HigH Voltage Pulsed generators - Physical Instruments
HigH Voltage Pulsed generators - Physical Instruments
HigH Voltage Pulsed generators - Physical Instruments
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Ion induced stress relaxation in cBN<br />
by pulsed ion implantation<br />
Pulse schema of BIAS for quasi stress free cBN coating<br />
RF magnetron sputter equipment with complex BIAS for cBN<br />
deposition<br />
The deposition of cubic boron nitride films as a super<br />
hard coating is very limited by the formation<br />
of extreme high intrinsic stress and the resulting<br />
delamination of the coating from the substrate at<br />
film thicknesses lower 100nm. This high compressive<br />
stress is caused by the low energy (< several<br />
hundreds eV) recoil implantation of film forming<br />
species nitrogen and boron, by densification and<br />
by defect production in the growing films.<br />
At biased rf magnetron sputter processes stress of<br />
more than 10GPa was measured. Under simultaneously<br />
application of a second ion energy (higher<br />
than several keV) it was obtained a 90% stress relaxation<br />
of the growing film by atomic displacements<br />
under the surface. A complex pulsed bias of<br />
the cBN growth with pulse voltages of<br />
� For cBN growth: -100 to -180 V<br />
� For stress relaxation: -2.5 to -8 kV<br />
� For Surface discharge: +80V<br />
(see pulse schema) enables a poor stress growth<br />
process for µm thick cBN hard coatings.<br />
(Forschungszentrum Dresden Rossendorf applied RUP3-10B)<br />
RF plasma of N2/Ar for cBN deposition