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Miniature Sensors for Biological Warfare Agents using Fatty Acid ...

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80. Library mass spectrum of methyl cis-9,12-octadecadienoate (C18:2 cis-<br />

9,12 ME).....................................................................................................87<br />

81. Library mass spectrum of methyl cis-9,12,15-octadecatrienoate (C18:3<br />

cis-9,12,15 ME). .........................................................................................87<br />

82. Library mass spectrum of cis-13 docosenoic acid methyl ester (C22:1<br />

cis-13 ME). .................................................................................................87<br />

83. Composition of Supelco 18920-1 FAME mixture........................................92<br />

84. Alltech catalog FAME chromatograms 1314, 1317-1319, 1321, and<br />

1322. ..........................................................................................................93<br />

85. Alltech catalog FAME chromatograms 1754, 1327, and 1316....................94<br />

86. Alltech FAME chromatograms 2140, 1318. ................................................94<br />

87. J&W DB-23 FAME chromatogram..............................................................95<br />

88. J&W DB-23 FAME chromatogram..............................................................95<br />

89. J&W canola chromatogram. .......................................................................96<br />

90. Alltech canola chromatograms 2214, 2213. ...............................................96<br />

91. Alltech catalog FAME chromatograms (packed columns). .........................97<br />

Tables<br />

1. Diseases and the bacteria that cause them................................................18<br />

2. <strong>Fatty</strong> acids found in food and other items...................................................19<br />

3. Relative amounts of fatty acid constituents, detected by pyrolysis/mass<br />

spectrometry[24].........................................................................................20<br />

4. <strong>Fatty</strong> acids detected <strong>for</strong> bacteria <strong>using</strong> pyrolysis methods. ........................21<br />

5. <strong>Fatty</strong> acids detected <strong>for</strong> viral-related agents <strong>using</strong> pyrolysis methods........22<br />

6. Species detected in spores <strong>using</strong> pyrolysis methods. ................................23<br />

7. GC columns used <strong>for</strong> fatty acids.................................................................25<br />

8. Characteristics of B. anthracis cells............................................................27<br />

9. General characteristics of B. anthracis spores. ..........................................30<br />

10. Derivatizing reagents used <strong>for</strong> general methylation....................................33<br />

11. Byproducts of TMAH derivatization [5]. ......................................................35<br />

12. Derivatizing reagents used <strong>for</strong> pyrolysis methylation..................................36<br />

13. Instruments used <strong>for</strong> pyrolysis....................................................................39<br />

14. History or pyrolysis / methylation................................................................40<br />

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