Shimadzu Techno-Research Inc., Japan - UNEP Chemicals

HRGC/HRMS Condition
GC HP 6890 Series GC System (Agilent)
Injector
7683 Series Injector (Agilent)
Auto Sampler 7683 Series Auto Sampler (Agilent)
He flow rate 1.0 mL/min
Injector On-column injector
Injection Volume 2mL
GC Column DB-17HT(J&W) 30m x 0.32mmi.d. (0.15um)
120�(1 min)-20�/min-160�(0 min)-3�/min-220�(0 min)-
10�/min-300��3min)
Column DB-17HT
DB-5MS
MS Micromass Autospec Ultima or Premier (Waters)
Ionization mode EI
Ionization Volt. 35-40eV
Accel. Volt. 8kV
Ion source Temp. 300 o C
Interface Temp. 300 o C
Resolution M/�M > 10,000 (10% Valley)
POPs* PBDEs PCBs
DB-5MS
POPs Monitor Ion
120�(0.1 min)-100�/min-300�(15 min)
DB-5MS
HT-8 PCB
OH-PCBs
DB-5MS
SHIMADZU TECHNO RESEARCH, Inc.
M + [M+2] + [M+4] +
DDD(M-CHCl 2), DDT(M-CCl 3) 235.0081 237.0053
13 C12-DDD(M-CHCl 2), 13 C 12-DDT(M-CCl3) 247.0483 249.0454
DDE(M-Cl2) 246.0003 247.9975
13 C12-DDE(M-Cl2) 258.0405 260.0376
Chlordane(M-Cl) 372.8260 374.8231
+10 mass
13 C10-Chlordane(M-Cl) 382.8595 384.8565
Nonachlor(M-Cl) 406.7870 408.7841
+10 mass
13 C10-Nonachlor(M-Cl) 416.8205 418.8175
Oxychlordane(M-Cl) 386.8053 388.8024
+10 mass
13 C10-Oxychlordane(M-Cl) 396.8387 398.8358
Aldrin(M-C5H6Cl), Dieldrin, Endrin(M-C5H6ClO) 262.8570 264.8541
13
C12-Aldrin(M-C5H6Cl), 13 C12-Dieldrin, Endrin(M-C5H6ClO) 269.8804 271.8775
Heptachlor(M-C5H5Cl)
13
C10-Heptachlor(M-C5H5Cl)
+5 mass
269.8131
274.8299
271.8102
276.8269
273.8072
278.8240
Heptachlor epoxide(M-Cl) 352.8442 354.8413
+10 mass
13 C10-Heptachlor epoxide(M-Cl) 362.8777 364.8748
HCB 283.8102 285.8073
+6 mass
+7 mass
13
C6-HCB 289.8303 291.8273
Mirex(M-C5Cl6)
13
C10-Mirex(M-C5Cl6)
+5 mass
269.8131
274.8299
271.8102
276.8269
273.8072
278.824
HCH(M-H2Cl3) 180.9379 182.9349
+6 mass
13
C6-HCH(M-HCl2) 186.9580 188.9550
13
C12-DiCB* 234.0406 236.0376
13
C12-TeCB* 301.9626 303.9597
SHIMADZU TECHNO RESEARCH, Inc.