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Investigation of the optically stimulated luminescence dating method ...

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Essentials <strong>of</strong> <strong>luminescence</strong> <strong>dating</strong> 9<br />

conditions <strong>of</strong> impurity content and heat treatment that a more complete picture can be<br />

obtained. Never<strong>the</strong>less, <strong>the</strong> main features <strong>of</strong> <strong>the</strong> mechanism by which <strong>luminescence</strong> is<br />

produced, and <strong>of</strong> how <strong>the</strong> phenomenon can be exploited for <strong>dating</strong> purposes, can be<br />

understood from <strong>the</strong> simplified representation given above. It can be added that o<strong>the</strong>r<br />

types <strong>of</strong> insulators (such as glasses), as well as semi-conductors also exhibit<br />

<strong>luminescence</strong>; metals, on <strong>the</strong> o<strong>the</strong>r hand, do not. For more complex and detailed accounts<br />

on <strong>the</strong> physical <strong>the</strong>ory, reference is made to McKeever (1985), Chen and McKeever,<br />

(1997) and Bøtter Jensen et al. (2003a).<br />

1.3. Signal growth and trap stability<br />

From <strong>the</strong> previous section it is clear that <strong>the</strong> intensity <strong>of</strong> <strong>the</strong> <strong>luminescence</strong> signal is<br />

proportional to <strong>the</strong> number <strong>of</strong> electrons trapped: <strong>the</strong> longer <strong>the</strong> irradiation time, <strong>the</strong> more<br />

electrons will have become trapped and <strong>the</strong> higher <strong>the</strong> <strong>luminescence</strong> intensity. There are<br />

however two limitations. First <strong>of</strong> all, <strong>the</strong> total number <strong>of</strong> traps that is available for storing<br />

<strong>the</strong> charge is limited. Consequently, under continuous irradiation, <strong>the</strong> available traps are<br />

gradually filled and eventually saturation will be reached. A second limitation is that<br />

electrons are also spontaneously evicted from <strong>the</strong>ir traps, a process which is termed<br />

‘<strong>the</strong>rmal fading’ (see later).<br />

Taking both effects <strong>of</strong> <strong>the</strong>rmal fading and saturation into account, <strong>the</strong> growth <strong>of</strong> <strong>the</strong><br />

<strong>luminescence</strong> intensity (I) as a function <strong>of</strong> time can be described by <strong>the</strong> following<br />

equation (Wagner, 1995):<br />

with:<br />

I (t)<br />

•<br />

= S×<br />

D × τ ×<br />

( 1 − e<br />

S = <strong>the</strong> sensitivity; <strong>the</strong> amount <strong>of</strong> <strong>luminescence</strong> per unit <strong>of</strong> dose<br />

•<br />

D = <strong>the</strong> dose rate; <strong>the</strong> dose received per unit <strong>of</strong> time<br />

τ = <strong>the</strong> apparent mean lifetime<br />

t = <strong>the</strong> time span <strong>of</strong> signal accumulation<br />

t<br />

−<br />

τ<br />

)<br />

(1.1)

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