PDF rendering: DokumentID 1415884, Version 1.0, Status Godkänt, Sekretessklass ÖppenThe total lack of enthalpy data for Cm does not allow a proper solubility limitestimation with temperature.The degree of confidence of solubility changes with temperature is subject tothe availability of enthalpy data.As a final remark, it is worth mentioning that the implementation of the whole set ofphosphate selected thermodynamic data in the Simple Functions has been discussedand verified in the present work. The verification has been done by comparisonbetween calculated results obtained with the Simple Functions Spreadsheet tool andobtained with the geochemical code PhreeqC.77
PDF rendering: DokumentID 1415884, Version 1.0, Status Godkänt, Sekretessklass Öppen7. ReferencesAfonin, E.G. and Pechurova, N.I. (1987) Complex formation of Nd (III) with phosphoricacid. Zhur. Neorg. Khim., 33, 2141-2142.Arcos, D. and Piqué, A. (2009): Update of the thermodynamic database used in <strong>SKB</strong>TR-06-32 and <strong>SKB</strong> TR-06-17. Amphos technical note to <strong>SKB</strong>.Baes Jr, C.F. (1956) A spectrophotometric investigation of uranyl phosphate complexformation in perchloric acid solution. The Journal of Physical Chemistry, 60(7), 878-883.Baeyens, B., and McKinley, I.G. (1989). A PHREEQE database for Pd, Ni and Se.NAGRA, NTB-88-28.Baldwin, W.G. (1969) Phosphate equilibria. II. Studies on the silver phosphateelectrodes. Arkiv Kemi, 31, 407-414.Bingler, L.S. and Byrne, R.H. (1989) Phosphate complexation of Gd(III) in aqueoussolutions. Polyhedron, 8, 1315-1320.Borisov, M.S., Yelesin, A.A., Lebedev, I.A., Filimonov, V.T. and Yakoliev, G.I. (1966)Investigations of complex formation of trivalent actinides and lanthanides in phosphoricsolutions. Radiokhimyia, 8, 42-48.Bottger, W. (1903) Loslichkeitsstudien an schwer loslich en Stoffen (PhD. dissertation,Leipzig)Brandel, V., and Dacheux, N. (2004) Chemistry of tetravalent actinide phosphates—Part I. Journal of Solid State Chemistry, 177(12), 4743-4754.Brendler, V., Geipel, G., Bernhard, G., and Nitsche, H. (1996) Complexation in thesystem UO 2+ 2 /PO 3- 4 /OH-(aq): Potentiometric and spectroscopic investigations at verylow ionic strengths. Radiochimica Acta, 74, 75-80.Brown, P., Curti, E. and Grambow, B. (2005) Chemical Thermodynamics 8. ChemicalThermodynamics of Zirconium. NEA Data bank, OECD. North Holland ElsevierScience Publishers B.V., Amsterdam, Netherlands78
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