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Testing and quality

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SULZER INNOVATION<br />

The ideal solution for corrosive media<br />

The new Sulzer KnitMesh XCOAT™ mist eliminator<br />

combines the chemical resistance of fluoropolymers<br />

with the strength <strong>and</strong> form stability of alloys. Thus,<br />

the Sulzer KnitMesh XCOAT mist eliminator sets a<br />

new dimension in contact with strong acids, especially<br />

in applications involving sulfuric <strong>and</strong> acetic acid.<br />

In many applications, droplets need to<br />

be efficiently separated from a gas<br />

stream in order to avoid problems or<br />

damages in downstream processes. For<br />

applications with severe process conditions<br />

involving corrosive liquids, special<br />

resistant materials are required. Suitable<br />

materials are characterized by a high<br />

corrosion resistance in a wide range of<br />

operating conditions <strong>and</strong> a long lifetime<br />

of service.<br />

Sulfuric acid production process<br />

Sulfuric acid is a chemical compound<br />

of sulfur with the formula H2SO4. It<br />

is a colorless, oily, very viscous, <strong>and</strong><br />

hygroscopic liquid. It is one of the<br />

strongest acids <strong>and</strong> is highly corrosive.<br />

Sulfuric acid is one of the most<br />

important chemicals in general <strong>and</strong><br />

one of the most-produced commodity<br />

chemicals.<br />

The new Sulzer KnitMesh XCOAT mist eliminator.<br />

Sulfuric acid is produced from sulfur<br />

dioxide (SO2), which is oxidized to sulfur<br />

trioxide (SO3). This is reacted with water<br />

in concentrated sulfuric acid to sulfuric<br />

acid.<br />

Drying column in the sulfuric acid<br />

production<br />

The gas stream to <strong>and</strong> from the reactor<br />

is, in direct contact with concentrated<br />

sulfuric acid, dehydrated in order to<br />

prevent corrosion caused by wet SO2 or<br />

SO3 gas as well as to avoid condensation<br />

of acid during plant shutdowns, which<br />

would damage the catalyst in the reactor.<br />

Therefore, to avoid corrosion, the<br />

columns are either made of special high<br />

alloy steels or lined with acid- <strong>and</strong> heatresistant<br />

bricks.<br />

Droplet in the drying column<br />

At the top of the drying column, a mist<br />

eliminator is installed so that no droplets<br />

are entrained to the downstream process.<br />

Sulzer Chemtech markets wire mesh<br />

mist eliminators with the trademark<br />

KnitMesh. A KnitMesh mist eliminator<br />

is knitted from wires or fibers.<br />

The strengths of the KnitMesh<br />

XCOAT mist eliminator<br />

Mist eliminators in sulfuric acid drying<br />

columns require high-grade materials.<br />

Particularly concerned are the knitted<br />

mesh pads with their thin wires which<br />

are most sensitive for corrosion. Therefore,<br />

alloys that are optimized to prevent cor-<br />

Close-up image of XCOAT:<br />

Thin metal wire coated with 100%<br />

pure PTFE (polytetrafluoroethylene).<br />

rosion caused by sulfuric acid are<br />

applied. Alternatively, synthetic fibers,<br />

in some cases in combination with metal<br />

wires, are used.<br />

However, the above alloys do not<br />

completely prevent corrosion, which is<br />

why the lifetime is limited. Mist eliminators<br />

using fluoropolymer fibers show,<br />

indeed, an excellent chemical resistance,<br />

but at higher temperatures they tend<br />

to shrink, which leads to bypasses in<br />

the mesh pad.<br />

In the Sulzer KnitMesh XCOAT mist<br />

eliminator, the strength <strong>and</strong> form<br />

stability of a metal wire are ideally<br />

combined for the first time with the<br />

chemical resistance of fluoropolymers. A<br />

thin metal wire coated with 100% pure<br />

PTFE, the best known chemical- <strong>and</strong><br />

temperature-resistant plastic, shows a<br />

longer service time in hot corrosive<br />

media than wires from special alloys or<br />

fibers from fluoropolymers. Thus, the<br />

Sulzer KnitMesh XCOAT mist eliminator<br />

sets a new dimension in contact with<br />

strong acids.<br />

The Sulzer KnitMesh XCOAT mist<br />

eliminator is now exclusively available<br />

to our customers from Sulzer Chemtech.<br />

Daniel Egger<br />

For more information or to express your interest,<br />

please contact:<br />

Rohit N. Joshi<br />

Sulzer Chemtech India, Pune<br />

Phone +91 2137 304740<br />

rohitn.joshi@sulzer.com<br />

4334 Sulzer Technical Review 1/2011 | 25

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