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Mid Infrared Focal Plane Arrays with Nanoscale Quantum Dots and ...

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<strong>Mid</strong> <strong>Infrared</strong> <strong>Focal</strong> <strong>Plane</strong> <strong>Arrays</strong> With <strong>Nanoscale</strong><strong>Quantum</strong> <strong>Dots</strong> <strong>and</strong> SuperlatticesS. KrishnaCenter for High Technology Materials, Department ofElectrical <strong>and</strong> Computer EngineeringUniversity of New Mexico,1313 Goddard SE, Albuquerque NM 87106Email: skrishna@chtm.unm.eduif desiredAbstract—Keywords- Molecular beam epitaxy, <strong>Nanoscale</strong>, <strong>Quantum</strong> <strong>Dots</strong>Superlattices, Antimonides, <strong>Mid</strong>-infrared photodetector.I. INTRODUCTIONPresently, the state of the art photon detectors for the mid waveinfrared (MWIR, 3-5 µm) <strong>and</strong> long wave infrared (LWIR, 8-12µm) are based on interb<strong>and</strong> transitions in bulk IndiumAntimonide (InSb) <strong>and</strong> Hg 1-x Cd x Te (MCT) alloys respectively.Two emerging technologies for next generation sensors thatoffer enhanced functionality include (i) intersubb<strong>and</strong> detectorsbased on nanoscale quantum dots <strong>and</strong> (ii) interb<strong>and</strong> transitionsin the Type II InAs/GaSb strain layer superlattice system.<strong>Infrared</strong> detectors based on InAs/GaSb strain layer superlattices(SLSs) were proposed by Smith <strong>and</strong> Mailhiot [1] in 1980s <strong>and</strong>appear as a promising alternative to the present-day infra-red(IR) detection technologies. SLSs offer numerous advantagesover existing detector technologies, including better uniformity,reduced tunneling currents, normal incidence absorption <strong>and</strong>suppressed Auger recombination. SLSs are characterized by thebroken-gap type-II alignment. Presently all SLSs detectors arebased on a photodiode (p-i-n or n-i-p) design. During theconventional fabrication process of photodiodes, the deep etchthrough the absorbing region is utilized in order to define theoptical area of the detector. Electronic surface states <strong>with</strong>in theenergy b<strong>and</strong> gap of SLS are generated, resulting in large surfaceleakage currents. The suppression of these currents is the mostdem<strong>and</strong>ing challenge for the SLS technology. A recentlyproposed nBn heterostructure design [2] implemented on SLSbaseddetectors showed a dark current reduction of two ordersof magnitude (at 77K) in comparison <strong>with</strong> conventionallyprosessed photodiodes [3]. We have recently fabricated a highperformance InAs/GaSb SLS detector <strong>with</strong> a P on N polarity<strong>and</strong> a 320x 256 MWIR FPA <strong>with</strong> a noise equivalent temperaturedifference of 24 mK at 77K based on this structure [4}In the quantum dots in a well (DWELL) heterostructure, InAsquantum dots are placed in a thin InGaAs quantum well that isin turn placed in a GaAs matrix. Three-color DWELL detectors,operating at 78K, <strong>with</strong> spectral response in the MWIR ( p1 ~ 4), LWIR ( p2 ~ 8 ) <strong>and</strong> VLWIR ( p3 ~ 23 ) regime havebeen fabricated in our group. Recently, we have fabricated thefirst long wave infrared <strong>and</strong> two-color quantum dot focal planearray (320x256 pixels).II.EXPERIMENTAL PROCEDUREThe SLS devices presented in this work were grown usingsolid source MBE on Te-doped epi-ready (100) GaSbsubstrates. The detector structure consists of an unintentionallydoped (n.i.d.) thick SLS absorber layer which isgrown on the top of n-type bottom contact layer <strong>and</strong> followedby the barrier layer. The structure is capped by a top contactlayer <strong>with</strong> the same superlattice composition, thickness, <strong>and</strong>doping concentration as the bottom contact layer. The samplewas processed into FPAs <strong>with</strong> each die consisting of 320 x 256pixels <strong>with</strong> a 30 m pitch using st<strong>and</strong>ard photolithographytechniques. Unlike conventional photodiode processing, thesize of the device <strong>with</strong> nBn design is not defined by the etchdimensions but rather by the lateral diffusion length of minoritycarriers (holes).III. RESULTS AND DISCUSSIONThe measured FPA average dark current density was as 1 x10 -7 A/cm2 (V b =0.7V). This value is comparable to the stateof-the-artreports for MWIR SLS detectors based on aconventional photodiode design <strong>with</strong> a suitable passivationscheme. The noise equivalent temperature difference (NETD)was equal to 23.8 mK <strong>with</strong> a st<strong>and</strong>ard deviation of 10 mK at aFPA temperature of 77K. The external QE was obtained usingthe spectral response curve from the test diode on the FPA chip<strong>with</strong> 380mm x 380mm optical area. Spectral measurementswere performed using a Fourier Transform <strong>Infrared</strong>Spectrometer (FTIR). Values of specific detectivity, QE <strong>and</strong>responsivity as a function of wavelength are presented inFigure 1. Peak values of QE, responsivity <strong>and</strong> specificdetectivity were equal to 52%, 1.6 A/W, <strong>and</strong> 6.7 x 1011 Jones,respectively (77K, V b =0.7V, 3.8 mm). A thermal image taken<strong>with</strong> 320 x 256 MWIR FPA at a detector temperature of 77 K<strong>and</strong> integration time of 16.3 ms is shown in Figure 2.978-1-4244-2104-6/08/$25.00 ©2008 IEEE. 42


Figure 3. Images taken <strong>with</strong> a long wave infrared quantum dots in a wellfocal plane array (320x256).Figure 1. Spectral detectivity D*, responsivity <strong>and</strong> quantum efficiency for4.2 µm cut-off wavelength FPAACKNOWLEDGMENTWork supported by NSF, AFRL, AFOSR <strong>and</strong> DARPA.REFERENCESFigure 2. Thermal image taken <strong>with</strong> a MWIR 320x256 InAs/GaSb SLs nBncamera at a detector temperature of 77 K <strong>and</strong> integration time of 16.3 ms.<strong>Focal</strong> plane arrays were also made using nanoscalequantum dots using a similar procedure. Imaging obtainedfrom these arrays in the long wave infrared region are shown inFig. 3.[1] D.L. Smith <strong>and</strong> C. Mailhiot, J. Appl. Phys., vol. 62, 2545-2549 (1987).[2] S. Maimon <strong>and</strong> G. W. Wicks, Appl. Phys. Lett., vol. 89, 151109-15111(2006)[3] J.B. Rodriguez, E. Plis, G. Bishop, Y.D. Sharma, H. Kim, L.R. Dawson<strong>and</strong> S. Krishna, Appl. Phys. Lett., vol. 91, 043514-043516 (2007).[4] H. S. Kim, E. Plis, J. B. Rodriguez, G. D. Bishop, Y. D. Sharma, L. R.Dawson, S. Krishna, J. Bundas, R. Cook, D. Burrows, R. Dennis, K.Patnaude, A. Reisinger, <strong>and</strong> M. Sundaram, Appl. Phys. Lett. 92, 183502(2008)43

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