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HigH Voltage Pulsed generators - Physical Instruments

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Ion induced stress relaxation in cBN<br />

by pulsed ion implantation<br />

Pulse schema of BIAS for quasi stress free cBN coating<br />

RF magnetron sputter equipment with complex BIAS for cBN<br />

deposition<br />

The deposition of cubic boron nitride films as a super<br />

hard coating is very limited by the formation<br />

of extreme high intrinsic stress and the resulting<br />

delamination of the coating from the substrate at<br />

film thicknesses lower 100nm. This high compressive<br />

stress is caused by the low energy (< several<br />

hundreds eV) recoil implantation of film forming<br />

species nitrogen and boron, by densification and<br />

by defect production in the growing films.<br />

At biased rf magnetron sputter processes stress of<br />

more than 10GPa was measured. Under simultaneously<br />

application of a second ion energy (higher<br />

than several keV) it was obtained a 90% stress relaxation<br />

of the growing film by atomic displacements<br />

under the surface. A complex pulsed bias of<br />

the cBN growth with pulse voltages of<br />

� For cBN growth: -100 to -180 V<br />

� For stress relaxation: -2.5 to -8 kV<br />

� For Surface discharge: +80V<br />

(see pulse schema) enables a poor stress growth<br />

process for µm thick cBN hard coatings.<br />

(Forschungszentrum Dresden Rossendorf applied RUP3-10B)<br />

RF plasma of N2/Ar for cBN deposition

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