Chemical Reference Standards AccuStandard®

Petrochemical ASTM Standards
Through a collaborative effort involving the instrument manufactures, Petrochemical end users, and Chemical Reference Standard manufacturers,
the following proposed D-5769 method is under consideration. A number of end users would like to evaluate this proposed D-5769 method and
have asked AccuStandard to make the standards. We have formulated the following certified standards to meet those requests.
Summary Proposed Modifications for D-5769
• Calibration standards when combined with internal standards are diluted into significantly more isooctane.
• The analytes in the Performance Standard have been expanded to better tune the GC/MS system for optimum performance.
• The number of components in the QA/QC mix has been reduced with new QA/QC tolerances.
• The number of analytes in the calibration mix has been reduced.
• Samples that exceed the linear range are to be diluted, reducing the number of extra calibration points required.
ASTM D-5769-XX Calibration Curve with No Internal Standard Added
ASTM-P-0140-SET
$ 1500 / Set of 5 x 5 mL
ASTM-P-0140-05
ASTM-P-0140-04
ASTM-P-0140-03
ASTM-P-0140-02
ASTM-P-0140-01
Core Calibr. Mix Level 1 Level 2 Level 3 Level 4 Level 5
Compound Target Mass % Mass % Mass % Mass % Mass %
Benzene 5 3 1 0.5 0.1
Toluene 12 9 6 3 0.5
Ethylbenzene 5 3.75 2.5 1.25 0.2
1,3-Dimethylbenzene 10 7.5 5 2.5 0.2
1,4-Dimethylbenezene 5 3.75 2.5 1.25 0.2
1,2-Dimethylbenezene 5 3.75 2.5 1.25 0.2
(1-Methylethyl)-benzene 3 2.25 1.5 0.75 0.2
1-Methyl-3-ethylbenzene 3 2.25 1.5 0.75 0.2
1-Methyl-4-ethylbenzene 3 2.25 1.5 0.75 0.2
1,3,5-Trimethylbenzene 3 2.25 1.5 0.75 0.2
1-Methyl-2-ethylbenzene 3 2.25 1.5 0.75 0.2
1,2,4-Trimethylbenzene 6 4.5 3 1.5 0.2
1,2,3-Trimethylbenzene 3 2.25 1.5 0.75 0.2
Indan 3 2.25 1.5 0.75 0.2
1,2-Diethylbenzene 2 1.5 1 0.5 0.2
Naphthalene A 2 1.5 1 0.5 0.1
2-Methylnaphthalene A 2 1.5 1 0.5 0.1
1-Methylnaphthalene A 2 1.5 1 0.5 0.1
Isooctane (solvent) * balance balance balance balance balance
4 Comp. Deuterated Internal Std. Mix
ASTM-P-0140-IS
ASTM-P-0140-IS-PAK
Compound Mass %
Benzene-d 6 2
Ethylbenzene-d 10 2
$ 75 / 1 x 10 mL
$ 300 / 5 x 10 mL
4 comps.
Compound Mass %
Naphthalene-d 8 1
Isooctane * balance
4 Comp. Deuterated Internal Std. Mix
ASTM-P-0140-IS2
ASTM-P-0140-IS2-PAK
Compound Mass %
Benzene-d 6 2
Ethylbenzene-d 10 2
A = This component is a solid at room
temperature
$ 95 / 1 x 10 mL
$ 380 / 5 x 10 mL
5 comps.
Compound Mass %
Naphthalene-d 8 1
Toluene-d 8 7
Isooctane * balance
Technical Note
* The isooctane balance is the
amount of material to make up
a 100 mL calibration standard.
Certificate will reflect actual
weight of each component in
the 100 mL batch including the
isooctane.
ASTM Standards
Performance Evalutation Standard
ASTM-P-0140-PES
ASTM-P-0140-PES-PAK
Target
Compound Mass %
Benzene 1
1,2-Diethylbenzene 0.005
1,3,5-Trimethylbenzene 1
1-Methyl-2-ethylbenzene 1
Styrene 0.1
Indene 0.1
Biphenyl 0.1
1,2,4,5-Tetramethylbenzene 1
1,2,3,5-Tetramethylbenzene 1
Hexadecane 1
Isooctane:Toluene(1:1) * balance
$ 55 / 1 x 1 mL
$ 220 / 5 x 1 mL
11 comps.
Composition of Daily QC Standard
ASTM-P-0140-QC
$ 125 / 1 x 10 mL
ASTM-P-0140-QC-PAK
$ 500 / 5 x 10 mL
9 comps.
Target
Compound Mass %
Benzene 1
Toluene 10
Ethylbenzene 3
1,3-Dimethylbenzene 6
1,2-Dimethylbenzene 3
1,2,4-Trimethylbenzene 3
1,2-Diethylbenzene 0.02
Naphthalene 1
Isooctane (solvent) * balance
For MSDSs visit our website at www.AccuStandard.com 177