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YSM Issue 90.4

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INN VATI N<br />

STATION<br />

Decluttering our Landfills<br />

►BY LESLIE SIM<br />

Half of the plastics we use today are used once and then<br />

left to accumulate in landfills. This statistic is symbolic of<br />

a greater issue: given our ever-increasing rate of plastic<br />

consumption, overstuffed landfills will create dire problems<br />

for future generations. And while humans eventually will<br />

have to face the consequences of plastic pollution on land—<br />

if we aren’t doing so already—plastic pieces are currently<br />

floating in our oceans, being ingested by marine animals and<br />

contaminating natural habitats.<br />

Reducing our plastic consumption is certainly one way to<br />

address this issue, but researcher Yiqi Yang and his team at the<br />

University of Nebraska-Lincoln have an even better solution:<br />

biodegradable plastics. Yang believes that his lab may have<br />

found a way to create a cost-effective biodegradable plastic<br />

that targets the textile industry, where polyester plastics are<br />

a big source of plastic consumption. Production of these<br />

plastics requires a lot of petroleum, a limited resource.<br />

Other researchers have designed biodegradable plastics in<br />

the past. For example, polylactic acid (PLA) was the first and<br />

largest-scale biopolymer produced from annually renewable<br />

resources such as corn starch and sugarcane. Biopolymers<br />

like PLA are very long molecules consisting of a biologicallyrelevant<br />

repeating subunit. However, PLA’s limitations make<br />

it ineffective for use in the textile industry: “Others have<br />

been able to find biodegradable products such as PLA, but<br />

those products cannot be used widely in the textile industry<br />

because they are easily hydrolyzed at high temperature,”<br />

Yang said. Hydrolysis refers to the degradation of a plastic<br />

by breakdown into its subunits. PLA-based plastics risk<br />

being too soft and too easily broken-down, and are thus<br />

not suitable for textile materials. While engineers have<br />

made some progress, the main problem today isn’t finding<br />

a biodegradable product, but rather one that is both costeffective<br />

for manufacturers and has the properties necessary<br />

for a quality plastic.<br />

The plastics we use daily have the opposite problem. Most<br />

plastics are too stable and stick around in landfills or natural<br />

habitats for a long time, unable to biodegrade. After some<br />

experiments, however, Yang and his team have developed<br />

a biodegradable plastic without those shortcomings. In<br />

their experiments, the team obtained two biopolymers,<br />

poly-L-lysine (PLL) and poly-D-lysine (PDL). With these<br />

biopolymers, they formed plastic fibers and employed a<br />

thermal treatment to form tighter structures with strong<br />

interactions between the polymers. This key process<br />

ultimately decreased the plastic’s sensitivity to hydrolysis,<br />

especially at high temperatures.<br />

Several experiments testing the new plastic’s properties<br />

show that Yang’s team may indeed have the key to tackling<br />

the two main problems in plastic development (hydrolysis<br />

and softness at high temperatures). However, until their<br />

materials are examined in large-scale production, they can’t<br />

say for sure whether their plastic will work on the industrial<br />

scale. The next step for Yang and his team is to test the plastic<br />

on a small scale in the textile industry. From there, they can<br />

target other industries. Nonetheless, Yang and his team have<br />

gotten a step closer to making a product that will hopefully<br />

prove useful in decreasing, if not eliminating, plastic waste.<br />

The impact of a biodegradable plastic in reducing plastic<br />

pollution is far-reaching. Currently, animals on land and in<br />

oceans are easily harmed by ingesting plastic microparticles<br />

or by getting caught in large pieces of plastic. For humans,<br />

plastic remains in our landfills for far too long, and we’re<br />

running out of space. Yang also cautions that tap water from<br />

all around the world contains microscopic pieces of plastic,<br />

and without our knowing, we could be accumulating plastic<br />

in our bodies.<br />

Since demand for plastic is growing exponentially as the<br />

human population grows, it is especially critical for us to<br />

find a sustainable resource that meets our needs without<br />

damaging our environment. As we move in the direction<br />

of finding cost-effective and useful forms of biodegradable<br />

plastic, we can rest assured that researchers like Yang and his<br />

team are on the case.<br />

www.yalescientific.org<br />

October 2017<br />

Yale Scientific Magazine<br />

35

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