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A review of greenhouse gas emission factors for fertiliser production.

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technologies (IPCC 2000). Non-Selective Catalytic Reduction (NSCR), a typical tail<strong>gas</strong> treatment in the USA and Canada, may reduce N 2 O <strong>emission</strong>s by 80-90% (IPCC2000) and a nitric acid manufacturer in Norway has developed a N 2 O abatementprocess giving 70-85% N 2 O reduction (Kongshaug 1998). Despite their advantages,an estimated 80% <strong>of</strong> the nitric acid plants worldwide do not employ NSCRtechnology (IPCC 2000).3.2.2. Emission Factors <strong>for</strong> Nitric Acid ProductionEmission <strong>factors</strong> <strong>for</strong> nitric acid <strong>production</strong> are given in Table 4. With the exception <strong>of</strong>Kramer (1999) and Mortimer (pers. comm.) the only GHG included is N 2 O. Estimatesare generally based on point source measurement <strong>of</strong> N 2 O concentration in tail <strong>gas</strong>es atnitric acid plants. In LCA studies where <strong>emission</strong>s credits from steam generatedduring nitric acid <strong>production</strong> were considered (see Table 2), the credit was generallyapplied elsewhere in the <strong>fertiliser</strong> <strong>production</strong> life cycle. Mortimer (pers. comm.)presented a small <strong>emission</strong> credit in this step <strong>of</strong> the <strong>fertiliser</strong> life cycle.N 2 O <strong>emission</strong>s from nitric acid <strong>production</strong> are highly variable with estimates rangingfrom 550-2945 g CO 2-e /kg Nitric Acid (Table 4). Variation among estimates can beattributed to the installation <strong>of</strong> <strong>emission</strong>s abatement technologies. It should be notedthat <strong>emission</strong> <strong>factors</strong> as high as 5890 CO 2-e /kg Nitric Acid are given <strong>for</strong> plants notequipped with NSCR technology (IPCC 2000).Table 4: Greenhouse <strong>gas</strong> <strong>emission</strong> <strong>factors</strong> <strong>for</strong> Nitric Acid ProductionProduct Country Composition a g CO 2-e ReferenceN:P:K per kg N per kg CO 2:N 2O:CH 4ProductNitric Acid USA 22.2:0:0 2818.2- 620-2790 0:100:0 IPCC (2000)12681.8Nitric Acid Norway – modern, integrated 22.2:0:0 2818.2

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