Nukleinsavak - Szerves Kémiai Tanszék
Nukleinsavak - Szerves Kémiai Tanszék
Nukleinsavak - Szerves Kémiai Tanszék
SHOW LESS
- No tags were found...
You also want an ePaper? Increase the reach of your titles
YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.
Oligo(poli)nukleotidkonformációConformationalfreedom is heavilyrestricted in nucleicacids owing to lack offree rotation aboutO3-P and P-O5 bonds.Free rotation isprimarily dampedowing to the gaucheeffect in which lonepair-σ* orbitaloverlaps inphosphodiester links togenerate double bondcharacter in O-Pbonds that restrict freerotation.OOs* P-O n O3'3'O OO O5'5'OP PO OOO Os* P-On Oa nemkötõ elektronpár helyzetea síkban van a sík elé mutat a sík mögé mutat
Change language