Bacher - LC/MS

Applikation 3: Analyse von Glyphosate und AMPA
in Pflanzenmaterial mit LC/MS/MS
FMOC-
Glyphosate
0.1 mg/kg (LOQ)
IS: 13 C 2 - 15 N-
FMOC-
Glyphosate
Sample Name: "P821-64" Sample ID: "" File: "P821api#115.wiff"
Peak Name: "Glyphosate" Mass(es): "390.0/167.9 amu"
Comment: "Olive LOQ" Annotation: "P821-05.dam"
Sample Index: 1
Sample Type: Unknown
Concentration:
Calculated Conc:
N/A
0.105 mg/kg
2800
Acq. Date: 30-Apr-05
2600
Acq. Time: 01:53:54
2400
Modified: Yes
Bunching Factor: 3
2200
Noise Threshold:
Area Threshold:
46.96
234.78
cps
cps
2000
Num. Smooths:
RT Window:
2
30.0 sec
1800
Expected RT: 6.91 min
1600
Sep. Width: 0.20
Sep. Height: 0.01
1400
Exp. Peak Ratio: 5.00
Exp. Adj. Ratio: 4.00
1200
Exp. Val. Ratio:
Use Relative RT:
3.00
No
1000
Int. Type: Manual
Retention Time: 7.06 min
Area: 2.19e+004 counts
Height: 2.20e+003 cps
Start Time: 6.81 min
End Time: 7.33 min
In ten s ity , c p s
Sample Name: "P821-64" Sample ID: ""
0
4.5 5.0 5.5
File: "P821api#115.wiff"
6.0 6.5 7.0
Time, min
7.5 8.0 8.5 9.0
Peak Name: "Glyphosate IS(IS)" Mass(es): "393.0/171.0 amu"
Comment: "Olive LOQ" Annotation: "P821-05.dam"
Sample Index:
Sample Type:
1
Unknown
7000
7.05
Concentration: 0.400 mg/kg
Calculated Conc: N/A
6500
Acq. Date:
Acq. Time:
30-Apr-05
01:53:54
6000
8.24
Modified: Yes
Bunching Factor: 3
Noise Threshold: 17.63 cps
Area Threshold: 88.15 cps
Num. Smooths: 2
RT Window: 30.0 sec
Expected RT: 6.90 min
Sep. Width: 0.20
Sep. Height: 0.01
Exp. Peak Ratio: 5.00
Exp. Adj. Ratio: 4.00
Exp. Val. Ratio: 3.00
Use Relative RT: No
Int. Type: Manual
Retention Time: 7.05 min
Area: 6.98e+004 counts
Height: 7.08e+003 cps
Start Time: 6.83 min
End Time: 7.41 min
In te n sity , c p s
800
600
400
200
5500
5000
4500
4000
3500
3000
2500
2000
1500
1000
500
7.06
7.53
7.85
8.03
0
4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0
Time, min
8.88