Volume 4 - Loctite.ph

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Polybutylene Terephthalate (PBT)ThermoplasticTrade Names Manufacturer• ArniteDSM Engineering• CelanexHoescht Celanese• MinlonE.I. DuPont• PocanAlbis Corporation• TorayToray Industries• UltradurBASF• ValoxGeneral Electric• VybexFerro CorporationTypical Properties of Polybutylene Terephthalate (PBT)American EngineeringSIProcessing Temperature 400°F to 500°F 204°C to 274°CLinear Mold Shrinkage 0.001 to 0.004 in./in. 0.001 to 0.004 cm/cmMelting Point 430°F to 433°F 221°C to 223°CDensity 62.4 to 81.2 lb./ft. 3 1.00 to 1.30 g/cm 3Tensile Strength, Yield 4.6 to 7.9 lb./in. 2 x 10 3 3.2 to 5.6 kg/cm 2 x 10 2General DescriptionPolybutylene terephthalate (PBT) is a crystalline thermoplasticpolyester formed by the catalyzed melt polycondensation of dimethylterephthalate and 1,4-butanediol. The resulting polymer is known forits good mechanical properties, low moisture absorption, and chemicalresistance. Specialty grades available include glass filled, mineralfilled, impact resistant, and flame retardant grades. In 2004, the priceof PBT ranged approximately from $2.60 to $4.00 per pound attruckload quantities.General PropertiesThe most notable properties of PBT are its chemical resistance andmechanical properties. PBT offers good resistance to water, weakacids and bases, ketones, alcohols, glycols, ethers, aliphatic hydrocarbons,and chlorinated aliphatic hydrocarbons at room temperature.At temperatures up to 140°F (60°C), PBT is resistant to transmissionfluid, brake fluid, gasoline, and motor oil. It is not recommended foruse in strong bases at any temperature, or in aqueous mediums attemperatures above 125°F (52°C). PBT has good tensile strength, highdimensional stability, and a lubricity which makes it very resistant towear. It has a relatively low heat deflection temperature, but glassfilled grades can increase this to over 400°F (204°C). Due to theextremely low water absorption of PBT (0.05% to 0.15%), itsdimensional stability and electrical properties are unaffected by highhumidity conditions. It has a volume resistivity independent oftemperature that exceeds 1016 ohm-cm. In medical applications, PBTis suitable for sterilization with ethylene oxide, but does not haveenough heat resistance to be steam sterilized.Tensile Strength, Break 4.0 to 12.0 lb./in. 2 x 10 3 2.8 to 8.4 kg/cm 2 x 10 2Elongation, Break 1.0 to 50.0% 1.0 to 50.0%Tensile Modulus 2.0 to 12.0 lb./in. 2 x 10 5 1.4 to 8.4 kg/cm 2 x 10 4Flexural Strength, Yield 6.2 to 20.0 lb./in. 2 x 10 3 4.4 to 14.1 kg/cm 2 x 10 2Flexural Modulus 2.5 to 4.4 lb./in. 2 x 10 5 1.8 to 3.1 kg/cm 2 x 10 4Compressive Strength 6.5 to 17.0 lb./in. 2 x 10 3 4.6 to 12.0 kg/cm 2 x 10 2Izod Notched, R.T. 0.5 to 12.0 ft.-lb./in. 2.7 to 64.8 kg cm/cmHardness R95 - R125 Rockwell R95 - R125 RockwellThermal Conductivity 1.2 to 1.6 BTU-in./hr.-ft. 2 -°F 0.17 to 0.23 W/m-°KLinear ThermalExpansionDeflection Temperature@ 264 psiDeflection Temperature@ 66 psiContinuousService Temperature1.1 to 5.7 in./in.-°F x 10 -5 2.0 to 10.3 cm/cm-°C x10 -5170°F to 240°F 77°C to 116°C190°F to 245°F 88°C to 118°C130°F to 180°F 54°C to 82°CDielectric Strength 350 to 500 V/10 -3 in. 1.4 to 2.0 V/mm x 10 4Dielectric Constant@ 1 MHzDissipation Factor@ 1 MHzWater Absorption,24 hr.3.1 to 3.4 3.1 to 3.40.019 to 0.030 0.019 to 0.0300.03 to 0.50% 0.03 to 0.50%Typical Applications• Automotive – Brake system parts, distributor caps,fuel injection modules, grille opening panels• Electronics – Connectors, switches, relays, TV tuners,motor housings, fuse cases, light sockets• Medical – Specialty syringes, irrigation and wound drainagesystems, check valves, catheter housings• Miscellaneous – Industrial zippers, power tool housings,hair dryers, calculators, cooker-fryer handles, iron and toasterhousings, food processor blades38The Loctite ® Design Guide for Bonding Plastics, Volume 4
ADHESIVE SHEAR STRENGTH(psi)(MPa)Polybutylene TerephthalateUNFILLED RESINGRADE 3254 rmsGRADE 325ROUGHENED60 rmsGRADE DR5115% Glass ReinforcedGRADE 42030% Glass ReinforcedGRADE 50830% GlassReinforced AlloyGRADE 732E30% Glass/MineralReinforcedGRADE 73540% Glass/MineralReinforcedGRADE 83030% GlassReinforced AlloyGRADE 85015% Glass ReinforcedPBT AlloyValox courtesy of GE PlasticsLoctite ® 380 Black Max ® Instant Adhesive,Rubber ToughenedLoctite ® 401 Prism ® Instant Adhesive,Surface InsensitiveMEDICAL: Loctite ® 4011 Prism ®Instant Adhesive, Surface InsensitiveLoctite ® 401 Prism ®Loctite ® 770 Prism ® PrimerMEDICAL: Loctite ® 4011 Prism ® /Loctite ® 7701 Prism ® PrimerLoctite ® 414 Super Bonder ®Instant Adhesive, General PurposeLoctite ® 330 Depend ® Adhesive,Two-Part No-Mix AcrylicLoctite ® 3105 Light Cure Adhesive,MEDICAL: Loctite ® 3311 Light Cure AdhesiveLoctite ® 3340 Light Cure Adhesive,UV Cationic EpoxyLoctite ® 4305 Flashcure ® Light Cure AdhesiveFLUORESCENT: Loctite ® 4307 Flashcure ®Light Cure AdhesiveLoctite ® H3000 Speedbonder Structural Adhesive, General PurposeLoctite ® H4500 Speedbonder Structural Adhesive, Metal BonderLoctite ® 3030 Adhesive, Polyolefin BonderLoctite ® E-00CL Hysol ® Epoxy Adhesive,Low OdorLoctite ® E-90FL Hysol ® Epoxy Adhesive,FlexibleLoctite ® E-30CL Hysol ® Epoxy Adhesive,Glass BonderMEDICAL: Loctite ® M-31CL Hysol ®Epoxy Adhesive, Glass BonderLoctite ® E-20HP Hysol ® Epoxy Adhesive,Fast SettingMEDICAL: Loctite ® M-21HP Hysol ®Epoxy Adhesive, Fast SettingLoctite ® E-214HP Hysol ® Epoxy Adhesive,High StrengthLoctite ® Fixmaster ® High Performance EpoxyLoctite ® 1942 Hysol ® Hot Melt Adhesive,EVA BasedLoctite ® 3651 Hysol ® Hot Melt Adhesive,PolyolefinLoctite ® 7804 Hysol ® Hot Melt AdhesiveLoctite ® 3631 Hysol ® Hot Melt Adhesive,UrethaneLoctite ® U-05FL Hysol ® Urethane Adhesive,High StrengthLoctite ® Fixmaster ® Rapid Rubber RepairOEM: Loctite ® U-04FL Hysol ®Urethane Adhesive, Fast SettingLoctite ® 5900 ® Flange Sealant,Heavy Body RTV Silicone1000.72501.75003.59506.6>3150 1450>21.9 10.02501.71000.72001.43502.43502.43502.46504.511007.65503.55003.57004.85503.8150010.45003.42501.71501.01501.014009.710006.98005.52001.4215014.82001.46004.11000.74002.8420029.04503.11000.72001.42001.43002.14503.1210014.5>4150 3350>28.6 23.15503.81501.06004.1180012.4165011.412508.69506.69006.21501.0>2650 >2600 600>18.3 >17.9 4.12001.44002.8>2900 >2800 >4050 >4400 >20.0 >19.3 >27.9 >30.3 >2200 >2650 350>15.2 >18.3 2.49506.6175012.13502.47505.21501.05503.811007.61501.07004.8Adhesive PerformanceLoctite ® 401 Prism ® Instant Adhesive used in conjunction with Loctite ® 770 Prism ® Primer, achieved thehighest bond strengths on all the grades of PBT which were evaluated. Typically, Loctite ® 401 Prism ® and414 Super Bonder ® Instant Adhesives, Loctite ® 3030 Adhesive, Loctite ® E-214HP Hysol ® EpoxyAdhesive, Loctite ® U-05FL Hysol ® Urethane Adhesive, and Loctite ® 3631 Hysol ® Hot Melt Adhesiveachieved the highest bond strengths, followed by Loctite ® H4500 Speedbonder Structural Adhesive,Loctite ® E-00CL , E-90FL and E-30CL Hysol ® Epoxy Adhesives, and Loctite ® Fixmaster ® HighPerformance Epoxy and Rapid Rubber Repair. Loctite ® 380 Black Max ® Instant Adhesive and Loctite ®330 Depend ® Adhesive achieved the lowest bond strengths on PBT.Surface TreatmentsSurface roughening, plasma treatment, UV-ozone treatment, and the use of Loctite ® 770 or 7701 Prism ®Primers have all proven to cause large, statistically significant increases in the bondability of PBT.Other Important Information• Good solvents for PBT are hexafluoroisopropanol, trifluoroacetic acid, o-chlorophenol,and mixtures of phenol with chlorinated aliphatic hydrocarbons.• PBT is compatible with all Loctite ® brand adhesives, sealants, primers, and activators.• Surface cleaners: isopropyl alcohol, Loctite ® ODC-Free Cleaner & Degreaser.NOTES: The force applied to the tests specimens exceededthe strength of the material resulting in substrate failurebefore the actual bond strength achieved by the adhesivecould be determined.The addition of the indicated additive (or surfaceroughening) caused a statistically significant decrease inthe bond strength within 95% confidence limits.The addition of the indicated additive (or surfaceroughening) caused a statistically significant increase inthe bond strength within 95% confidence limits.The Loctite ® Design Guide for Bonding Plastics, Volume 4 39
Page 3: Table of ContentsIntroduction 2How
Page 6 and 7: How To Use The Plastic Bonding Guid
Page 8 and 9: Cyanoacrylate AdhesivesGeneral Desc
Page 10 and 11: Hot Melt AdhesivesGeneral Descripti
Page 12 and 13: Polyurethane AdhesivesGeneral Descr
Page 14 and 15: No-Mix and Static Mix Acrylic Adhes
Page 16: Acetal HomopolymerThermoplasticTrad
Page 20: Acrylic-Styrene-Acrylonitrile (ASA)
Page 23 and 24: ADHESIVE SHEAR STRENGTH(psi)(MPa)Ac
Page 25 and 26: ADHESIVE SHEAR STRENGTH(psi)(MPa)Di
Page 27 and 28: ADHESIVE SHEAR STRENGTH(psi)(MPa)Ce
Page 29 and 30: ADHESIVE SHEAR STRENGTH(psi)(MPa)Ep
Page 31 and 32: ADHESIVE SHEAR STRENGTH(psi)(MPa)Po
Page 33 and 34: ADHESIVE SHEAR STRENGTH(psi)(MPa)Io
Page 35 and 36: ADHESIVE SHEAR STRENGTH(psi)(MPa)Li
Page 37 and 38: ADHESIVE SHEAR STRENGTH(psi)(MPa)Ph
Page 39: ADHESIVE SHEAR STRENGTH(psi)(MPa)Po
Page 53 and 54: ADHESIVE SHEAR STRENGTH(psi)(MPa)Lo
Page 73 and 74: ADHESIVE SHEAR STRENGTH(psi)(MPa)St
Page 75 and 76: ADHESIVE SHEAR STRENGTH(psi)(MPa)Vi
Page 77 and 78: Surface TreatmentsAdhesive Abrading
Page 79 and 80: Adhesive Joint DesignIntroductionIn
Page 81 and 82: TitleDesign GuidelinesEngineers mus
Page 83 and 84: Shortening bond overlaps reduces bo
Page 85 and 86: Softening and weakening of the surf
Page 87 and 88: Determining The Test MethodThe lap
Page 89 and 90: Block Shear Test Method1. Assemblie
Page 91 and 92:
ViscosityViscosity is a product pro
Page 93 and 94:
Index of Trade NamesTrade Name Plas
Page 95 and 96:
Trade Name Plastic Type Manufacture
Page 97 and 98:
AcknowledgmentsThis manual would no
Page 99:
For more information, please call 1
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