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Investigation of the optically stimulated luminescence dating method ...

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– CHAPTER 2 –<br />

OSL FROM QUARTZ<br />

Quartz is <strong>the</strong> dosimeter that has been used throughout this work. This mineral was chosen<br />

because <strong>of</strong> its abundance in <strong>the</strong> sediments to be investigated, and because it has certain<br />

advantages with regard to microdosimetry and anomalous fading. Fur<strong>the</strong>rmore, over <strong>the</strong><br />

last seven years or so, considerable progress has been made in <strong>the</strong> understanding <strong>of</strong> its<br />

<strong>luminescence</strong> properties, through which it nowadays has become <strong>the</strong> preferred mineral for<br />

<strong>dating</strong> purposes. In this chapter, <strong>the</strong> key features <strong>of</strong> <strong>the</strong> quartz OSL signal are discussed.<br />

2.1. Stimulation <strong>of</strong> quartz<br />

A stimulation spectrum yields information on <strong>the</strong> efficiency by which a certain<br />

wavelength is able to stimulate a certain mineral. For instance, Hütt et al. (1988)<br />

discovered in this manner that infrared light could be used for stimulating feldspars, but<br />

not for quartz. Knowledge <strong>of</strong> <strong>the</strong> stimulation spectra is however not only important<br />

because it allows <strong>the</strong> selection <strong>of</strong> a specific mineral, but also for optimising <strong>the</strong><br />

stimulation wavelength to obtain a maximum light output.<br />

Bøtter-Jensen et al. (1994) investigated <strong>the</strong> stimulation efficiency <strong>of</strong> quartz at different<br />

wavelengths. They found an increase in signal intensity (I) with decreasing stimulation<br />

wavelength (increasing energy), as is shown in Figure 2.1. Stimulation spectra were also<br />

published by Ditlefsen and Huntley (1994; fur<strong>the</strong>r elaborated by Huntley et al., 1996) and<br />

Kuhn et al. (2000), with no significant differences. It can be seen in Figure 2.1 that <strong>the</strong>re<br />

is a slight change in response at around 500-520 nm. The reason for this “knee” is still<br />

poorly understood. The same observation was made by Kuhn et al. (2000) who,<br />

consequently, recommended avoiding stimulation with wavelengths in this region to<br />

minimize additional scatter in <strong>the</strong> <strong>luminescence</strong> output from identical samples.<br />

The stimulation spectrum also shows that practically no luminescent signal is to be<br />

expected when quartz is <strong>stimulated</strong> with infrared light. Spooner (1994b) also found that<br />

wavelengths greater than 690 nm are inefficient for stimulating a <strong>luminescence</strong> signal

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