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Groundwater arsenic in the Red River delta, Vietnam ... - Fiva

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Jessen et al., manuscript to be submitted to Geochim. Cosmochim. Acta<br />

FIGURE CAPTIONS<br />

Figure 1 (a) The location of <strong>the</strong> field site for <strong>the</strong> present and related studies. The<br />

transects are located adjacent to tributary channels active <strong>in</strong> <strong>the</strong> wet<br />

season. (b) Pump<strong>in</strong>g and selected observation wells <strong>in</strong> <strong>the</strong> N transect.<br />

Figure 2 Cross section of <strong>the</strong> N transect (Fig. 1) and channel bed sediments.<br />

Screened <strong>in</strong>tervals are <strong>in</strong>dicated for <strong>the</strong> pump<strong>in</strong>g and observation wells.<br />

Three non-screened channel bed drill<strong>in</strong>gs are <strong>in</strong>dicated.<br />

Figure 3 Anoxic elution by 10 mM NaHCO3 (pH 7) of a reduced Holocene aquifer<br />

sediment, obta<strong>in</strong>ed at a sediment-to-eluent ratio of 106 ± 21 g/L. (a) Total<br />

(cumulated) eluted As and Si as a function of <strong>the</strong> total amount of eluent<br />

added and (b) as a function of <strong>the</strong> aqueous As concentration at <strong>the</strong> end of<br />

each elution step. The arrow <strong>in</strong> (b) <strong>in</strong>dicates an extrapolation to <strong>the</strong> y-axis.<br />

Note <strong>the</strong> different units for As and Si. Model l<strong>in</strong>es <strong>in</strong>dicate CD-MUSIC<br />

and D&M surface complexation models for goethite (full) and ferrihydrite<br />

(dotted), respectively. Model l<strong>in</strong>es <strong>in</strong> (a) are for As(III) (upper two l<strong>in</strong>es)<br />

and Si (lower two l<strong>in</strong>es). Model l<strong>in</strong>es <strong>in</strong> (b) are for As(III).<br />

Figure 4 As(III) adsorption iso<strong>the</strong>rm for a reduced Holocene aquifer sediment<br />

calculated us<strong>in</strong>g Eq.(1). Dashed l<strong>in</strong>es trace <strong>the</strong> desorption path between<br />

po<strong>in</strong>ts obta<strong>in</strong>ed by a desorption step follow<strong>in</strong>g an adsorption step. Model<br />

l<strong>in</strong>es <strong>in</strong>dicate CD-MUSIC and D&M surface complexation models for<br />

goethite (full) and ferrihydrite (dotted), respectively.<br />

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