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Selective Salt Recovery from Reverse Osmosis Brine - University of ...

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LIST OF FIGURES<br />

Figure 1: Proposed RO Concentrate Treatment Train .........................................................3<br />

Figure 2: Research Schedule ................................................................................................7<br />

Figure 3: Ideal Resin Phase Concentration Pr<strong>of</strong>ile <strong>from</strong> [17]............................................14<br />

Figure 4: Loading and Regeneration <strong>of</strong> an Ion Exchange Column ...................................15<br />

Figure 5: Model Scheme ....................................................................................................25<br />

Figure 6: Response to Pulse Tracer Input for TIS Model with Differing Number <strong>of</strong> Tanks25<br />

Figure 7: Effluent Concentration Curve <strong>from</strong> TIS Model using Different Numbers <strong>of</strong><br />

Tanks ..........................................................................................................................26<br />

Figure 8: Effluent Concentration Curve <strong>from</strong> MATLAB Model using Different Numbers<br />

<strong>of</strong> Segments ................................................................................................................26<br />

Figure 9: Graphical User Interface for MATLAB model ..................................................27<br />

Figure 10: Example Column Snapshot <strong>from</strong> Model ..........................................................29<br />

Figure 11: Example Breakthrough Curve <strong>from</strong> Model ......................................................29<br />

Figure 12: Comparison <strong>of</strong> Column Snapshots with Different Numbers <strong>of</strong> Segments .......30<br />

Figure 13: Resin Samples ..................................................................................................33<br />

Figure 14: Atomic Absorption Spectrometer (left) and Ion Chromatography System<br />

(right) .........................................................................................................................34<br />

Figure 15: Calcium Separation Factors vs. Equivalent Fraction <strong>of</strong> Calcium ....................38<br />

Figure 16: Calcium Separation Factors vs. Solution Ionic Strength ..................................38<br />

Figure 17: Predicted Calcium Separation Factors vs. Measured Calcium Separation<br />

Factors ........................................................................................................................39<br />

Figure 18: Modeled Breakthrough Curves for Systems with Separation Factors Ranging<br />

<strong>from</strong> 1.5 to 6 ...............................................................................................................40<br />

Figure 19: Bed Volumes to Breakthrough as a Function <strong>of</strong> Calcium Separation Factor ..41<br />

Figure 20: Separation Factor as a Function <strong>of</strong> Ionic Strength and Equivalent Ionic<br />

Fraction <strong>of</strong> Calcium ...................................................................................................42<br />

Figure 21: Magnesium Separation Factors vs. Equivalent Fraction <strong>of</strong> Magnesium ..........42<br />

Figure 22: Magnesium Separation Factors vs. Ionic Strength ..........................................43<br />

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