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3 - International Joint Commission

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were 21 ppb (top 1 cm) and 5 ppb for HCBD (Charlton and Oliver, 1986). The<br />

concentrations of HCB and HCBD in Lake St. Clair are still increasing, or at<br />

least not dropping significantly (UGLCCS, 1989). High levels of HCB (up to<br />

140 ppb), were found in 1985 in the Detroit River adjacent to the Rouge<br />

River, in the Trenton Channel and at the mouth of the Detroit River but no<br />

major point sources have been identified (UGLCCS, 1989). A similar<br />

distribution was found in 1983 for total chlorobenzenes, except for a high<br />

concentration (3,500 ppb) west of Fighting Island (Kaiser et al., 1985).<br />

Mirex was not detected in Lake St. Clair in 1982 (Oliver and Bourbonniere,<br />

1985) or the Detroit River in 1980 (Hamdy and Post, 1985). Dioxins<br />

and furans were detected in sediment samples collected in the mid-1980s<br />

from the St. Clair River (DOE and MOE, 1985, 1986; UGLCCS, 1989). The<br />

highest concentrations were found in the Township ditch and the 1st Street<br />

sewer. The octa- and hepta- congeners predominated and 2,3,7,8-TCDD was<br />

not detected.<br />

A review of PCBs in St. Clair River sediments concluded that a<br />

temporal trend could not be assessed because of the variations in the studies<br />

(Pugsley et al., 1985). However, there was an increase in concentration at the<br />

Polysar-Dow area of the St-Clair River (on the Canadian shore), (DOE and<br />

MOE, 1986) (Figure 8). The maximum levels were considerably higher than<br />

the dredge spoil guideline of 0.05 ppm. Other areas where there is PCB<br />

contamination include the vicinity of Ontario Hydro's Lambton generating<br />

station on both sides of the river and in the Belle River (UGLCCS, 1989). The<br />

range of concentrations along the American shore was relatively low. Oliver<br />

and Bourbonniere (1985) did not detect an increase in the concentration of<br />

PCBs in sediments between southern Lake Huron and Lake St. Clair. In<br />

1982, mean concentrations of PCBs in Lake St. Clair sediments were much<br />

lower than those reported for western Lake Erie (Oliver and Bourbonniere,<br />

1985).<br />

The Detroit River is a major source of PCBs to Lake Erie (Oliver and<br />

Bourbonniere, 1985). PCBs enter the river from Lake St. Clair and there are<br />

several point sources along the river. In 1980, PCBs were found in 78% of<br />

the bottom sediment samples (Hamdy and Post, 1985). The highest<br />

concentrations (> 500 ppb) were found along the Michigan shore, south of<br />

Detroit. In 1982, the highest levels were found at the head of the river (Fallon<br />

40

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