The Linear Response Function. - Vrije Universiteit Brussel
The Linear Response Function. - Vrije Universiteit Brussel
The Linear Response Function. - Vrije Universiteit Brussel
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
Unsaturated systems• alternating values• C 1 , C 3 , C 5 of the chain: minimaC 0 , C 2 , C 4 , C 6 : maximaR= OH, NH 2 : resonance structures5316 4 2C 1 , C 3 , C 5 : mesomeric passive atoms→ follow same trend as alkane structures (inductive effect)C 0 , C 2 , C 4 , C 6 : mesomeric active atoms→ effect remains consistently large even after 6 bonds (small decrease due tosuperposition of inductive and mesomeric effect)N. Sablon, F. De Proft, P. Geerlings, JPCLett., 1, 1228, 2010Pag.6-1-2012 24