Postma et al., submitted to Geochim. Cosmochim. Acta Horneman, A., van Geen, A., Kent, D.V., Ma<strong>the</strong>, P.E., Zheng, Y., Dhar, R.K., et al., 2004. Decoupl<strong>in</strong>g of As and Fe release to Bangladesh groundwater under reduc<strong>in</strong>g conditions: Part I. Evidence from sediment profiles. Geochim. Cosmochim. Acta 68, 3459–3473. Hyac<strong>in</strong><strong>the</strong>, C., Bonneville, P., Van Cappellen, P., 2006 Reactive iron(III) <strong>in</strong> sediments: Chemical versus microbial extractions. Geochim. Cosmochim. Acta 70, 4166- 4180. Islam, F.S., Gault, A.G., Boothman, C., Polya, D.A., Charnock, J.M., Chatterjee, D., Lloyd, J.R., 2004. Role of metal-reduc<strong>in</strong>g bacteria <strong>in</strong> <strong>arsenic</strong> release from Bengal <strong>delta</strong> sediments. Nature 430, 68–71. Jung, H.B., Zheng, Y., 2006. Enhanced recovery of arsenite sorbed onto syn<strong>the</strong>tic oxides by L-ascorbic acid addition to phosphate solution: calibrat<strong>in</strong>g a sequential leach<strong>in</strong>g method for <strong>the</strong> speciation analysis of <strong>arsenic</strong> <strong>in</strong> natural samples. Water Res. 40, 2168 – 2180. Kocar, B.D., Polizzotto, M.L., Benner S.G., Y<strong>in</strong>g, S.C., Ung, M., Ouch, K., Samreth, S., Suy, B., Phan, K., Sampson, M., Fendorf, S., 2008. Integrated biogeochemical and hydrologic processes driv<strong>in</strong>g <strong>arsenic</strong> release from shallow sediments to groundwaters of <strong>the</strong> Mekong <strong>delta</strong>. Appl. Geochem. 23, 3059–3071. Larsen, F., Pham, N.Q., Dang, D.N., Postma, D., Jessen, S., Pham, V.H., Nguyen, T.B., Trieu, H.D., Nguyen, H., Chambon, J., Nguyen, H.V., Ha, D.H., Nguyen, T.M.H. Mai T.D. 2008. Controll<strong>in</strong>g geological and hydrogeological processes <strong>in</strong> an <strong>arsenic</strong> contam<strong>in</strong>ated aquifer on <strong>the</strong> <strong>Red</strong> <strong>River</strong> floodpla<strong>in</strong>, <strong>Vietnam</strong>. Appl. Geochem. 23, 3099-3115. 29
Postma et al., submitted to Geochim. Cosmochim. Acta Larsen, O., and Postma, D., 2001: K<strong>in</strong>etics of bulk dissolution of lepidocrocite, ferrihydrite and goethite. Geochim. Cosmochim. Acta, 65, 1367-1379. Larsen, O., Postma, D. and Jakobsen, R. 2006: The reactivity of iron oxides towards reductive dissolution <strong>in</strong> a shallow sandy aquifer (Rømø, Denmark). Geochim. Cosmochim. Acta 70, 4827-4835. Lear, G., Song, B., Gault, A.G., Polya, D.A., Lloyd, J.R., 2007. Molecular analysis of arsenate-reduc<strong>in</strong>g bacteria with<strong>in</strong> Cambodian sediments follow<strong>in</strong>g amendment with acetate. Appl. Environ. Microbiol. 73, 1041–1048. McArthur, J.M., Ravenscroft, P., Safiulla, S., Thirlwall, M.F., 2001. Arsenic <strong>in</strong> groundwater: test<strong>in</strong>g pollution mechanisms for sedimentary aquifers <strong>in</strong> Bangladesh. Water Resour. Res. 37, 109–117. Meng, X., Wang, W., 1998. Speciation of <strong>arsenic</strong> by disposable cartridges. In: Proc. Third Int.Conf. Arsenic Exposure and Health Effects. Soc. Environ. Geochem. and Health, Univ. Colorado at Denver. Murad, E., Cashion, J., 2004. Mössbauer Spectroscopy of Environmental Materials and <strong>the</strong>ir Industrial Utilization, Kluwer, Dordrecht. Nickson, R., McArthur, J., Burgess, W., Ahmed, K.M., Ravenscroft, P., Rahman, M., 1998. Arsenic poison<strong>in</strong>g of Bangladesh groundwater. Nature 395, 338. Nickson, R.T., McArthur, J.M., Ravenscroft, P., Burgess, W.G., Ahmed, K.M., 2000. Mechanism of <strong>arsenic</strong> release to groundwater, Bangladesh and West Bengal. Appl. Geochem. 15, 403–413. Pedersen, H.D., Postma, D., Jakobsen, R., Larsen, O., 2005. Fast transformation of iron oxyhydroxides by <strong>the</strong> catalytic action of Fe(II). Geochim. Cosmochim. Acta 69, 3967–3977. 30
- Page 1 and 2:
Groundwater arsenic in the Red Rive
- Page 3 and 4:
Søren Jessen Groundwater arsenic i
- Page 5 and 6:
organic matter may prevent As mobil
- Page 8 and 9:
Resumé Naturligt frigivet arsen (A
- Page 10 and 11:
efterfølgende forsøgt at opstille
- Page 12 and 13:
Preface This PhD thesis deals with
- Page 14:
Table of contents 1 INTRODUCTION: T
- Page 17 and 18:
The PhD research presented in this
- Page 19 and 20:
educed form as As(III), which is al
- Page 21 and 22:
A more complex and intimate relatio
- Page 23 and 24:
sedimentary As content (Postma et a
- Page 25 and 26:
(Anawar and Mihaljevi, 2009), and g
- Page 28 and 29:
3 Regional As distribution in the R
- Page 30 and 31:
in large part by changes in the eus
- Page 32:
In the Red River delta, the Pleisto
- Page 35 and 36:
the Red River delta, which are not
- Page 38 and 39:
5 The mitigation potential of bank
- Page 40:
Noteworthy is, that the ratio of Fe
- Page 43 and 44:
trend in the distribution of the RF
- Page 45 and 46:
2008) or the Hach or Merck test kit
- Page 47 and 48:
Badloe C., Nguyen T. P. T. and Nguy
- Page 49 and 50:
Driehaus W., Seith R. and Jekel M.
- Page 51 and 52:
Islam F. S., Boothman C., Gault A.
- Page 53 and 54:
Mondal D. and Polya D. A. (2008) Ri
- Page 55 and 56:
A. Ali and Z. Adeel). ITN Centre, B
- Page 57 and 58:
Ahmed K. M. (2006) A transect of gr
- Page 60:
Arsenic in groundwater of the Red R
- Page 63 and 64:
In short, there is a consensus amon
- Page 65 and 66:
The local geology shows mainly sand
- Page 67 and 68:
ane concentration and P CO2 values
- Page 69 and 70:
Fig. 7. The distribution of arsenic
- Page 71 and 72:
H3AsO3 þ H2O $ H2AsO4 þ 3H þ þ
- Page 73 and 74:
Fig. 12. The relative composition o
- Page 75 and 76:
of the Fe-oxides in the upper 3 m c
- Page 77 and 78:
found that while As(V) coprecipitat
- Page 79 and 80:
desh: further evidence of decouplin
- Page 82 and 83:
Controlling geological and hydrogeo
- Page 84 and 85:
Here the results of the geological
- Page 86 and 87:
sediments. In general, the coarser
- Page 88 and 89:
Fig. 5. Thickness of the clay-rich
- Page 90 and 91:
a b c The groundwater head distribu
- Page 92 and 93:
Table 2 Total As and stable isotope
- Page 94 and 95: delayed yield from the fine grained
- Page 96 and 97: that the situation in Dan Phuong co
- Page 98: Mathers, S., Zalasiewicz, J., 1999.
- Page 102 and 103: 0883-2927/$ - see front matter © 2
- Page 104 and 105: 3118 S. Jes sen et al. / Applied Ge
- Page 106 and 107: 3120 S. Jes sen et al. / Applied Ge
- Page 108 and 109: 3122 S. Jes sen et al. / Applied Ge
- Page 110 and 111: 3124 S. Jes sen et al. / Applied Ge
- Page 112: 3126 S. Jes sen et al. / Applied Ge
- Page 116 and 117: Postma et al., submitted to Geochim
- Page 118 and 119: Postma et al., submitted to Geochim
- Page 120 and 121: Postma et al., submitted to Geochim
- Page 122 and 123: Postma et al., submitted to Geochim
- Page 124 and 125: Postma et al., submitted to Geochim
- Page 126 and 127: Postma et al., submitted to Geochim
- Page 128 and 129: Postma et al., submitted to Geochim
- Page 130 and 131: Postma et al., submitted to Geochim
- Page 132 and 133: Postma et al., submitted to Geochim
- Page 134 and 135: Postma et al., submitted to Geochim
- Page 136 and 137: Postma et al., submitted to Geochim
- Page 138 and 139: Postma et al., submitted to Geochim
- Page 140 and 141: Postma et al., submitted to Geochim
- Page 142 and 143: Postma et al., submitted to Geochim
- Page 146 and 147: Postma et al., submitted to Geochim
- Page 148 and 149: Postma et al., submitted to Geochim
- Page 150 and 151: Postma et al., submitted to Geochim
- Page 152 and 153: Postma et al., submitted to Geochim
- Page 154 and 155: Postma et al., submitted to Geochim
- Page 156 and 157: Postma et al., submitted to Geochim
- Page 158 and 159: Postma et al., submitted to Geochim
- Page 160 and 161: Postma et al., submitted to Geochim
- Page 162: The mobility of arsenic in a Red Ri
- Page 165 and 166: Jessen et al., manuscript to be sub
- Page 167 and 168: Jessen et al., manuscript to be sub
- Page 169 and 170: Jessen et al., manuscript to be sub
- Page 171 and 172: Jessen et al., manuscript to be sub
- Page 173 and 174: Jessen et al., manuscript to be sub
- Page 175 and 176: Jessen et al., manuscript to be sub
- Page 177 and 178: Jessen et al., manuscript to be sub
- Page 179 and 180: Jessen et al., manuscript to be sub
- Page 181 and 182: Jessen et al., manuscript to be sub
- Page 183 and 184: Jessen et al., manuscript to be sub
- Page 185 and 186: Jessen et al., manuscript to be sub
- Page 187 and 188: Jessen et al., manuscript to be sub
- Page 189 and 190: Jessen et al., manuscript to be sub
- Page 191 and 192: Jessen et al., manuscript to be sub
- Page 193 and 194: Jessen et al., manuscript to be sub
- Page 195 and 196:
Jessen et al., manuscript to be sub
- Page 197 and 198:
Jessen et al., manuscript to be sub
- Page 199 and 200:
Jessen et al., manuscript to be sub
- Page 201 and 202:
Jessen et al., manuscript to be sub
- Page 203 and 204:
Jessen et al., manuscript to be sub
- Page 205 and 206:
Jessen et al., manuscript to be sub
- Page 207 and 208:
Table 1
- Page 209 and 210:
Fig. 1
- Page 211 and 212:
Fig. 3
- Page 213 and 214:
Fig. 5
- Page 215 and 216:
Fig. 7
- Page 217 and 218:
Fig. 9
- Page 219 and 220:
Fig. 11