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chemia - Studia

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ANDRA TĂMAŞ, MARTIN VINCZE<br />

2%B + 98% sol.1<br />

35<br />

30<br />

a<br />

P<br />

,<br />

s<br />

t<br />

re<br />

s<br />

25<br />

r<br />

a<br />

e<br />

h<br />

S<br />

20<br />

15<br />

0 20 40 60 80 100 120 140 160<br />

Shear rate, s -1<br />

after 1 hour after 10 days after 30 days<br />

Figure 5. Dependence τ = f (γ ) for sample PC 2 (t=32°C)<br />

3. The influence of the amphiphilic surfactant VB<br />

For samples PA 3-9 , PA 3-10 and PA 3-12 , in Figure 6, is shown the τ = f (γ&<br />

)<br />

dependence, and the evolution of apparent viscosity with amphiphilic<br />

surfactant content is shown in Figure 7. From the obtained rheological<br />

equations (Table 6) is observed the non-Newtonian behavior specific to<br />

yield-pseudoplastic fluids, and the increase of apparent viscosity with<br />

increasing the concentration of amphiphilic component, respectively.<br />

&<br />

3%VAD; t=25 o C<br />

40<br />

35<br />

30<br />

Shear stress, Pa<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

0 200 400 600 800 1000 1200 1400<br />

Shear rate, s -1<br />

9%VB 10%VB 12%VB<br />

Figure 6. Dependence τ = f (γ&<br />

) for PA 3-9 , PA 3-10 and PA 3-12<br />

252

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