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Module 1: Regulations - International Association of Fire Fighters

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IAFF Training for Hazardous Materials: Technician© Student Text<br />

Characteristics <strong>of</strong> Reactive Waste (D003)<br />

40 CFR 261.23 defines a reactive hazardous waste stream<br />

as follows:<br />

• Normally unstable and readily undergoes violent<br />

changes without detonating<br />

• Can react violently with other waste(s)<br />

• Forms potentially explosive mixtures with water<br />

• Generate toxic gases, vapors, or fumes when mixed<br />

with water that are a danger to human health or the<br />

environment<br />

• Cyanide or sulfide-bearing wastes which can generate<br />

toxic gases, vapors, or fumes when exposed to pH<br />

conditions between 2 and 12.5<br />

Examples <strong>of</strong> reactive hazardous wastes (D003) include:<br />

potassium cyanide; lithium aluminum hydride; and<br />

trimethylchlorosilane.<br />

Characteristic <strong>of</strong> Toxic Waste (D004-D043)<br />

EPA waste codes D004 through D043 have been designated<br />

to specific organic and inorganic chemicals that are toxic.<br />

The definition can be found in 40 CFR 261.24. The existence<br />

<strong>of</strong> pesticides, metals, and miscellaneous organic<br />

chemicals exceeding specified concentrations provide<br />

evidence <strong>of</strong> the characteristic toxicity. Toxicity is evaluated<br />

using the Toxicity Characteristic Leaching Procedure<br />

(TCLP). A solid waste that exhibits the characteristic <strong>of</strong><br />

toxicity has the EPA hazardous waste number specified in<br />

Table I which corresponds to the toxic contaminant causing<br />

it to be hazardous.<br />

1-74 <strong>Module</strong> 1: <strong>Regulations</strong>

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