Etude stratigraphique, pétrographique et diagénétique des grès d ...
Etude stratigraphique, pétrographique et diagénétique des grès d ...
Etude stratigraphique, pétrographique et diagénétique des grès d ...
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tel-00534181, version 1 - 9 Nov 2010<br />
Chapter I<br />
Hematite cements. In Zone III, the hematite cements are particularly common in the section measured<br />
within the Lokitaung Gorge, and they are clearly early cements; as they occur as pore-lining cements<br />
followed, in many instances, by later generations of siliceous and kaolin cements (sample LOK 11/04)<br />
(Fig. 23g, h). This type of cementation is very common within this zone and the different cements and their<br />
relative timing of generation are clearly distinguishable.<br />
Siliceous cements. These occur only in the top zone of the LSF and they are amorphous non-crystalline<br />
in texture (sample LOK 11/04) (Fig. 23g, h), identifiable only through SEM-EDS analysis. This<br />
type of cement is predated by the reddish-brown hematite cement and post dated by pore-filling vermicular<br />
kaolin cements.<br />
4.4.3. Porosity<br />
Porosity measurements were performed on a total of 24 samples taken from the LSF type-section<br />
(Fig. 24). The present total porosity in the samples is the n<strong>et</strong> porosity after the original porosity at deposition<br />
has been reduced by diagen<strong>et</strong>ic processes. These processes include mechanical compaction and the precipitation<br />
of cements. From the samples studied, the LSF has total porosity values ranging from a minimum of 3 %<br />
to a maximum of 25 %. While this porosity appears to be evenly distributed, it is markedly less abundant in<br />
the lower-most parts and the top-most parts of the LSF (which are cemented by poikilotopic calcite). This is<br />
as would be expected that the presence of pervasive cementation by poikilotopic calcite would drastically<br />
reduce the amount of primary intergranular porosity and this is what is observed in the LSF samples at the base<br />
of the formation. The percentage of calcite cement in the samples is close to the assumed original intergranular<br />
porosity of about 40 %. A significant part of the remaining porosity can be attributed to microporosity<br />
inside the kaolin cements and to K-feldspar dissolution.<br />
4.4.4. Source of cements ad diagen<strong>et</strong>ic reactions<br />
This discussion attempts to postulate the possible sources of the major cement types in the LSF in view<br />
of the important role these cements play in the d<strong>et</strong>ermination of the reservoir quality of any sandstone unit.<br />
4.4.4.1. Calcite cementation. In the basal section of the LSF, calcite cements were probably precipitated<br />
prior to any significant sediment compaction. The main diagen<strong>et</strong>ic events in this section were the deposition<br />
of grain-coating hematite cement, the formation of kaolin cements mainly from the alteration of feldspars<br />
and the precipitation of poikilotopic calcite cement. Assuming that the sandstones had 45 % initial intergranular<br />
porosity and the present residual porosity is less than 5 %, and the amount of cement is approximately<br />
40 %, this suggests that there has been no appreciable loss of porosity through compaction. There is no<br />
evidence of a significant mechano-chemical (pressure-solution) compaction; most of the compaction is therefore<br />
mechanical and it involves ductile deformation, re-arrangement and fracturing of grains. In other parts of<br />
the formation that do not have calcite cement, there is evidence of a higher amount of compaction with the<br />
presence of broken muscovite grains. Early calcite cement may have greatly inhibited sediment compaction<br />
and the mechanical compaction is assumed to have been early.<br />
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