look around campus and around town for places where rusty iron bars and flakedconcrete reveal damage to bridges, park<strong>in</strong>g ramps, roadways, etc. (H<strong>in</strong>t: A photoof serious rust or crumbl<strong>in</strong>g concrete, with the location noted, would be a goodaddition to your lab report or to a poster on deicers.10-8

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