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<strong>Gallium</strong> Phosphide (GaP) 449<br />

tween the a experimental data from Cardona et al. [17, 18] and the a values<br />

obtained from KK processing of early R data [16] can be attributed to<br />

R-limited range of R spectra and to the inadequacy of the conventional gasdischarge<br />

spectroscopic sources; in fact, hot-cathode argon lamps have typical<br />

separation of about 1 e V between adjacent lines, equal to the expected<br />

spin-orbit splitting of core levels (0.53 e V for Ga) and to separation between<br />

peaks in the density of conduction states.<br />

In Table IV nand k values in the 0.44-0.08-J-lm range have been obtained<br />

by KK transform on R spectra from Philipp and Ehrenreich [16J and<br />

Stokowski and Sell [19J, extended to shorter wavelengths with the data of<br />

Gudat et al. [20] and longer wavelengths (visible and infrared) with those of<br />

Kleiman and Spitzer [lJ, Giehler and lahne [6J, and Bond [9]. The results<br />

are in fair agreement with the dielectric function ellipsometrically determined<br />

between 0.36 and 0.31 J-lm [21].<br />

REFERENCES<br />

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2. A. S. Barker, Jr., Phys. Rev. 165,917 (1968).<br />

3. D. F. Parsons and P. D. Coleman, App/. Opt. 10, 1683 (1971).<br />

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16. H. R. Philipp and H. Ehrenreich, in "Semiconductors and Semimetals" (R. K. Willardson<br />

and A. C. Beer, eds.), Vol. 3, Chapter 4. Academic, New York, 1967.<br />

17. M. Cardona, W. Gudat, B. Sonntag, and P. Y. Yu, Proc. Int. ConI Phys. Semicond. Cambridge,<br />

1970, p. 208. U.S. Atomic Energy Commission, Oak Ridge, Tennessee, 1970.<br />

18. M. Cardona, W. Gudat, E. E. Koch, M. Skibowski, B. Sonntag, and P. Yu, Phys. Rev.<br />

Lett. 25, 659 (1970).<br />

19. S. E. Stokowski and D. D. Sell, Phys. Rev. B 5, 1636 (1972).<br />

20. W. Gudat, E. E. Koch, P. Y. Yu, M. Cardona, and C. M. Penchina, Phys. Status Solidi<br />

B 52,505 (1972).<br />

21. G. Jungk, Phys. Status Solidi B 67,85 (1975).<br />

22. H. Welker, J. Electron. I, 181 (1955).<br />

23. B. O. Seraphin and H. E. Bennett, in "Semiconductors and Semi metals" (R. K. Willardson<br />

and A. C. Beer, eds.), Vol. 3, p. 219. Academic, New York, 1967.<br />

24. D. E. Aspnes and A. A. Studna, Phys. Rev. B 27, 985 (1983); D. E. Aspnes and A. A. Studna,<br />

private communication (1982).

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