IJIFR VOLUME 3 ISSUE 12 AUGUST 2016
RESEARCH PAPER
RESEARCH PAPER
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ISSN: 2347-1697<br />
International Journal of Informative & Futuristic Research (<strong>IJIFR</strong>)<br />
Volume - 3, Issue -<strong>12</strong>, August <strong>2016</strong><br />
Continuous 36 th Edition, Page No: 4578-4589<br />
The more likely route for permanganate oxidation of piperidone will be scheme-II.<br />
Scheme-II<br />
Formation of permanganate cycle complex and cleaning of complex will require more<br />
energy compared to the promotion of the alcohol. The dehydration is facilitated by the<br />
stabilization of positive charge possible through a non-classical carbonium ion of the type.<br />
7. COMPARISON OF THE OXIDATION RATE OF 2, 6- DIPHENYL<br />
PIPERIDINE-4-ONE AND 3-METHYL-2, 6- DIPHENYL PIPERIDINE-4-ONE<br />
A comparison of the oxidation state of 2, 6- diphenyl piperidine with or without 3-alkyl<br />
substituent during the cause of oxidation with Mn(VII) reveals that the rate of oxidation of<br />
the former is higher than that of the 3-alkyl substituent (Table 6).<br />
Table-6: Rate constants for the oxidation of 2, 6- diphenyl piperidine-4-one and 3-methyl-2, 6-<br />
diphenyl piperidine-4-one by Mn(VII), Mn(IV) and Mn(III)<br />
[piperidone] H 2 SO 4 Oxidant<br />
Mn(III) Mn(IV) Mn(VII)<br />
2,6- diphenyl piperidine-4-one 0.3<br />
0.4<br />
0.5<br />
3-methyl-2,6- diphenyl piperidine-4-one 0.3<br />
0.4<br />
0.5<br />
32.5<br />
50.0<br />
61.3<br />
19.0<br />
32.0<br />
41.0<br />
49.5<br />
57.5<br />
71.0<br />
32.0<br />
39.0<br />
60.0<br />
16.0<br />
25.5<br />
56.5<br />
14.0<br />
29.0<br />
51.0<br />
Bhoopesh Kumar Sharma, Dr. Soni Rani, Devesh Singh:: Kinetics<br />
And Mechanism Of Oxidation Of 2, 6 Diphenyl-Piperidine-4-One<br />
And 3-Methyl 2, 6 Diphenyl-Piperidine-4-One By Manganese (VII)<br />
Ion<br />
4588
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