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CEL Halogen-free - California Eastern Laboratories

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April 6, 2009<br />

TO:<br />

SUBJECT:<br />

All <strong>CEL</strong> Customers<br />

<strong>CEL</strong> <strong>Halogen</strong>-<strong>free</strong> Transition Plan<br />

To All <strong>CEL</strong> Customers:<br />

Thank you for your continued support of <strong>CEL</strong> products.<br />

In our ongoing efforts to offer green products and remain responsive to the global trend of substance<br />

regulations, we have taken steps to meet the restricted use of <strong>Halogen</strong>s in Consumer Electronics (e.g.<br />

IEC 61249-2-21).<br />

<strong>Halogen</strong> <strong>free</strong> devices are defined as containing chlorine (Cl)


(1) Product List Change from April, 2009 Appendix 1<br />

Si-Tr、FET Si-IC GaAs-LNFET GaAs-IC<br />

Part No. Part No. Part No. Part No.<br />

2SC5369 UPB1511TB NE3503M04 UPG2008TK<br />

2SC5507 UPC2708TB NE3508M04 UPG2009TB<br />

2SC5508 UPC2709TB NE3509M04 UPG2010TB<br />

2SC5509 UPC2710TB NE3509M14 UPG2012TB<br />

2SC5751 UPC2711TB NE3510M04 UPG2012TK<br />

2SC5753 UPC2712TB UPG2015TB<br />

2SC5754 UPC2745TB UPG2030TK<br />

2SC5761 UPC2746TB UPG2041TK<br />

NE5814M14 UPC2747TB UPG2134TB<br />

NE661M05 UPC2748TB UPG2151TK<br />

NESG2021M05 UPC2749TB UPG2155TB<br />

NESG2031M05 UPC2756TB UPG2156TB<br />

NESG2101M05 UPC2757TB UPG2179TB<br />

NESG3031M05 UPC2758TB UPG2189TB<br />

NESG3031M14 UPC2762TB UPG2214TB<br />

NESG3032M14 UPC2763TB UPG2214TK<br />

NESG3033M14 UPC2771TB UPG2304TK<br />

NESG4030M14 UPC2776TB UPG2310TK<br />

UPA800T UPC3215TB UPG2406TB<br />

UPA801T UPC3223TB UPG2406TK<br />

UPA802T UPC3224TB UPG2408TB<br />

UPA804T UPC3225TB UPG2408TK<br />

UPA806T UPC3226TB UPG2409TB<br />

UPA807T<br />

UPC3227TB<br />

UPA808T<br />

UPC3232TB<br />

UPA810T<br />

UPC3236TK<br />

UPA811T<br />

UPC3237TK<br />

UPA812T<br />

UPC3239TB<br />

UPA813T<br />

UPC3240TB<br />

UPA814T<br />

UPC8106TB<br />

UPC8112TB<br />

UPC8128TB<br />

UPC8151TB<br />

UPC8163TB<br />

UPC8172TB<br />

UPC8172TK<br />

UPC8178TB<br />

UPC8178TK<br />

UPC8179TB<br />

UPC8179TK<br />

UPC8181TB<br />

UPC8182TB<br />

UPC8187TB<br />

UPC8204TK<br />

UPC8211TK<br />

UPC8226TK<br />

UPC8231TK<br />

UPC8233TK<br />

UPD5710TK<br />

UPD5713TK<br />

UPD5745TK


(2) Product List Change from July, 2009 Appendix 2<br />

Si-Tr, FET<br />

Si-IC<br />

Part No. Part No. Part No.<br />

2SC5004 UPA828TD UPB1512TU<br />

2SC5005 UPA831TD UPB1513TU<br />

2SC5006 UPA841TD UPB1514TU<br />

2SC5007 UPA851TD UPC8215TU<br />

2SC5008 UPA854TD UPC8217TU<br />

2SC5010 UPA855TD UPC8230TU<br />

2SC5011 UPA859TD UPD5702TU<br />

2SC5012<br />

UPA860TD<br />

2SC5013<br />

UPA861TD<br />

2SC5015<br />

UPA862TD<br />

2SC5180<br />

UPA863TD<br />

2SC5181<br />

UPA869TD<br />

2SC5185<br />

UPA873TC<br />

2SC5186<br />

UPA873TD<br />

2SC5195<br />

UPA891TC<br />

2SC5431<br />

UPA891TD<br />

2SC5432<br />

UPA895TD<br />

2SC5433<br />

UPA901TU<br />

2SC5435<br />

2SC5436<br />

2SC5606<br />

2SC5614<br />

2SC5615<br />

2SC5617<br />

2SC5618<br />

2SC5667<br />

2SC5668<br />

2SC5674<br />

2SC5676<br />

2SC5704<br />

2SC5746<br />

2SC5750<br />

2SC5752<br />

2SC5787<br />

2SC5800<br />

2SC5801<br />

2SC5843<br />

3SK254<br />

3SK255<br />

NE662M03<br />

NESG2021M16<br />

NESG2031M16<br />

NESG204619<br />

NESG2101M16<br />

NESG210719


To Customers<br />

GET-SB-1653<br />

The Change of Mold Resin Material<br />

to <strong>Halogen</strong> Free<br />

for Microwave Devices<br />

March, 2009<br />

NEC Electronics Corporation<br />

Compound Semiconductor Devices Division<br />

Microwave Devices Sales Engineering Group<br />

1


Introduction<br />

This is to announce that NEC Electronics will change the mold<br />

resin material of microwave devices to environment-conscious<br />

type material, “<strong>Halogen</strong> Free”, according to the schedule.<br />

This pack of slides as a pamphlet is prepared for explanation<br />

about the detail of <strong>Halogen</strong> Free products.<br />

This pamphlet will help your better understanding about the<br />

change to <strong>Halogen</strong> Free.<br />

2


Notification of Change: Mold Resin of Microwave<br />

Devices for <strong>Halogen</strong> <strong>free</strong><br />

Cf. GTP-SB-2613 dated in February 2nd, 2009<br />

1. Description of changes:<br />

1)The package mold resin is changed to non-brominated flame retardants<br />

(<strong>Halogen</strong> Free Resin).<br />

2) NEC Electronics defines “halogen <strong>free</strong>” products by which the content<br />

of chlorine (Cl) and bromine (Br) in the package mold resin.<br />

3) The substrate fills following criteria.<br />

Bromine (Br)


The Background of the change to<br />

<strong>Halogen</strong> Free<br />

Serving “green products” to protect global environment is one<br />

of NEC Electronics’ important missions.<br />

Needs for environment-conscious operation have been raised.<br />

The plastic containing Bromine and Chlorine will produce toxic<br />

Dioxin with high possibility when they burn.<br />

It is the environmental pollutant.<br />

Due to above conditions, Bromine <strong>free</strong> and Chlorine <strong>free</strong> products<br />

are required.<br />

4


The Countermeasure for <strong>Halogen</strong> Free<br />

Which material in device would be contained halogen<br />

substances *1 ?<br />

*1: Chlorine and Bromine only.<br />

Mold Resin<br />

Silver Conductive Paste<br />

Mold Resin<br />

<br />

As flame retardants, bromine (Br) or<br />

antimony (Sb) is contained<br />

approximately 3%.<br />

<br />

Change to alternative flame retardants<br />

composed with metallic hydrate<br />

components (Aluminum compound)<br />

Silver Conductive Paste<br />

High purity silver conductive paste. (No need to change)<br />

‣The packing materials (e.g. reels, cartons, etc.) are out of the halogen-<strong>free</strong> subject<br />

5


Physicality of <strong>Halogen</strong> Free Resin<br />

Br/Sb flame retardants resin<br />

(Current)<br />

Metallic hydrate retardant resin<br />

(after Change)<br />

Principle<br />

of<br />

retardant<br />

Content<br />

Br or Sb react with the volatile portion<br />

of burning source<br />

Reduce high reactive volatile portion<br />

Decomposition of metallic hydrate is<br />

endothermic react.<br />

Restrain reaction by reducing<br />

heat for burning<br />

Around 3% 10~15%<br />

Flame<br />

Retardant<br />

grade<br />

UL94 V-0 UL94 V-0<br />

Flame retardant grade will be same.<br />

Inorganic phosphorus is not used in both “current” and “change” resins.<br />

6


Mechanism of Flame Retardant (Overview)<br />

Current Resin<br />

Heat decomposition<br />

of resin<br />

Production of<br />

Flammable gas<br />

Reduce<br />

Flammable gas<br />

<strong>Halogen</strong> Free Resin<br />

Burning Cycle<br />

Reaction<br />

by Br/Sb<br />

Reduce<br />

temp. rising<br />

Temp.<br />

Rising<br />

Ignition<br />

and<br />

Burn<br />

Endothermic<br />

by Metallic Hydrate<br />

Continuous burning can be prevented<br />

by breaking the chain of burning cycle.<br />

7


Contents of Environmental Pollutants<br />

in <strong>Halogen</strong> Free Products<br />

<strong>Halogen</strong> Free<br />

Compliant<br />

RoHS Compliant<br />

Cadmium<br />

Hexavalent Chrome<br />

Mercury<br />

Lead<br />

Bromine<br />

Chlorine<br />

Cd<br />

Cr 6+<br />

Hg<br />

Pb<br />

Br<br />

Cl<br />


No Impact by Resin Change<br />

• Result of reliability test:<br />

Humidity resistance, heat resistance and thermal<br />

cycle test were performed and evaluated.<br />

No impact was observed by changing the resin.<br />

• Electric Characteristics:<br />

There is no impact on electric characteristics<br />

by changing resin.<br />

MSL (Moisture Sensitive Level: Level 1) and flame<br />

retardant level(V-0) stay the same as non <strong>Halogen</strong><br />

Free products.<br />

The details are shown in followings.<br />

9


Reliability Test Results(1)<br />

1. Evaluation of Product<br />

Item<br />

Condition<br />

High Temp.<br />

High Temp.<br />

Burn in<br />

High Temp.<br />

High Humidity<br />

Pressure<br />

Cooker Test<br />

Thermal Cycle<br />

Ta=150 ºC 1000Hrs<br />

Tj=150 ºC, Vcc or Vdd=Recommended maximum<br />

voltage, 1000Hrs<br />

Ta=85 ºC, RH=85%, Vcc or Vdd=Recommended<br />

maximum voltage, 1000Hrs<br />

Ta=125 ºC, RH=100%, 96Hrs<br />

Ta=-55 - +150 ºC, 100 Cycles<br />

Saturated moisture absorption, Infrared reflow(260 ºC peak 3times)<br />

are performed as pretreatment for each test item.<br />

No defects are observed with above tests.<br />

These tests are performed by representative packages.<br />

10


Reliability Test Results(2)<br />

2. Evaluation of Material<br />

(1) Migration Test<br />

(2) Resin Mechanical Strength Test<br />

0.42mm<br />

Copper Frame<br />

0.32mm<br />

Silver Plating<br />

0.11mm<br />

0.16mm<br />

0.15mm<br />

20V<br />

PCT Bath<br />

Ta=125 ºC<br />

Rh=100%<br />

Dendrite growth was observed<br />

on neither copper nor silver at 1000Hrs<br />

Terminal pull out strength was<br />

the same as current resin.<br />

11


Evaluation Result of Electric Characteristics<br />

S11<br />

S22<br />

Evaluation Method:<br />

Compared two resin’s RF signal<br />

characteristics at the smallest pin<br />

pitch package of NEC Electronics.<br />

(Without Die)<br />

Measurement Condition<br />

Ta=25 ºC, Pin=0dBm,<br />

f=10MHz- 8.0GHz<br />

Test Equipment<br />

Equipment Maker Type No.<br />

S21<br />

S12<br />

Network<br />

Analyzer<br />

Agilent<br />

Technology<br />

E5071B<br />

Evaluated Package<br />

UPAxxxTS<br />

(6P SLM2 non-die package)<br />

Ref<br />

Ref<br />

Eva. Board<br />

Conclusion : There is no significant difference in small<br />

signal electrical characteristics between two resins.<br />

Port 1<br />

Port 2<br />

(Top View) (mm)<br />

12


Distinction of <strong>Halogen</strong> Free Products<br />

“Y” mark is printed in S/No. column on reel and packing carton box label.<br />

It expresses <strong>Halogen</strong> Free product.<br />

This S/No. is described as “Rank” on the data sheets of Si/SiGe Transistors<br />

and Twin Transistors.<br />

(1) One and two digit mark/rank<br />

Add “Y” as the first digit.<br />

Example “K” → “YK”<br />

“FB” → “YFB”<br />

(2) Three digit mark/rank<br />

The first digit is changed into “Y”<br />

Example “R29” → “Y29”<br />

“79M” → “Y9M”<br />

Some package categories will not be printed “Y” mark in S/No. column<br />

even though they are halogen <strong>free</strong> products. These packages were originally<br />

designed without <strong>Halogen</strong>. Please see below package suffix.<br />

Total 24 packages as of 1st/Feb/2009<br />

T5F,T5J,T5K,T5L,T5M,T5N,T5R,T5S,T5T,T5X,T5Y,T5Z,<br />

T6A,T6C,T6E,T6J,T6L,T6M,T6N,T6Q,T6R,T6S,T6U,M06<br />

Example :UPG2150T5L<br />

NE3561M06<br />

13


Example of Label<br />

Label of Reel<br />

Current Label<br />

Changed<br />

Product Label<br />

14


Shipping Specification<br />

The “Rank” is described on the shipping specifications of Si/SiGe<br />

Transistors and Twin Transistors.<br />

If you need the revised shipping specifications, please request to<br />

our sales.<br />

15

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