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observed were very similar to those produced by 'soft' Laue-Bragg x-rays (13) ,<br />

which was satisfactory, since the electrons' wavelength as predicted by de Broglie' s<br />

relation was very similar to that of these x-rays .<br />

Thomson performed a similar experiment of a more spectacular natur e<br />

using the Debye-Scherrer method2 in x-ray diffraction work . He scattered an<br />

undirectional monochromatic beam of cathode rays with a very thin film containin g<br />

a large number of randomly orientated crystals of white tin . Experiments with<br />

x-rays had shown that the diffracted beam should emerge from the group of<br />

crystals along the surfaces of concentric c<strong>one</strong>s centred about the inciden t<br />

direction . In Thomson's experiment (14) a photographic plate was placed 32 .5 cm<br />

from the group of crystals at a normal to the beam . The image on this plat e<br />

was found to consist of a series of concentric circles similar to those obtaine d<br />

with x-rays . In order to prove that these were caused by the electrons themselve s<br />

and not by secondary electromagnetic radiation, a magnetic field was applied to<br />

the diffracted beam, causing the image to move . Panto (15) developed Thomson' s<br />

technique by using metallic oxides deposited on a thin metal wire instead o f<br />

delicate crystalline films . In 1920 Rupp and Worsnop (16) showed that electron s<br />

were also diffracted by ruled gratings .<br />

Johnson investigated the wave-like nature of hydrogen (17) by reflectin g<br />

the gas from crystal surfaces . His detector was a plate smoked with molybdenu m<br />

trioxide, which becomes blackened when it reacts with hydrogen . Stern, Knauer,<br />

and Eotermann found that the wavelength of molecules in hydrogen were in exac t<br />

agreement with de Broglie's relation (18) . Ellett, Olson and Zahl (19) then<br />

showed that mercury, cadmium and arsenic ion beams could be diffracted b y<br />

crystals, using rock salt as a detector . Some years later Zinn (20) demonstrate d<br />

that neutrons also displayed wave characteristics . Neutrons from a chain-reacting<br />

pile were slowed down by graphite blocks and collimated by a series of cadmiu m<br />

slits . They were reflected from the face of a calcite crystal and detected b y<br />

means of a boron trifluoride counter .

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