SAFETY DATA SHEET Chockfast Orange Hardener 620 TS

REVISION DATE: 16/03/2009SAFETY DATA SHEETChockfast Orange Hardener 620 TS1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKINGPRODUCT NAMESUPPLIERChockfast Orange Hardener 620 TSPhiladelphia ResinsSHANNON INDUSTRIAL ESTATECO. CLAREIRELAND.T: 353 (0)61 471299F: 353 (0)61 471285admin@itwsnn.ieEMERGENCY TELEPHONE +44 (0)208 762 83222 HAZARDS IDENTIFICATIONCauses burns. May cause sensitisation by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.CLASSIFICATIONC;R34. R43. R52/53.3 COMPOSITION/INFORMATION ON INGREDIENTSNameEC No.CAS-No.ContentClassification2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL202-013-990-72-2 1-5%Xn;R22 Xi;R36/38TETRAETHYLENEPENTAMINE203-986-2112-57-2 10-30%C;R34 Xn;R21/22 R43 N;R51/53The Full Text for all R-Phrases are Displayed in Section 164 FIRST-AID MEASURESINHALATIONRemove victim immediately from source of exposure. Move into fresh air and keep at rest. For breathing difficulties oxygen may benecessary. Get medical attention if any discomfort continues.INGESTIONDO NOT induce vomiting. Get medical attention immediately. Drink a few glasses of water or milk.SKIN CONTACTRemove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation persists after washing.EYE CONTACTPromptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attentionimmediately!5 FIRE-FIGHTING MEASURESEXTINGUISHING MEDIAFire can be extinguished using: Carbon dioxide (CO2). Dry chemicals. Water.SPECIAL FIRE FIGHTING PROCEDURESSelf contained breathing apparatus and full protective clothing must be worn in case of fire.UNUSUAL FIRE & EXPLOSION HAZARDSNo unusual fire or explosion hazards noted.6 ACCIDENTAL RELEASE MEASURES1 / 4

REVISION DATE: 16/03/2009Chockfast Orange Hardener 620 TSPERSONAL PRECAUTIONSExtinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate.ENVIRONMENTAL PRECAUTIONSAvoid release to the environment. Contain spillages with sand, earth or any suitable adsorbent material.SPILL CLEAN UP METHODSDam and absorb spillages with sand, earth or other non-combustible material. Collect in containers and seal securely. Remove containersand flush area with water.7 HANDLING AND STORAGEUSAGE PRECAUTIONSAvoid contact with skin and eyes. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap beforeleaving the work site. Provide appropriate ventilation/respiratory protection against decomposition products during welding/flame cuttingoperations and to protect against dust during sanding grinding of cured product.STORAGE PRECAUTIONSStore in a cool and well-ventilated place. Avoid heat, flames and other sources of ignition.8 EXPOSURE CONTROLS/PERSONAL PROTECTIONPROCESS CONDITIONSProvide eyewash, quick drench.ENGINEERING MEASURESProvide adequate ventilation, including appropriate local extraction, to ensure that the defined workplace exposure limit is not exceeded.RESPIRATORY EQUIPMENTIf ventilation is insufficient, suitable respiratory protection must be provided.HAND PROTECTIONProtective gloves are recommended. Use protective gloves made of: Butyl rubber. Polyvinyl chloride (PVC). Neoprene. To preventrepeated or prolonged skin contact, wear impervious clothing and boots.EYE PROTECTIONWear splash-proof eye goggles to prevent any possibility of eye contact.HYGIENE MEASURESWash at the end of each work shift and before eating, smoking and using the toilet.9 PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCESOLUBILITYLiquidN/DMELTING POINT (°C) n/d RELATIVE DENSITY 0.95VAPOUR DENSITY (air=1) >1 VAPOUR PRESSURE

REVISION DATE: 16/03/2009INHALATIONChockfast Orange Hardener 620 TSIrritation of nose and throat. Irritating. May cause nausea, stomach pain and vomiting.INGESTIONCauses irritation, a burning sensation of the mouth, throat and gastrointestinal tract and abdominal pain.SKIN CONTACTMay cause sensitisation by skin contact.EYE CONTACTMay cause severe irritation to eyes. Vapour or spray may cause eye damage, impaired sight or blindness.ROUTE OF ENTRYSkin and/or eye contact. Ingestion. Inhalation.MEDICAL SYMPTOMSRepeated skin contact can cause sensitisation, with itching, rashes or swelling of the skin. May cuase respiratory sensitisation/asthmaticresponse. Repeated and/or prolonged exposure may result in adverse respiratory effects such as asthma.12 ECOLOGICAL INFORMATIONECOTOXICITYThere are no data on the ecotoxicity of this product.13 DISPOSAL CONSIDERATIONSGENERAL INFORMATIONWhen handling waste, consideration should be made to the safety precautions applying to handling of the product.DISPOSAL METHODSDispose of waste and residues in accordance with local authority requirements.14 TRANSPORT INFORMATIONUK ROAD CLASS 8PROPER SHIPPING NAMEUN NO. ROADADR CLASS NO.CORROSIVE LIQUID, N.O.S. (TETRAETHYLENEPENTAMINE,BIS[(DIMETHYLAMINO)METHYL]PHENOL)17608UK ROAD PACK GR.ADR CLASSADR PACK GROUP IIIHAZARD No. (ADR)80ADR LABEL NO.8HAZCHEM CODECEFIC TEC(R) NO. 80GC9-II+IIIRID CLASS NO.8RID PACK GROUP IIIUN NO. SEA1760IMDG CLASSEMS8F-A, S-BIMDG PACK GR.MARINE POLLUTANTUN NO. AIR 1760AIR CLASS8AIR PACK GR.15 REGULATORY INFORMATIONIIIIIIClass 8: Corrosive substances.2XIIINo.LABELLING3 / 4

REVISION DATE: 16/03/2009Chockfast Orange Hardener 620 TSCorrosiveCONTAINSTETRAETHYLENEPENTAMINERISK PHRASESR34R43Causes burns.May cause sensitisation by skin contact.SAFETY PHRASESR52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.S25Avoid contact with eyes.S26S45S36/37/39S60In case of contact with eyes, rinse immediately with plenty of water and seek medicaladvice.In case of accident or if you feel unwell, seek medical advice immediately (show labelwhere possible).Wear suitable protective clothing, gloves and eye/face protection.This material and its container must be disposed of as hazardous waste.16 OTHER INFORMATIONREVISION DATE 16/03/2009REV. NO./REPL. SDS GENERATED 2RISK PHRASES IN FULLR21/22R22R34R36/38R43R51/53Harmful in contact with skin and if swallowed.Harmful if swallowed.Causes burns.Irritating to eyes and skin.May cause sensitisation by skin contact.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.DISCLAIMERThis information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or inany process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, nowarranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to thesuitability of such information for his own particular use.4 / 4