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Session A5<br />

Paper #3204<br />

ENGINEERED CEMENTITIOUS COMPOSITES: APPLICATIONS AND<br />

IMPACT OF HIGH TENSILE, SELF-HEALING CONCRETE<br />

Jayne Marks (jam347@pitt.edu, Vidic 2:00), Jon Conklin (jjc105@pitt.edu, Vidic 2:00)<br />

Abstract— <strong>Engineered</strong> <strong>Cementitious</strong> Composite, or ECC, is<br />

a unique type of cement mixture that was initially developed<br />

by Victor Li at the University of Michigan in 2001 [1]. It<br />

improves upon current concrete mixes and Fiber Reinforced<br />

Concrete (FRC) types due to its “unique composition of low<br />

volume fibers and variable composites,” that give it a high<br />

tensile strength and the ability to repair itself [2]. The<br />

concrete mix was created based mainly on the interactions<br />

between the microfibers included in the mixture and the<br />

other materials present (the matrix). These interactions<br />

create flat steady state cracking of the concrete when under<br />

stress [3]. This type of cracking better protects the concrete<br />

from the introduction of solvents and corrosive elements<br />

while also promoting the reactions that cause self-healing,<br />

and these properties are what set <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite apart from the concrete currently in use today.<br />

The improvement to concrete <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite displays has many societal applications that can<br />

help improve the current state of the world’s structures<br />

including longer lasting infrastructure, less repair costs, and<br />

more versatile physical properties of structures it is used in<br />

[4].<br />

This paper will discuss experiments performed to test<br />

tensile strength, compression resistance, and shrinkage of<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite concrete based on<br />

variations in the composite make up of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite that cause it to differ from other<br />

concretes and Fiber Reinforced Concretes in the areas of<br />

ductility, durability, permeability, and other important<br />

properties. It will also explore the benefits of application to<br />

society and economic advantages while also taking into<br />

account environmental impacts and cost by citing specific<br />

examples of <strong>Engineered</strong> <strong>Cementitious</strong> Composite use in<br />

society today; such as seismic dampening support columns<br />

in skyscrapers of Japan, or dam overlay repair.<br />

Key Words— Cement, Concrete, ECC, <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite, Fiber Reinforced Concrete, Victor<br />

Li<br />

CONCRETE AS IT STANDS<br />

Concrete is the most widely used construction material in<br />

the world [5]. Not only is it used on highways and<br />

buildings, concrete is a vital component of many other<br />

structures necessary for the function of society such as<br />

underground transit, wastewater treatment, marine<br />

structures, and bridges. Every year, the use of concrete for<br />

construction projects globally exceeds 12 billion tons [2]. To<br />

put that into perspective, there are roughly 7 billion people<br />

on the planet, averaging out to 1.7 tons of concrete per<br />

person used each year Concrete is one of the most<br />

prominently used construction resources, yet the main types<br />

of concrete in use tend to have major issues that hinder their<br />

performance. Concrete is fundamentally a mixture of<br />

aggregates and paste. The aggregates are sand and gravel or<br />

crushed stone; the paste is water and Standard Portland<br />

cement. When the average person thinks of concrete, this<br />

basic mixture is typically what they are thinking of.<br />

However, this particular type of concrete has drawbacks that<br />

make it a less than ideal choice for such an important<br />

resource. This traditional concrete may be strong initially,<br />

but it tends to be very brittle and cracks easily under<br />

mechanical and environmental loads [5]. The cracks that<br />

develop tend to be very large, allowing sulfates and<br />

corrosive agents to permeate through and damage any inner<br />

steel structures the concrete may be covering. In the event<br />

of a catastrophe such as an earthquake, a damaged section of<br />

concrete could be the difference between a building standing<br />

or collapsing.<br />

For this reason, it is necessary to consider an ideal<br />

concrete mixture that would retain the strength of basic<br />

concrete, while better handling the stresses of the<br />

environment that these types of structures experience on a<br />

daily basis. This ideal concrete would need to be ductile, or<br />

able to deform under tensile stress, so it would not crack and<br />

crumble under mechanical loads, but it would have to retain<br />

a large tensile (or bending) strength. The concrete should not<br />

be easily permeated so the infrastructure is kept away from<br />

harmful chemicals, and it should also be easily repaired if<br />

damage is sustained.<br />

One improvement that has been used commercially since<br />

the 1900s is the addition of small fibers, usually made of<br />

steel or glass, to the concrete mixture. This addition<br />

increases the bending strength of the material due to the<br />

flexible nature of the fibers. These concretes are known as<br />

Fiber Reinforced Concrete (FRC), and while this does solve<br />

some of the problems presented by regular concrete, it was<br />

not until 2001 that an ideal concrete solution was developed.<br />

This new MIXTURE incorporates the strength of regular<br />

concrete with the flexibility of Fiber Reinforced Concrete. It<br />

also exhibits a rather useful quality that far exceeded the<br />

ability of the other two options. This concrete mixture is<br />

called <strong>Engineered</strong> <strong>Cementitious</strong> Composite (ECC): the<br />

strong, flexible, and self-healing concrete [3].<br />

WHAT IS ENGINEERED CEMENTITIOUS<br />

COMPOSITE?<br />

University of Pittsburgh<br />

Swanson School of Engineering March 7, 2013<br />

1


Jayne Marks<br />

Jon Conklin<br />

According to a research article published by the<br />

University of Michigan Transportation Research Record,<br />

“<strong>Engineered</strong> <strong>Cementitious</strong> Composite is “a special type of<br />

high performance fiber reinforced concrete containing a<br />

small amount of short random fibers micromechanically<br />

designed… to achieve high damage tolerance under severe<br />

loading and high durability under normal service conditions”<br />

[5]. It was developed in 2001 by Dr. Victor Li at the<br />

University of Michigan. However, <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite is no longer confined to the academic research<br />

laboratory; it is finding its way into precast plants,<br />

construction sites, and repair and retrofitting jobs in<br />

countries including Japan, South Korea, Australia,<br />

Switzerland, Canada, and the United States [4]. What<br />

makes <strong>Engineered</strong> <strong>Cementitious</strong> Composite different from<br />

other regular and fiber reinforced concretes are the unique<br />

properties associated with its specially tailored composites.<br />

These properties include a smaller crack width, superior<br />

tensile strength, significantly higher ductility, self-healing<br />

properties, and low fiber volume [5]. All of these properties<br />

contribute to improving the safety, strength, and<br />

sustainability of the structures it’s implemented into.<br />

CHARACTERISTICS AND PROPERTIES<br />

OF ENGINEERED CEMENTITIOUS<br />

COMPOSITE<br />

The introduction and application of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite would be pointless without the very<br />

specific qualities and strengths that it exhibits. These special<br />

qualities are based upon its material make up and the<br />

interactions with the surrounding environment it<br />

experiences. The characteristics break down into the<br />

physical strength and interactions that <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite undergoes, along with the chemical<br />

reactions and properties that allow the process of selfhealing<br />

to occur. These physical properties include<br />

remarkable tensile (or bending) strength and ductility, which<br />

allow for one of the more important interactions in the<br />

concrete itself: micro-cracking. The process of microcracking<br />

exponentially increases the tensile strength and<br />

remains within a low degree of permeability. This low<br />

permeability reduces the effects associated with the<br />

absorption of chemicals which include the weakening of any<br />

underlying support structures and erosion of the concrete<br />

itself [4]. This increases the lifespan and repair cycle of the<br />

concrete and the structure as a whole, while also creating the<br />

conditions that allow specific chemical reactions to occur<br />

that help to fill in the cracks of the concrete.<br />

Physical Properties and Stress Interactions of<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite concrete exhibits<br />

many natural, physical qualities that allow it to be applied in<br />

place of standard fiber reinforced concrete as a more<br />

dependable, long-term replacement. These characteristics<br />

include its low permeability along with high tensile strength,<br />

flexibility, and resistance to corrosion and spalling, or the<br />

fragmentation of the concrete under stress [3].<br />

When stress is introduced to a sample of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite, the major transfer of this stress is<br />

through the formation of micro-cracks in response to a<br />

tensile strain. The nature of these cracks is different from<br />

that of the cracks seen on other fiber reinforced concretes<br />

due to the fact that flat steady state micro-cracks are formed<br />

as opposed to localized Griffith crack propagation [3]. The<br />

former of the stress responses is ideal because when this<br />

type of micro-cracking occurs, it forms multiple, uniform<br />

cracks over a small area, whereas Griffith crack propagation<br />

forms large jagged cracks that are localized and harmful to<br />

the strength and permeability of the concrete. Under the<br />

conditions of steady state flat crack propagation, a process<br />

known as plasticity occurs where the material strength is<br />

higher after the first crack is formed and increases linearly to<br />

the final tensile strength factor. These cracks in <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite then follow simple formulae of<br />

crack potential and width that allows <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite to form smaller crack widths.<br />

These equations used to predict things such as crack width,<br />

strength, length, and flexibility can be found below.<br />

P=(ε sh -(ε e +ε cp +ε i )) (1)[3]<br />

This equation demonstrates that as the sum of the elastic<br />

tensile strain capacity (ε e ), tensile creep strain (ε cp ), and<br />

strain capacity (ε i ) increase or decrease relative to the<br />

shrinkage strain (ε sh ), the cracking potential (P) will increase<br />

or decrease respectively.<br />

L ch =EG f /σ t<br />

2<br />

(2)[3]<br />

This equation demonstrates that as the tensile strength (σ t )<br />

increases or decreases relative to the product of the Young’s<br />

modulus (E) and the fracture energy (G f ), the Hillerborg’s<br />

material characteristic length (L ch ) will decrease or increase<br />

respectively.<br />

W=L(P/(1-L/2L ch ) (3)[3]<br />

In equation 3, crack width (W) is proportional to the<br />

product of the crack length (L) and the crack potential<br />

divided by the crack length minus one divided by the<br />

Hillerborg’s material characteristic length. This relates that a<br />

larger cracking potential will result in a greater crack width<br />

which is shown to be the opposite for <strong>Engineered</strong><br />

<strong>Cementitious</strong> <strong>Composites</strong>.<br />

University of Pittsburgh<br />

Swanson School of Engineering March 7, 2013<br />

2


Jayne Marks<br />

Jon Conklin<br />

These equations also show that when cracking potential<br />

(P) is greater than or equal to zero, a single crack forms in<br />

the concrete with a proportional width (W) and the material<br />

will have a larger strain capacity as the number of cracks<br />

increases until the strain capacity value reaches an ultimate<br />

tensile strength. <strong>Engineered</strong> <strong>Cementitious</strong> Composite has a<br />

large strain capacity of about five percent (500 times that of<br />

standard concrete), and an extremely low chance of the<br />

formation of localized fracture damage [3].<br />

The formation of these micro-cracks creates a unique<br />

resistance to the absorption of water and chloride ions which<br />

pose the greatest threat to the underlying structure of any<br />

reinforced concrete. Through experimentation and analysis,<br />

it was determined that <strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

exhibits crack width well under the threshold of permeability<br />

for water and chloride ions under accelerated corrosion<br />

testing. When compared to that of normal concrete over a 14<br />

week freeze thaw cycle, the traditional concrete was<br />

deteriorated at such a rapid rate, that it was removed from<br />

testing after five weeks. The <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite sample went on to complete the 14 weeks with<br />

no degradation of the surface or strength. Similarly, a 26<br />

week test of <strong>Engineered</strong> <strong>Cementitious</strong> Composite was<br />

conducted in a high temperature and alkaline environment,<br />

which, when complete, showed that the <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite dropped in tensile strain from 4.5%<br />

to 2.75%. While this seems to show a significant degradation<br />

in the concrete, similar traditional concretes are still 250<br />

times weaker in comparison [6].<br />

Material makeup of <strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

also plays a part in the properties of strength and<br />

micromechanical interactions. The introduction of certain<br />

composites to the mix of <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite results in a greater compressive and tensile<br />

strength, while also increasing the bond strength between the<br />

underlying structure and the concrete [4]. The increase in<br />

compressive and tensile strength means that <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite is able to experience large axially<br />

directed pushing forces and lateral stretching or pulling<br />

forces without showing serious deformation or sharp breaks.<br />

This ductility is similar to that seen in metals. The flexibility<br />

of the material can be seen in Figure 1 below.<br />

FIGURE 1<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite’s flexibility<br />

exemplified [7]<br />

This has been experimented on multiple times and has<br />

reached a point of customization to the project that would<br />

allow a longer period between repairs than is already<br />

expected for similar applications of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite. One such experiment consisted of<br />

the addition and substitution of different proportion of glass<br />

beads to specifically form a lightweight, coarse aggregate<br />

that would lower the density in a uniform manner. This<br />

customized, lightweight version of <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite showed significant improvement in tensile and<br />

compressive strength, while allowing for a product that<br />

provided 40 MPa (mega-Pascal) of compressive strength and<br />

4MPa of tensile strength on average (much higher than other<br />

concretes) [8]. However, the cost and practicality of certain<br />

mixtures is regarded as a serious factor to consider when<br />

application of <strong>Engineered</strong> <strong>Cementitious</strong> Composite is<br />

compared to that of standard fiber reinforced concretes.<br />

Along with this same experiment, a sample that had a<br />

density of .93 g/cm 3 , less than that of water, was deemed<br />

acceptable for application in seismic dampeners with a<br />

tensile strength of 2.85MPa and a compressive strength of<br />

28.1MPa [8]. This relationship shows that at a certain point,<br />

the relationship between density and the strength of<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite will drop to a point that<br />

resembles the compressive strength of standard concrete<br />

while retaining the tensile properties that makeup the major<br />

benefits of the application of <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite.<br />

Chemical Interactions of Self-Healing <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite<br />

While the durability of <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite is due to a low permeability and diffusion rate,<br />

along with a high tensile and compressive strength, the long<br />

lifespan is also due to a chemical process of self-healing that<br />

occurs inside the micro-cracks of the concrete. During the<br />

early stages of cracking (fewer than fifty micrometers), the<br />

concrete will engage automatically in a self-healing reaction<br />

University of Pittsburgh<br />

Swanson School of Engineering March 7, 2013<br />

3


Jayne Marks<br />

Jon Conklin<br />

that will mechanically fill in the micro-cracks. It takes place<br />

directly in the crack and under a multitude of environmental<br />

conditions ranging from freezing-thawing cycles to chloride<br />

submersion which allows the self-healing to be dependable<br />

in real life applications. This process of self-healing stems<br />

from the carbonation of the calcium in the cement matrix,<br />

but only occurs in the presence of specific acidity levels of<br />

the water and calcium ion concentration at the crack surface.<br />

As water moves more slowly through cracks of a smaller<br />

width, as opposed to quickly through larger cracks in regular<br />

Fiber Reinforced Concretes, pH levels will rise as carbonate<br />

precipitation occurs. This reaction is shown in equation<br />

number 4 below [3].<br />

Ca2 + + HCO 3<br />

-<br />

CaCO 3 +H + (7.58) (4)[3]<br />

As the water, which contains carbon dioxide, penetrates<br />

the pores of hardened cement paste even deeper, it dissolves<br />

additional calcium ions from the calcium hydroxide. This<br />

then raises the pH value of the solution even more towards<br />

the ideal pH creating a more favorable environment for the<br />

self-healing process. The formation of CaCO 3 is the<br />

compound that will ultimately fill in the micro-cracks in<br />

which the reaction is occurring.[3]<br />

Experimentation has shown that a sample of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite put under tensile strain and then<br />

subject to three wet dry cycles, will successfully fill a one<br />

hundred micrometer crack with calcium carbonate crystals.<br />

Additional testing in this experiment also showed that the<br />

introduction of fly ash to the <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite mixture would decrease average crack width to<br />

around ten micrometers, thus promoting a quicker and more<br />

filled self-healing sample [9]. The results of this experiment<br />

can be seen in Figure 2.<br />

FIGURE 2<br />

The process of self-healing that <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite undergoes during this time has little effect on the<br />

tensile strength of the concrete: lowering the overall strength<br />

from 4.5% to 3%, a value well beyond that of standard fiber<br />

reinforced concrete [3]. Along with this, the introduction of<br />

additives such as fly ash (an industrial waste resulting from<br />

coal-fired thermoelectric power generation) to <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite would allow it to be applied to<br />

situations where a more consistent self-healing process<br />

would be observed. Certain other additives create different<br />

customized properties of <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite, including the ability to be sprayed as a much<br />

lighter material, higher tensile strength, or higher<br />

compressive strength. These various forms of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite make it much more applicable to<br />

various commercial needs.<br />

APPLICATIONS OF ENGINEERED<br />

CEMENTITIOUS COMPOSITE AND ITS<br />

AFFECTS ON SOCIETY<br />

The many positive qualities of <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite have been repeatedly exemplified in a laboratory<br />

setting, but the superior physical characteristics also pose<br />

many benefits to society through application. <strong>Engineered</strong><br />

<strong>Cementitious</strong> <strong>Composites</strong> pave the way for many possible<br />

improvements to the current standing of concrete, and in<br />

some cases, <strong>Engineered</strong> <strong>Cementitious</strong> Composite has already<br />

been implemented in construction projects. These cases<br />

exhibit structures that are more resilient and less susceptible<br />

to damages. Because sustainability is the capacity to endure,<br />

the more durable and longer lasting structures associated<br />

with the use of <strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

contribute not only to the sustainability of the world’s<br />

infrastructure, but also to a reduction in maintenance and<br />

repair costs, a better environmental impact, and an overall<br />

improvement of the safety of structures constructed with<br />

concrete.<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite a) before healing and<br />

b) after healing [9]<br />

Cost/Benefit Analysis<br />

When comparing costs of <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite and regular concrete, it is important to not only<br />

look at the initial manufacturing cost of the product, but to<br />

also consider the cost over the span of the concrete’s<br />

lifetime. If the initial costs are compared, regular concrete<br />

does exhibit a lower starting value (about three times less<br />

than <strong>Engineered</strong> <strong>Cementitious</strong> Composite), but this initial<br />

benefit comes at the price of quality [7]. The prices may<br />

differ in favor of regular concrete, but the long term<br />

financial benefits are substantial enough to drive the market<br />

in favor of <strong>Engineered</strong> <strong>Cementitious</strong> Composite. The reason<br />

for the gap in startup price arises from the composition of<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite. Unlike regular cement,<br />

University of Pittsburgh<br />

Swanson School of Engineering March 7, 2013<br />

4


Jayne Marks<br />

Jon Conklin<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite contains tiny fibers that<br />

drive up the price of production, and while other Fiber<br />

Reinforced Concrete’s use steel fibers, <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite typically uses more expensive<br />

poly-vinyl alcohol (PVA) fibers. These are fibers made from<br />

poly-vinyl alcohol or a type of plastic [3]. These PVA fibers<br />

are more expensive to use, but they weigh considerably less<br />

than the steel or glass fibers used in ordinary Fiber<br />

Reinforced Concrete Similarly, <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite has an extremely low fiber volume compared<br />

with other Fiber Reinforced Concrete. Both of these factors<br />

reduce the weight of <strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

compare to other Fiber Reinforced Concrete, and because it<br />

is typical to price concrete based on mass, it is possible that<br />

using <strong>Engineered</strong> <strong>Cementitious</strong> Composite could be cheaper<br />

than Fiber Reinforce Concrete. However both are still<br />

considerably more expensive than basic concrete which<br />

includes no fibers. In order to lower the cost of <strong>Engineered</strong><br />

<strong>Cementitious</strong> composite, the expensive cement that is used<br />

in the mixture to make the paste component of the concrete<br />

can easily be replaced with a less expensive alternative such<br />

as fly ash. This substitution would cause no drastic changes<br />

in function [10, 2]. The practice of adding fly ash has<br />

already been implemented and has been shown to include<br />

benefits other than cost reduction such as less environmental<br />

pollution. The cost of manufacturing <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite may be high, but in the long term,<br />

the concrete proves to help reduce expenses.<br />

The main long term financial benefit of using <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite is the reduction of the maintenance<br />

costs when compared to regular concrete. Because<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite is much more sturdy,<br />

less brittle, more flexible, and self-healing, it requires repairs<br />

less frequently than other concretes. The brittle nature of<br />

regular concretes leads to “repeated cycles of short-term<br />

repair scenarios which result in increased consumption of<br />

repair materials and fuels”[10]. Dr. Victor Li stated that “a<br />

bridge built with traditional concrete will average $350,000<br />

a year in maintenance, user, and environmental costs –its so<br />

called “life-cycle cost”—over 60 years. The same bridge, if<br />

built with [<strong>Engineered</strong> <strong>Cementitious</strong> Composite], ought to<br />

have a 50% lower life-cycle cost. That would add up to a<br />

savings of $11 million, potentially justifying the much<br />

higher initial price tag.”[7]. Similarly, structures in better<br />

condition mean less financial repercussions for those using<br />

them. Currently 32% of US major roads are in poor or<br />

mediocre condition [2]. Driving on these roads costs drivers<br />

an average of $22 extra per driver in vehicle operating costs<br />

each year totaling $41.5 billion. The implementation of<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite would save money in<br />

the long term, and that compensates for any discrepancy<br />

between initial manufacturing costs of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite, Fiber Reinforced Concrete, and<br />

regular concrete.<br />

Practical Applications of <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite<br />

The superiority of <strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

not only financially, but in overall quality and performance,<br />

has caused the beginnings of implementation to the<br />

commercial concrete business. <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite has been used in a skyscraper in Japan, a mall in<br />

Canada, and a bridge in Michigan. In the specific case of the<br />

bridge, <strong>Engineered</strong> <strong>Cementitious</strong> Composite was used as a<br />

link slab to connect portions of the bridge deck as seen in<br />

Figure 3.<br />

FIGURE 3<br />

Section of Michigan bridge replaced by <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite [6]<br />

Bridges experience necessary movement such as<br />

expansion and contraction due to temperature, vehicle loads,<br />

and settlement. It must be able to withstand all of these<br />

stresses, while also exhibiting good riding quality and<br />

minimal noise. Normally, sections of the bridge deck are<br />

connected using mechanical expansion joints, however,<br />

these metal joints can easily fall into disrepair and begin to<br />

deteriorate the bridge structure itself. In the case of the<br />

bridge in Michigan, the four span simply supported steel<br />

girder bridge with a nine-inch thick reinforced concrete deck<br />

constructed in 1976 underwent construction to replace the<br />

deck and include an <strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

slab. This was the initial implementation of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite. Two days after patching, the<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite showed no visible<br />

cracking, yet the concrete patch had a clearly visible crack<br />

approximately 300mm wide. Ten months after patching, the<br />

maximum <strong>Engineered</strong> <strong>Cementitious</strong> Composite crack width<br />

was 50μm while the section of concrete was described as<br />

“severely deteriorating.” Five winters after installation, the<br />

concrete needed re-repaired, but the <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite still only showed small cracks [10].<br />

The reason for this difference in performance is due to the<br />

flexibility of the <strong>Engineered</strong> <strong>Cementitious</strong> Composite. It is<br />

better able to handle the thermal expansion and contraction<br />

of the bridge. Also, the micro-cracks that do develop are<br />

either self-healed or small enough to not affect the<br />

functioning of the bridge.<br />

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Jon Conklin<br />

This unique outperformance is the case for all examples<br />

of <strong>Engineered</strong> <strong>Cementitious</strong> Composite application. Because<br />

it can be cast, extruded (pushed through a die of desired<br />

shape and cross sectional area), or sprayed, and has unique<br />

self-healing capabilities, <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite is a good choice for a long lasting repair material.<br />

In an experiment involving damaged concrete beams that<br />

were repaired with <strong>Engineered</strong> <strong>Cementitious</strong> Composite, it<br />

was found that <strong>Engineered</strong> <strong>Cementitious</strong> Composite actually<br />

increased the tensile strength of the beam to levels higher<br />

than the original, undamaged beam [11]. This can be seen in<br />

Figure 4 below.<br />

from Portland cement, and hot mixed asphalt (HMA) on<br />

important environmental statistics.<br />

FIGURE 5<br />

FIGURE 4<br />

Energy use for regular concrete, <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite, and HMA (hot mix asphalt) compared [2]<br />

FIGURE 6<br />

Regular concrete beam (left) compared to <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite beam (right) during a strength<br />

loading experiment [4]<br />

Although <strong>Engineered</strong> <strong>Cementitious</strong> Composite has a<br />

higher price than regular concrete, using even small amounts<br />

to repair beams, dams, bridges, and other construction<br />

projects or to coat undamaged structures is an investment in<br />

the stability of the structure. This creates a more sustainable<br />

building material, reduces the price of repairs and the<br />

amount of materials used for repairs, and helps to lower the<br />

negative impact on the environment<br />

Sustainability and Environmental Impact of <strong>Engineered</strong><br />

<strong>Cementitious</strong> <strong>Composites</strong><br />

“Cement is responsible for 3% of global greenhouse gas<br />

emissions.” Every time 1 ton of cement is produced, 1 ton<br />

of CO 2 is released as well [2]. When structures like roads are<br />

built with regular cement, they need to be repaired more<br />

frequently. This uses more cement which releases more<br />

greenhouse gases into the atmosphere. While a road is being<br />

repaired, the traffic in that area increases due to<br />

constructions and road closings. This congestion leads to<br />

increased fuel use and emissions [2]. Using <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite can help to slightly decrease this<br />

environmental impact which improves the overall<br />

sustainability of the project. Figures 5 and 6 compare<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite, concrete made only<br />

Carbon Dioxide production due to concrete, <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite, and HMA (hot mix asphalt<br />

compared) [2]<br />

These figures demonstrate the decrease in energy use and<br />

CO 2 emissions that can be achieved by using <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite, however, there is still room for<br />

improvement.<br />

The current accepted mixture of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite includes a significant amount of<br />

cement so the adverse environmental effects associated with<br />

this material are still present in <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite. However, by substituting this with industrial<br />

waste such as sands, kiln dust, and fly ash, the<br />

environmental effects of the cement production would be<br />

reduced while also disposing of waste. “70% of <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite’s composites may be replaced<br />

without reducing critical mechanical performance<br />

characteristics [10].” Also, as stated previously, the fly ash<br />

would not only lessen the negative environmental impacts of<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite manufacturing, it may<br />

also help to facilitate self-healing reactions better than in<br />

regular <strong>Engineered</strong> <strong>Cementitious</strong> Composite mixtures.<br />

Because sustainability is the ability of a process,<br />

method, or structure to endure over time and to support the<br />

endurance of society, the reduction of negative<br />

University of Pittsburgh<br />

Swanson School of Engineering March 7, 2013<br />

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Jayne Marks<br />

Jon Conklin<br />

environmental impacts, the increase in the life-span of<br />

structures using <strong>Engineered</strong> <strong>Cementitious</strong> Composite, and<br />

the decrease in the amount of resources needed to repair<br />

these structures all show that <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite is a sustainable alternative to regular concrete<br />

Using <strong>Engineered</strong> <strong>Cementitious</strong> Composite as a commercial<br />

replacement for cement and Fiber Reinforced Concretes<br />

would lessen the environmental footprint of the cement<br />

industry through not only the reduction of emissions during<br />

manufacturing, but also through the reduction of repair<br />

materials necessary to keep structural conditions safe.<br />

The Ethics Behind <strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

The most important aspect of any new building material is<br />

its safety. If <strong>Engineered</strong> <strong>Cementitious</strong> Composite was not<br />

safe, all of the previously stated characteristics would be<br />

irrelevant. In the American Society of Civil Engineers<br />

(ASCE) code of ethics, Canon #1 states that “engineers shall<br />

hold paramount the safety, health and welfare of the public”<br />

[12]. When using concrete, especially for load bearing<br />

structures such as buildings and bridges, it is absolutely<br />

essential that the concrete be able to hold up the weight of<br />

that structure. If the concrete cracks and crumbles under<br />

stress lower than the stress expected to be experienced<br />

during use, the possibility of structural failure could result.<br />

This can cause increased repair costs, malfunctions of<br />

essential societal systems like dams and water treatment<br />

plants, injury, or even death. <strong>Engineered</strong> <strong>Cementitious</strong><br />

Concrete has been experimentally proven multiple times to<br />

perform exceptionally well under many different types of<br />

loads, stresses, strains, and forces. The strain capacity for<br />

<strong>Engineered</strong> <strong>Cementitious</strong> Composite is high enough to be<br />

deemed safe for public use. Similarly, <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite is able to withstand damage caused<br />

by factors experienced in society such as varying weather<br />

conditions, wear, friction and grinding, corrosion, and many<br />

other environmental elements. <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite has an exceptionally long lifetime, and is able to<br />

not only withstand these conditions (as proven by multiple<br />

freeze-thaw, wet-dry tests mentioned above), in the case of<br />

weather patterns, precipitation actually increases <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite’s ability to function. The water<br />

better facilitates the self-healing processes creating a<br />

stronger concrete structure.<br />

In the code of ethics from the American Society of Civil<br />

Engineers, it is also stated in Canon #1, part D that<br />

“Engineers should seek opportunities to be of constructive<br />

service in civic affairs and work for the advancement of the<br />

safety, health and well-being of their communities…” [12].<br />

The use of <strong>Engineered</strong> <strong>Cementitious</strong> Composite rather than<br />

regular concrete would not only be a viable replacement, it<br />

would be a definite advancement of the current cement<br />

technology. It is becoming clear that <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite is a better alternative to regular<br />

concrete. For all aspects of safety involved in the use of<br />

cement and concrete, <strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

meets the requirements set by the American Society of Civil<br />

Engineers code of ethics and exceeds the performance of the<br />

current material majority.<br />

RECOUNTING ENGINEERING<br />

CEMENTITOUS COMPOSITE<br />

Concrete is an extremely vital component of today’s<br />

society and is used in many different structures that are<br />

critical to the function of the world. Due to the strong yet<br />

comparably brittle nature of current Fiber Reinforced<br />

Concrete, very little can be done in terms of high tensile<br />

strains and load bearing applications. <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite solves these problems and provides<br />

even greater advantages in application through its distinctive<br />

and unique properties of self-healing, high ductility, and<br />

tensile strength that is 500 times that of standard concretes.<br />

Application on the commercial level benefits many, based<br />

on the fact that the standard life cycle of repair is increased<br />

dramatically, the superior strength of the concrete can<br />

possibly increase the structural integrity of the projects it’s<br />

used in, and average maintenance time and cost as a whole is<br />

decreased. This not only improves safety, but also cuts down<br />

on materials used for maintenance which decrease negative<br />

environmental impact. The initial starting cost may propose<br />

a deterrent to the use of <strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite, however the long term savings from its<br />

application, will out weight the initial expense.<br />

Experimentation with <strong>Engineered</strong> <strong>Cementitious</strong> Composite<br />

is ongoing, and the fields of application are forever<br />

expanding for <strong>Engineered</strong> <strong>Cementitious</strong> Composite. The<br />

seemingly unbelievable characteristics of this bendable, selfrepairing<br />

concrete are being proven more and more<br />

applicable to society as testing and application continues,<br />

and in the future, it should be expected that <strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite becomes more prevalent in<br />

commercial concrete projects.<br />

REFERENCES<br />

[1] Li-li Kan, Hui-sheng Shi. (2012). “Investigation of Self-<br />

Healing Behavior of <strong>Engineered</strong> <strong>Cementitious</strong><br />

<strong>Composites</strong>(<strong>Engineered</strong> <strong>Cementitious</strong> Composite).”<br />

Construction and Building Materials. (Online Journal).<br />

http://www.highbeam.com/doc/1G1-284323187.html<br />

[2] V. Li, M. Lepech, S. Wang, M. Weimann, G. Keoleian.<br />

(2007). “Development of Green <strong>Engineered</strong> <strong>Cementitious</strong><br />

<strong>Composites</strong> For Sustainable Infrastructure Systems.”<br />

International Workshop on Sustainable Development and<br />

Concrete Technology. (Online Article).<br />

http://www.intrans.iastate.edu/publications/_documents/conf<br />

erence-proceedings-workshops/sustainable-devworkshop/ligreen.pdf<br />

[3] M. Li & V.C Li. (2006). “Behavior of <strong>Engineered</strong><br />

University of Pittsburgh<br />

Swanson School of Engineering March 7, 2013<br />

7


Jayne Marks<br />

Jon Conklin<br />

<strong>Cementitious</strong> Composite/Concrete Layered Repair System<br />

Under Drying Shrinkage Conditions.” Journal of<br />

Restoration of Buildings and Monument. (Online Article).<br />

http://hdl.handle.net/2027.42/84732 pg. 143-160<br />

[4] V. Li. (2003). “On <strong>Engineered</strong> <strong>Cementitious</strong> <strong>Composites</strong><br />

(<strong>Engineered</strong> <strong>Cementitious</strong> Composite): A review of the<br />

Material and Its Applications.” Journal of Advanced<br />

Concrete Technology. (Online<br />

Journal).https://www.jstage.jst.go.jp/article/jact/1/3/1_3_215<br />

/_article<br />

[5] M. Sahmaran, V. Li. (2005). “<strong>Engineered</strong> <strong>Cementitious</strong><br />

<strong>Composites</strong>: Can <strong>Composites</strong> Be Accepted as Crack-Free<br />

Concrete?” University of Michigan Transportation Research<br />

Record. (Online Article).<br />

http://deepblue.lib.umich.edu/bitstream/handle/2027.42/941<br />

98/sahmaran-trb-crackfree<strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite.pdf?sequence=1<br />

[6] E. Yang, J. Yu. (2010). “Microstructure of self-healed<br />

PVA <strong>Engineered</strong> cementitious composites under wet-dry<br />

cycles” Institute of Materials, Minerals and Mining. (Online<br />

Article).http://web.ebscohost.com/ehost/delivery?sid=c8a87<br />

805-c532/article<br />

[7] A. Vander-Broek. (November 2, 2009) “Self-Healing<br />

Concrete”. Forbes. (print article). pg. 46.<br />

[8] S.Wang, V. Li. (2005). “Lightweight <strong>Engineered</strong><br />

<strong>Cementitious</strong> <strong>Composites</strong> (<strong>Engineered</strong> <strong>Cementitious</strong><br />

Composite.)” Advanced Materials Council. (Online Article).<br />

http://www.advancedmaterialscouncil.org/prepare/uploaded<br />

_docs/material_id_387_pub/shuxinLW<strong>Engineered</strong><br />

<strong>Cementitious</strong> Composite.pdf<br />

[9] V. Li. (2003). “On <strong>Engineered</strong> <strong>Cementitious</strong> <strong>Composites</strong><br />

(<strong>Engineered</strong> <strong>Cementitious</strong> Composite): A review of the<br />

Material and Its Applications.” Journal of Advanced<br />

Concrete Technology. (Online<br />

Journal).https://www.jstage.jst.go.jp/article/jact/1/3/1_3_215<br />

/_article<br />

[10] M. Lepech, V. Li. (2006). “Sustainable pavement<br />

Overlays Using <strong>Engineered</strong> <strong>Cementitious</strong> <strong>Composites</strong>.”<br />

International Journal of Pavement Research and<br />

Technology. (Online Article).<br />

http://trid.trb.org/view.aspx?id=987336<br />

[11] A.M. Anwar, K. Hattori, H. Ogata, M. Ashraf &M.<br />

Mandula. (2009). “<strong>Engineered</strong> <strong>Cementitious</strong> <strong>Composites</strong> for<br />

Repair of Initially Cracked Concrete Beams.” Asian Journal<br />

of Applied Sciences. (Online Journal).<br />

http://scialert.net/fulltext/?doi=ajaps.2009.223.231<br />

[12]American Society of Civil Engineers. (September 2,<br />

1914). “Code of Ethics of the American Society of Civil<br />

Engineers.” American Society of Civil Engineers. (Code of<br />

Ethics)<br />

http://www.asce.org/Leadership-and-<br />

Management/Ethics/Code-of-Ethics/<br />

librarians who speak to our class about sources, Ms. Galle,<br />

John Broscious and Benjamin Hunter our chairs, and Agatha<br />

Carlin our co-chair.<br />

ACKNOWLEDGEMENTS<br />

We would like to acknowledge and thank Dr. Vidic,<br />

Nancy Koerbel, Dr. Budny, Beth Bateman-Newborg, the<br />

University of Pittsburgh<br />

Swanson School of Engineering March 7, 2013<br />

8

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