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Porifera-microbialites of the Lower Liassic (Northern Calcareous ...

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significance <strong>of</strong> microbial involvement and, if possible, to confirm taxonomic classification by<br />

sponge specific biomarkers (e.g. derivates <strong>of</strong> demospongic acids).<br />

The ion chromatograms (supplement 5) do not show any sponge specific substances and only a<br />

minor amount <strong>of</strong> bacterially sourced compounds. The total hydrocarbon fraction displays <strong>the</strong><br />

usual pattern <strong>of</strong> modal n-alkane distribution ranging from C14-C38. Branched alkenes, that could<br />

be <strong>of</strong> microbial source (due to sulfate reducing bacteria, Peckmann et al. 1999), are present in<br />

low concentration. Hopanoids, as being more characteristic residue <strong>of</strong> bacteria metabolism<br />

(Rohmer et al. 1984), were not detected. On <strong>the</strong> o<strong>the</strong>r hand, a significant concentration <strong>of</strong><br />

iso/anteiso-alkanoic acids is found in <strong>the</strong> Adnet limestone. Such terminally branched fatty acids<br />

are known as important constituents <strong>of</strong> bacterial lipids, thus <strong>the</strong>ir occurrence is in agreement with<br />

<strong>the</strong> assumption <strong>of</strong> microbially mediated carbonate formation (in decaying sponge organic<br />

matter).

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