YSM Issue 90.4
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INN VATI N<br />
STATION<br />
Decluttering our Landfills<br />
►BY LESLIE SIM<br />
Half of the plastics we use today are used once and then<br />
left to accumulate in landfills. This statistic is symbolic of<br />
a greater issue: given our ever-increasing rate of plastic<br />
consumption, overstuffed landfills will create dire problems<br />
for future generations. And while humans eventually will<br />
have to face the consequences of plastic pollution on land—<br />
if we aren’t doing so already—plastic pieces are currently<br />
floating in our oceans, being ingested by marine animals and<br />
contaminating natural habitats.<br />
Reducing our plastic consumption is certainly one way to<br />
address this issue, but researcher Yiqi Yang and his team at the<br />
University of Nebraska-Lincoln have an even better solution:<br />
biodegradable plastics. Yang believes that his lab may have<br />
found a way to create a cost-effective biodegradable plastic<br />
that targets the textile industry, where polyester plastics are<br />
a big source of plastic consumption. Production of these<br />
plastics requires a lot of petroleum, a limited resource.<br />
Other researchers have designed biodegradable plastics in<br />
the past. For example, polylactic acid (PLA) was the first and<br />
largest-scale biopolymer produced from annually renewable<br />
resources such as corn starch and sugarcane. Biopolymers<br />
like PLA are very long molecules consisting of a biologicallyrelevant<br />
repeating subunit. However, PLA’s limitations make<br />
it ineffective for use in the textile industry: “Others have<br />
been able to find biodegradable products such as PLA, but<br />
those products cannot be used widely in the textile industry<br />
because they are easily hydrolyzed at high temperature,”<br />
Yang said. Hydrolysis refers to the degradation of a plastic<br />
by breakdown into its subunits. PLA-based plastics risk<br />
being too soft and too easily broken-down, and are thus<br />
not suitable for textile materials. While engineers have<br />
made some progress, the main problem today isn’t finding<br />
a biodegradable product, but rather one that is both costeffective<br />
for manufacturers and has the properties necessary<br />
for a quality plastic.<br />
The plastics we use daily have the opposite problem. Most<br />
plastics are too stable and stick around in landfills or natural<br />
habitats for a long time, unable to biodegrade. After some<br />
experiments, however, Yang and his team have developed<br />
a biodegradable plastic without those shortcomings. In<br />
their experiments, the team obtained two biopolymers,<br />
poly-L-lysine (PLL) and poly-D-lysine (PDL). With these<br />
biopolymers, they formed plastic fibers and employed a<br />
thermal treatment to form tighter structures with strong<br />
interactions between the polymers. This key process<br />
ultimately decreased the plastic’s sensitivity to hydrolysis,<br />
especially at high temperatures.<br />
Several experiments testing the new plastic’s properties<br />
show that Yang’s team may indeed have the key to tackling<br />
the two main problems in plastic development (hydrolysis<br />
and softness at high temperatures). However, until their<br />
materials are examined in large-scale production, they can’t<br />
say for sure whether their plastic will work on the industrial<br />
scale. The next step for Yang and his team is to test the plastic<br />
on a small scale in the textile industry. From there, they can<br />
target other industries. Nonetheless, Yang and his team have<br />
gotten a step closer to making a product that will hopefully<br />
prove useful in decreasing, if not eliminating, plastic waste.<br />
The impact of a biodegradable plastic in reducing plastic<br />
pollution is far-reaching. Currently, animals on land and in<br />
oceans are easily harmed by ingesting plastic microparticles<br />
or by getting caught in large pieces of plastic. For humans,<br />
plastic remains in our landfills for far too long, and we’re<br />
running out of space. Yang also cautions that tap water from<br />
all around the world contains microscopic pieces of plastic,<br />
and without our knowing, we could be accumulating plastic<br />
in our bodies.<br />
Since demand for plastic is growing exponentially as the<br />
human population grows, it is especially critical for us to<br />
find a sustainable resource that meets our needs without<br />
damaging our environment. As we move in the direction<br />
of finding cost-effective and useful forms of biodegradable<br />
plastic, we can rest assured that researchers like Yang and his<br />
team are on the case.<br />
www.yalescientific.org<br />
October 2017<br />
Yale Scientific Magazine<br />
35