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IN WESTERN AUSTRALIA - Department of Mines and Petroleum

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y introducing appropriate organisms into suitable<br />

coals. This process <strong>of</strong> in-situ biogasification is at the<br />

conceptual stage at present, but has important longterm<br />

implications. Further refinement <strong>of</strong> this process<br />

may be provided by the use <strong>of</strong> genetic engineering<br />

to optimise the organisms for gas generation.<br />

There is some difference <strong>of</strong> opinion regarding the<br />

nature <strong>of</strong> biogenically generated gas in coal seams<br />

- some authorities consider that there is little, if any,<br />

adsorbed gas, <strong>and</strong> that the gas is present in a ‘free’<br />

form in the cleats (small fractures in the coal) <strong>and</strong><br />

other openings, as well as in formation waters. It is<br />

probable that both biogenic <strong>and</strong> thermogenic<br />

scenarios embrace adsorbed, ‘free’ <strong>and</strong> dissolved<br />

gas, but in different proportions. In both scenarios,<br />

the retention <strong>of</strong> gas is almost totally dependant<br />

upon hydrostatic pressure <strong>and</strong> commercial<br />

production, thus involving the production <strong>of</strong><br />

significant water to lower the hydrostatic pressure to<br />

permit the gas to flow.<br />

Coal quality<br />

Increasing ash content causes coal strength to<br />

increase, thereby decreasing the potential for<br />

fracturing/cleating. Coals with lesser amounts <strong>of</strong> ash<br />

are, therefore, the most likely to have the greatest<br />

cleat development - <strong>and</strong> thus the highest<br />

permeabilities. Also, as the ash component <strong>of</strong> coal<br />

cannot absorb methane, it reduces the volume <strong>of</strong><br />

gas that can be contained in a unit volume <strong>of</strong> coal.<br />

The maximum ash content before a coal becomes<br />

non-commercial has not been determined, but<br />

probably varies according to other parameters such<br />

as maturation level. Additionally, the cleat density is<br />

greater in the brighter coal types - such as vitrain<br />

<strong>and</strong> bright clarain <strong>and</strong> substantially less in the dull<br />

coals - like durain.<br />

The process <strong>of</strong> gas flow from the solid coal to the<br />

cleats is one <strong>of</strong> diffusion. Usually the cleats are filled<br />

with water <strong>and</strong> the desorption <strong>of</strong> gas within the cleats<br />

leads to the two phases existing within the cleats. If a<br />

secondary major fracture system exists, flow may<br />

then take place from the cleats to the major fractures<br />

(Figure 1). Both the cleats <strong>and</strong> major fractures exhibit<br />

their own phase dependant permeabilities.<br />

Diagenesis may cause deposition <strong>of</strong> mineral matter<br />

in the coal cleats, significantly reducing coal<br />

permeability. Carbonate infilling is the most<br />

common form <strong>of</strong> diagenesis in coals, but silica,<br />

pyrite, illite, smectite, kaolinite <strong>and</strong> other clays have<br />

also been observed as cleat infillings. Prospective<br />

gas coals should thus be relatively free <strong>of</strong> such<br />

cleat-filling substances.<br />

The gas content <strong>of</strong> any prospective coal should be<br />

greater than 8.5 cc/g (300 scf/t). The coals also<br />

need to reach a certain level <strong>of</strong> thermal maturity in<br />

order to generate gas <strong>and</strong> to produce the structure<br />

<strong>and</strong> chemistry necessary for storing commercial<br />

quantities <strong>of</strong> methane within the coal. The vitrinite<br />

reflectance should be in the range <strong>of</strong> R O <strong>of</strong> 0.7% to<br />

R O <strong>of</strong> 2.0%. In general, the higher the maturity, the<br />

greater the adsorption capability <strong>of</strong> any coal. From<br />

looking at coal seam methane operations in the US,<br />

where the industry is approaching a mature stage, it<br />

appears that the minimum thickness <strong>of</strong> coal<br />

required to produce commercial quantities <strong>of</strong> gas is<br />

5 to 6 metres in no more than 3 or 4 seams.<br />

The gas content <strong>of</strong> coal is usually determined by<br />

gas desorption procedures, which means gas is<br />

desorbed from coal by placing a sample <strong>of</strong> the coal<br />

(usually from drillcore) in a sealed container, <strong>and</strong><br />

measuring the amount <strong>of</strong> released gas over periods<br />

which may range from days to months. This<br />

procedure requires the gas to be desorbed from the<br />

coal’s micropore structure (ie the thermogenic<br />

scenario); however, the predominantly ‘free’ gas <strong>of</strong><br />

the biogenic scenario (or a significant component <strong>of</strong><br />

it) may not be detected by this desorption method<br />

<strong>and</strong>, hence, the resulting low to non-existent gas<br />

contents may give a quite false portrayal <strong>of</strong> gas<br />

producibility from a formation.<br />

Pressure <strong>and</strong> permeability<br />

In thermogenic situations, gas is adsorbed onto the<br />

coal’s micropore surfaces <strong>and</strong> held in place by the<br />

reservoir (water) pressure. The methane within a<br />

coal seam is released when the hydrostatic<br />

pressure is reduced, allowing the cleats in the coal<br />

to exp<strong>and</strong>, increasing permeability <strong>and</strong> commencing<br />

the process <strong>of</strong> desorption <strong>of</strong> the methane gas from<br />

the coal. Most coals show a significant relationship<br />

between effective stress (total stress minus<br />

hydrostatic pressure) <strong>and</strong> permeability. The cleats<br />

being closed by increasing effective stress cause a<br />

reduction in permeability. If fluid pressure is high, it<br />

tends to open the cleats <strong>and</strong> as pressure decreases<br />

with fluid withdrawal the cleats close. The reduction<br />

in permeability may be <strong>of</strong> an order <strong>of</strong> magnitude for<br />

anything between 2 <strong>and</strong> 10 MPa <strong>of</strong> increasing<br />

effective stress. The s<strong>of</strong>ter the coal the more<br />

pronounced this effect is.<br />

As water <strong>and</strong> gas are produced from the seam, the<br />

effective stress increases leading generally to a<br />

reduction in permeability. Many coals, however,<br />

exhibit an increase in permeability with production.<br />

Figure 1. Flow through cleats in coal<br />

PWA April Edition - Coal Seam Methane 35<br />

This is caused by an effect that tends to de-stress<br />

the seam. This de-stressing is a result <strong>of</strong> the fact<br />

that most coals shrink as gas is desorbed. The<br />

shrinkage reduces the lateral stress on the seam<br />

<strong>and</strong> shifts that stress into the surrounding rocks.<br />

These two opposing effects on the effective stress<br />

mean that the permeability <strong>of</strong> the seam may either<br />

decrease or increase with the removal <strong>of</strong> gas <strong>and</strong><br />

water from the seam, depending on the<br />

characteristics <strong>of</strong> the coal <strong>and</strong> associated gas.<br />

Frequently both these effects are present, with an<br />

initial permeability decrease in the reservoir<br />

pressure around the producing well, followed by an<br />

increase as significant desorption-induced<br />

shrinkage occurs within the coal.<br />

Depending on the nature <strong>of</strong> the coal <strong>and</strong> depth <strong>of</strong><br />

burial, this release <strong>of</strong> methane varies from negligible<br />

gas flow to commercial rates <strong>of</strong> gas flow, although<br />

in all cases a significant amount <strong>of</strong> time is required<br />

to dewater the coal bed before any gas is<br />

recovered. Timing <strong>of</strong> water h<strong>and</strong>ling is one <strong>of</strong> the<br />

major differences between CSM <strong>and</strong> convention<br />

gas. With conventional gas, gas is trapped under<br />

pressure <strong>and</strong> overlies water. This pressure is then<br />

used to allow the gas to flow to surface through the<br />

well casing until the rising water level in the trap<br />

increases to the point where the amount <strong>of</strong> gas<br />

produced relative to water becomes uneconomic<br />

because the rate <strong>of</strong> gas production is so low. In<br />

CSM operations, the water, which is holding the gas<br />

to the coal through hydrostatic pressure, is drained<br />

first <strong>and</strong> as the water pressure (measured in terms<br />

<strong>of</strong> hydrostatic pressure on the gasfield) decreases,<br />

adsorbed gas is released from the coal seam <strong>and</strong><br />

then produced through the well bore over a long<br />

period (Figure 2). Over time, the rate <strong>of</strong> gas<br />

desorption decreases until the flow rates become<br />

uneconomic to continue to produce from the bore.<br />

The water, which is commonly saline but in some<br />

areas can be potable, must be disposed <strong>of</strong> in an<br />

environmentally acceptable manner. Surface<br />

disposal <strong>of</strong> large volumes <strong>of</strong> potable water can<br />

affect streams <strong>and</strong> other habitats, <strong>and</strong> subsurface<br />

reinjection makes production more costly.

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