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The 6th International Conference on Remediation - Environmental ...

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<str<strong>on</strong>g>The</str<strong>on</strong>g> <str<strong>on</strong>g>6th</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong>Remediati<strong>on</strong> of Chlorinated andRecalcitrant CompoundsKennedy Space CenterCenter Operati<strong>on</strong>s DirectorateRemediati<strong>on</strong> Costing and InterimMeasures Selecti<strong>on</strong> for NASA’sLaunch Complex 34May 19, 2008Michael Deliz, P.G.Jim Langenbach, P.E.


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateAcknowledgementsNASA LC34 Team:♦ Geosyntec (source characterizati<strong>on</strong>, modeling,technology evaluati<strong>on</strong>s)♦ Tetra-Tech NUS (Data management, dissolved plumeassessment/m<strong>on</strong>itoring, technology evaluati<strong>on</strong>s)♦ LFR (technology evaluati<strong>on</strong>s, previous pilot studytechnical evaluati<strong>on</strong>s)♦ GeoTrans (model review, technology c<strong>on</strong>siderati<strong>on</strong>s)Less<strong>on</strong> Learned – A Team of 8 Professi<strong>on</strong>al Engineersand 7 Geologists can make for some very looo<strong>on</strong>gc<strong>on</strong>ference callsJune 21, 2007 2


Kennedy Space CenterCenter Operati<strong>on</strong>s Directorate♦ Site History♦ Site-specific C<strong>on</strong>siderati<strong>on</strong>s‣ Locati<strong>on</strong>‣ Groundwater flowGoals / Overview‣ DNAPL distributi<strong>on</strong> and magnitude‣ Hydrogeologic setting‣ Remediati<strong>on</strong> reality♦ Technology Evaluati<strong>on</strong>s/Costing♦ Costing Evaluati<strong>on</strong> Ramificati<strong>on</strong>s♦ Path ForwardJune 21, 2007 3


Kennedy Space CenterCenter Operati<strong>on</strong>s Directorate


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateSite HistoryView From the Northeast1961 2003June 21, 2007 5


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateSite History♦ C<strong>on</strong>structed between 1959 and 1961 for the Saturn 1and 1B rocket program‣ Seven Saturn 1 and 1B launches from 1961-1968‣ Locati<strong>on</strong> of the Apollo 1 mishap♦ Extensive cleaning of spaceflight comp<strong>on</strong>ents withtrichloroethene (TCE)♦ Following the success of Apollo 7 launch structuresdismantled and buildings aband<strong>on</strong>ed in placeJune 21, 2007 6


Kennedy Space CenterCenter Operati<strong>on</strong>s Directorate♦ 1994RCRA Corrective Acti<strong>on</strong> History‣ Chlorinated solvent c<strong>on</strong>taminati<strong>on</strong> discovered in groundwater♦ 1996 - 2007‣ RCRA Facility Investigati<strong>on</strong> & Corrective Measures Study♦ Investigati<strong>on</strong> Results• ∼330 acres of groundwater negatively impacted by historic releasesof chlorinated solvents (1 mile by ½ mile plume)• Source area groundwater c<strong>on</strong>taminati<strong>on</strong> is present to 118 ft belowland surface (bls)• Sand aquifer with inter-bedded silt, clay, and shell layers (8 Layers)• DNAPL (TCE) present between 18 ft & 80 ft bls– Shallow Z<strong>on</strong>e 300 mg/kg)– Deep Z<strong>on</strong>e >45 ft bls = 33,000 lbs TCE (sat. soil > 300 mg/kg)– Additi<strong>on</strong>al 12,000 lbs of TCE mass in “shell” of soil surrounding DNAPL(TCE sat. soil c<strong>on</strong>centrati<strong>on</strong>s 100 - 300 mg/kg)June 21, 2007 7


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateDNAPL Source Z<strong>on</strong>eEVS solids model sourcez<strong>on</strong>e (>300 mg/kg) basedup<strong>on</strong> over 1,200 saturatedz<strong>on</strong>e soil samplesGeoSyntec 2005June 21, 2007 8


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateDNAPL Source Z<strong>on</strong>eJune 21, 2007 9


Radial Groundwater FlowLayer 1(“S” Interval)Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateLayer 2(“I” Interval)Layer 3(“D” Interval)Layer 6(“D1” Interval)


TCE Distributi<strong>on</strong>cDCE Distributi<strong>on</strong>INSERT A LEGEND OR PHOTOHEREVC Distributi<strong>on</strong>


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateCross Secti<strong>on</strong> SW to NE - TCEJune 21, 2007 12


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateCross Secti<strong>on</strong> SW to NE - cDCEJune 21, 2007 13


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateCross Secti<strong>on</strong> SW to NE - VCJune 21, 2007 14


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateCritical Points Regarding Site Impacts♦ No complete exposure pathway‣ Site located <strong>on</strong> a barrier island‣ Highly unlikely source of future potable groundwater‣ No surface water present within plume footprint‣ Engineering Support Building removed (slab left behind)♦ Radial groundwater flow from source area♦ Significant mass, ~100,000 lbs♦ Large variati<strong>on</strong>s in hydraulic c<strong>on</strong>ductivity (1x10 -3 cm/secto 1x10 -8 cm/sec♦ DNAPL extending to 80 ft bls♦ 40+ yr old releaseJune 21, 2007 15


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateCritical Points Regarding Site Impacts♦ DNAPL source area encompasses ~2 acres (norecoverable product present)♦ Dissolved groundwater plume of ~330 acres♦ Groundwater modeling results‣ No Acti<strong>on</strong> – >900 yrs to reach MCLs‣ 85% DNAPL Source Removal and Dissolved Plume HydraulicC<strong>on</strong>trol – 750 yrs to reach MCLs‣ 99% DNAPL Source Removal (feasible?) and Dissolved PlumeHydraulic C<strong>on</strong>trol – 250 yrs to reach MCLs♦ So how much do you spend to reduce the cleanuptimeframe from “very l<strong>on</strong>g” to “l<strong>on</strong>g” <strong>on</strong> a barrier islandwith no exposure pathway?June 21, 2007 16


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateTechnology Screening♦ Divided site into three areas‣ DNAPL Source Z<strong>on</strong>e (DSZ)‣ High C<strong>on</strong>centrati<strong>on</strong> Plume‣ Low C<strong>on</strong>centrati<strong>on</strong> Plume♦ Aquifer was split vertically based up<strong>on</strong> technologylimitati<strong>on</strong>s and lithology (


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateTreatment Z<strong>on</strong>esDNAPL SourceZ<strong>on</strong>eHighC<strong>on</strong>centrati<strong>on</strong>PlumeLowC<strong>on</strong>centrati<strong>on</strong>PlumeJune 21, 2007 18


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateRetained Technologies♦ DNAPL Source Z<strong>on</strong>e‣ Hydraulic c<strong>on</strong>tainment via P&T to 85 ft bls‣ Permeable Reactive Barrier to 85 ft bls‣ Enhanced Bioremediati<strong>on</strong> to 85 ft bls‣ Excavati<strong>on</strong> to 55 ft bls/Enhanced Bioremediati<strong>on</strong> 55-85 ft bls‣ Large Diameter Auger (LDA)/Steam/Ir<strong>on</strong> to 55 ft bls/ EnhancedBioremediati<strong>on</strong> to 85 ft bls‣ ZVI Clay or Slurry Wall Barrier to 85 ft bls** barrier technologies evaluated independent from CMSJune 21, 2007 19


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateCosting♦ CMS and/or FS costs are typically presented as +50% to -30% andNPV is utilized‣ LC34 costs were based up<strong>on</strong> vendor quotes and/or best practicalengineering estimates♦ Net Present Value (NPV)‣ Required approach for presenting costing pursuant to NASA‟s HSWApermit‣ Issue with NPV – not c<strong>on</strong>sistent with NASA funding approach• Implies full upfr<strong>on</strong>t cleanup funding• NASA funds projects annually, therefore NPV can underestimate actual costs♦ N<strong>on</strong>-Discounted “Pay As you Go” Dollars‣ May be more representative of the actual cost to implement a cleanup‣ Important in projects with <strong>on</strong>going O&M&MJune 21, 2007 20


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateCorrective Measures Study CostsTreatment Z<strong>on</strong>es and AlternativesFirst Year Cost(Capital Cost + FirstYear O&M&M Cost)Total Cost(First Year Cost + TotalN<strong>on</strong>-Discounted O&M&M)Total NPV(First Year Cost +Total O&M&M NPV)DNAPL Source Z<strong>on</strong>ePump and Treat $1M $100M $4MPermeable Reactive Barrier $12M $60M $15MEnhanced Bioremediati<strong>on</strong> $5M $45M $10MC<strong>on</strong>venti<strong>on</strong>al Excavati<strong>on</strong> to 55feet bls,Enhanced Bioremediati<strong>on</strong>55-85 feet bls.LDA/Steam/Ir<strong>on</strong> to 55 feet bls,Enhanced Bioremediati<strong>on</strong>55-85 feet blsZVI Clay or Slurry Wall Barrierto 85 ft bls (C<strong>on</strong>tainment - NoTreatment Provided)$40 - $50M $54M $42 - $50M$50 - $70M $100M $55 – 75$M$5 - $6M $5 - $7M (based up<strong>on</strong> 30 yrs)$5 - $6M (based up<strong>on</strong> 30yrs)June 21, 2007 21


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateTechnology C<strong>on</strong>siderati<strong>on</strong>s♦ Technologies such as PRB and/or Barrier Wall do not provide significantDSZ treatment‣ Primary objective is to c<strong>on</strong>trol flux from DSZ‣ Would likely require adding a technology that provides source treatment♦ Highly aggressive technologies provide for significant DSZ mass reducti<strong>on</strong>- however:‣ Even 95% DSZ mass removal leaves 1,000‟s of pounds of mass in place‣ Time to MCLs still significant (centuries)‣ Follow-up technology to provide remaining mass flux c<strong>on</strong>trol likely required♦ Hydraulic c<strong>on</strong>tainment via P&T offers advantage of flux c<strong>on</strong>trol (primaryobjective) and mass removal (sec<strong>on</strong>dary benefit) over time♦ Hydraulic c<strong>on</strong>tainment via P&T represents an active site managementstrategy that provides NASA with risk management at a low capital andannual cost‣ System is not envisi<strong>on</strong>ed to operate for 100‟s of yrs as a final DSZ remedy‣ Technology can be potentially enhanced as a comp<strong>on</strong>ent of a final remedy (nextstep in the „treatment train”)June 21, 2007 22


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateP&T Technology C<strong>on</strong>siderati<strong>on</strong>s♦ Typically not c<strong>on</strong>sidered suitable for achieving MCLs at DNAPL sites‣ At LC34 no technology will rapidly achieve MCLs (100% mass removal)‣ Represents an interim measure which can be supplemented in the future:• bio-recirculati<strong>on</strong>, surfactants, oxidants, etc.• “treatment train” approach♦ C<strong>on</strong>sidered an expensive technology due to <strong>on</strong>going annual O&M&M costs‣ Lowest capital costs and NPV costs (though not realistic)‣ Highest overall “pay as you go” costs‣ Annual O&M&M costs that are manageable♦ Not c<strong>on</strong>sidered a sustainable technology‣ NASA is evaluating providing 100% of energy requirements via solar/windturbines‣ Electrical demand is not excessive (12 to 15 hp) compared to overall energyrequirements of other aggressive technologiesJune 21, 2007 23


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateTechnology C<strong>on</strong>siderati<strong>on</strong>s♦ How much P&T does $6 milli<strong>on</strong> buy at LC34?‣ P&T/GAC @ 25,000 µg/L VOC influent: 42 yrs‣ P&T/GAC @ 50,000 µg/L VOC influent: 37 yrs‣ P&T/GAC @ 100,000 µg/L VOC influent: 26 yrs‣ Advanced Oxidati<strong>on</strong> Systems: 28 - 32 yrs♦ As influent c<strong>on</strong>centrati<strong>on</strong>s decline, O&M costs drop (offsettinginflati<strong>on</strong> <strong>on</strong> annual O&M),♦ At an influent c<strong>on</strong>centrati<strong>on</strong> $40,000‣ significant savings benefit not factored into P&T analysisJune 21, 2007 24


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateCorrective Measures Study Costs♦ P&T to provide hydraulic c<strong>on</strong>tainment‣ Primary objective is hydraulic c<strong>on</strong>tainment of DSZ‣ A byproduct of c<strong>on</strong>tainment will be significant mass removal (t<strong>on</strong>s peryr)‣ Not anticipated as a m♦ Hydraulic c<strong>on</strong>tainment represents an active site managementstrategy that provides risk management at a low capital and annualcost‣ System is not envisi<strong>on</strong>ed to operate for 100‟s of yrs as a final DSZremedy‣ Technology can be potentially enhanced as a comp<strong>on</strong>ent of a finalremedy (next step in the treatment train)♦ DNAPL will c<strong>on</strong>tinue to “fuel” dissolved plume until source is depleJune 21, 2007 25


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateSelected Remedy♦ System eliminates flux & can remove significant mass♦ Allows time for new technologies to be developed♦ Cost‣ Capital cost for implementati<strong>on</strong> of the DNAPL Source Z<strong>on</strong>eremedy will be ∼$1M with annual O M & M costs of $150K• O M & M costs will be required for multiple decades and/orcenturies‣ Total CMS cost for the selected remedy for all three treatmentz<strong>on</strong>es is $339M• Total does not include the supplemental assessments andgroundwater “Hot Spot” treatments that are included in theproposed remedy for the High C<strong>on</strong>centrati<strong>on</strong> Plume• Additi<strong>on</strong>al “Hot Spot” treatment will reduce the time required for theentire plume to reach required cleanup levelsJune 21, 2007 26


Kennedy Space CenterCenter Operati<strong>on</strong>s DirectorateQuesti<strong>on</strong>sJune 21, 2007 27

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