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Brochure: Carbon Additives for Polymer Compounds - Timcal Graphite

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the product<br />

Introduction to EnSACo®<br />

Conductive <strong>Carbon</strong> Black<br />

Conductive carbon blacks are carbon blacks<br />

with high to very high stucture (or void volume)<br />

allowing the retention of a carbon network at<br />

low to very low filler content. The void volume<br />

can originate from the interstices between the<br />

carbon black particles, due to their complex arrangement,<br />

and from the porosity.<br />

HoW EnSACo® ConduCTIvE CARBon<br />

BLACkS ARE pRoduCEd<br />

The <strong>Timcal</strong> carbon black process has been developed<br />

around 1980 and is commercially exploited<br />

since 1982. The plant uses most modern<br />

technology. The process is based on partial oil<br />

oxidation of carbochemical and petrochemical<br />

origin. The major difference with other partial<br />

combustion carbon black technologies lies in<br />

the aerodynamic and thermodynamic conditions:<br />

• low velocity;<br />

• no quench;<br />

• no additives.<br />

This leads to a material with no or nearly no<br />

sieve residue on the 325 mesh sieve and allows<br />

the highest possible purity.<br />

The granulation process has been developed to<br />

achieve an homogeneously consistent product<br />

maintaining an outstanding dispersibility. It is in<br />

fact a free-flowing soft flake characterised by a<br />

homogeneous and very low crushing strength<br />

that guarantees the absence of bigger and<br />

harder agglomerates.<br />

The process enables the production of easily<br />

dispersible low surface area conductive carbon<br />

blacks as well as very high surface area conductive<br />

carbon blacks. The unique combination of<br />

high structure and low surface area also contributes<br />

to give outstanding dispersibility and<br />

smooth surface finish. The low surface area materials<br />

show a chain-like structure comparable<br />

to acetylene black. The very high surface area<br />

materials belong to the Extra Conductive (EC)<br />

family. Although ENSACO® <strong>Carbon</strong> Blacks are<br />

slightly more graphitic than furnace blacks, they<br />

are quite close to the latter ones as far as rein<strong>for</strong>cement<br />

is concerned.<br />

ENSACO® <strong>Carbon</strong> Blacks combine to a certain<br />

extent both the properties of furnace and acetylene<br />

black, reaching the optimal compromise.<br />

4<br />

TEM picture of ENSACO® 250 G<br />

<strong>Carbon</strong> Black showing the high<br />

level of aggregation.<br />

By courtesy of University of<br />

Louvain (Louvain-La-Neuve)<br />

STM picture of the surface of<br />

ENSACO® 250 G <strong>Carbon</strong> Black<br />

5x5 nm.<br />

By courtesy Prof. Donnet - Mulhouse<br />

SEM picture of ENSACO® 250 G<br />

<strong>Carbon</strong> Black illustrating the<br />

high void volume.<br />

By courtesy of University of<br />

Louvain (Louvain-La-Neuve)<br />

100 nm<br />

100 nm

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