CHEM<strong>360</strong> Report Book 2012-14IntroductionAcknowledgements:The authors wish to especially thank Ms. Aimee Caouette for all the artwork. <strong>Athabasca</strong> <strong>University</strong> alsowishes to thank Drs. K. Tanabe and T. Tamura and for their permission to use the IR and 1H-NMR Spectra used in ourlab manual and report book (pp. 15, 35, 46, 60, and 73). They were obtained from the SDBS web site:http://www.aist.go.jp/RIODB/SDBS/.Each experiment in CHEM<strong>360</strong> has been modified and rewritten from other sources, keeping the particularneeds of <strong>Athabasca</strong> <strong>University</strong> students in mind. The format of this Report Book have been checked in our <strong>Athabasca</strong>laboratories by Dr. Lawton Shaw, Klaus Thomson, Nyron Jaleel, and Robert Carmichael. Special thanks to Ms. AimeeCaouette for her help on the Infrared Tutorial (Summer 1999). Also thanks to Mr. Douglas Woudstra and Mr. JamesTaylor (CHEM<strong>360</strong> students 2004-05) for their helpful suggestions to improve the report book. The comments andsuggestions received from all the individuals mentioned above were greatly appreciated by the Course Co-ordinator.The following sources are also hereby acknowledged:L.M. Browne, 2005. Laboratory Report Book, <strong>Chemistry</strong> 161, <strong>University</strong> of Alberta.L.M. Browne, 2005. Laboratory Report Book, <strong>Chemistry</strong> 163, <strong>University</strong> of Alberta.Lehman, J.W. 1999. Operation Organic <strong>Chemistry</strong>: A Problem-Solving Approach to the Laboratory Course, 3 rd ed.,Prentice Hall, New Jersey.Mayo, D.W., R.M. Pike, and S.S. Butcher. 1989. Microscale Organic Laboratory, 2nd ed., John Wiley and Sons,Toronto, pp.229-232.McMurry, J., 1992. Organic <strong>Chemistry</strong>, 3 rd ed., Brooks/Cole Publishing Company, Pacific Grove, CA.Weast, R.C. et al, 1974. CRC Handbook of <strong>Chemistry</strong> and Physics, 65 th ed., CRC Press, Inc., Boca Raton, FL.4
CHEM<strong>360</strong> Report Book 2012-14Exp.10CHEM<strong>360</strong> Experiment 10 ReportStudent Name:___________________Date:___________ID Number:___________Experiment 10 Prelab Questions:Lab Safety1. What are the hazards of working with concentrated acids like glacial acetic acid and sulfuric acid?a) They are both extremely flammableb) They are only mildly corrosive and no significant precautions are neededc) Boiling these highly corrosive acids increases the danger to the experimenter, especially if thereaction flask should crack and break during heatingEquipment Preparation2. Why must the condenser be ‘clean and dry’ prior to use?a) Clean and dry glassware automatically guarantees a higher yieldb) Water is a by-product of the reaction and having ‘wet glassware’ will slow the reaction downc) Chemists are just neat3. The following diagram for the ‘reflux apparatus’ used in Experiment 10 is correctly labelled.a) Trueb) false5