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Pennsylvania sites also attacked by<br />

9/11 terrorists. People eligible can receive<br />

services, no matter where they<br />

live now in the U.S. The director of<br />

the National Institute for Occupational<br />

Safety and Health (NIOSH) administers<br />

the “WTC Health Program”,<br />

paid by the federal government and<br />

New York City. 9<br />

I was invited to participate in research<br />

into the chemical origins of<br />

the “WTC Cough” by the Naval Postgraduate<br />

School in 2010. Because<br />

no chemical-specific detectors were<br />

used, I used an indirect forensic science<br />

public policy approach, noting<br />

that almost all victims suffered<br />

from what is known in medicine as<br />

a “pulmonary edema”, characterized<br />

by fluid accumulation in the lungs,<br />

which collects in air sacs. Shortness<br />

of breath is the most common symptom<br />

of “pulmonary edema” and is due<br />

to the failure of the lungs to provide<br />

adequate Oxygen to the body.<br />

I examined the materials of construction<br />

used in World Trade Tower<br />

Centers 1 and 2 (WTCs), completed<br />

in 1973 and using from 200<br />

to 250,000 tons of common plastic,<br />

Polyvinyl chloride (PVC) as insulation<br />

in the WTCs. When the jet fuel<br />

ignited on “9/11”, the PVC was partially<br />

combusted, forming incomplete<br />

product of combustion chemicals,<br />

and creating from 10 to 15,000 tons<br />

of Phosgene within minutes. Phosgene<br />

is used both in industry and as a<br />

battle field weapon.<br />

The effects of exposure to irritants<br />

such as Hydrogen chloride, Phosgene,<br />

and particulates are dependent on the<br />

size of the particle and how readily<br />

the chemical dissolves in water. These<br />

properties determine where in the respiratory<br />

tract the chemical or particle<br />

is deposited and absorbed. Hydrogen<br />

chloride is very soluble therefore<br />

injury occurs in the upper airway as<br />

opposed to Phosgene, which effects<br />

mainly in the lower respiratory tract,<br />

the lungs.<br />

Phosgene is deadly at a concentration<br />

of 2 ppm. It appears as a white<br />

cloud and has a characteristic odor of<br />

sweet, newly mown hay in lower concentrations.<br />

Phosgene has low water<br />

solubility, so has a delayed onset of<br />

action, from 30 minutes to 8 hours. It<br />

readily reaches the respiratory alveoli<br />

and has direct toxic effects, leading to<br />

cellular damage of the alveolar-capillary<br />

membrane and subsequent pulmonary<br />

edema. 10 Alveoli tubes transfer<br />

O2 into and CO2 out of the lungs.<br />

Because there is no systemic absorption,<br />

other organs are not affected. 11<br />

I observed that when Phosgene reacted<br />

on the moisture of the alveoli in<br />

the lungs it formed corrosive Hydrogen<br />

chloride (HCl). Phosgene had reacted<br />

with the moisture of the alveoli<br />

to form corrosive Hydrogen chloride<br />

(HCl), causing “pulmonary edemas”<br />

in both residents and fire fighters.<br />

However, all Phosgene produced by<br />

the incomplete combustion of PVC<br />

was destroyed by the large amounts of<br />

14<br />

water used to fire the numerous fires<br />

at “Ground Zero”, preventing detection<br />

after “9/11”.<br />

To mitigate human exposure to<br />

Phosgene and other hazardous chemicals<br />

when responding to emergencies,<br />

I am designing and deploying<br />

autonomously operated chemical security<br />

networks capable of detecting,<br />

identifying and measuring not only<br />

Phosgene, but many other chemicals<br />

using a passive standoff chemical<br />

sensor using commercially available<br />

Fourier Transform Infrared (FTIR).<br />

Integrated with video surveillance,<br />

the chemical security “Tool<br />

Box” warns emergency responders<br />

of chemical hazards from up to three<br />

miles away in real-time, preventing<br />

firefighters and other emergency responders<br />

from becoming “canaries in<br />

a coal mine”, protecting both public<br />

health and critical infrastructure.<br />

Editor’s Note:<br />

Published reports within a few days<br />

of the 15th anniversary of 9/11 have<br />

indicated that Christine Todd Whitman,<br />

who was the administrator of<br />

the Environmental Protection Agency<br />

at the time of the 9/11 disaster, has<br />

finally apologized after fifteen years<br />

for her claim in the days immediately<br />

after the attacks that the air around<br />

Ground Zero and in lower Manhattan<br />

was safe. The reports also indicated<br />

that Ms Whitman had stated that<br />

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