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Issue 2_2012<br />

<strong>FFD</strong> <strong>IM</strong><br />

DIALOG<br />

More information under www.forschungsdienste.info<br />

Innovative lithium ion battery separators<br />

<strong>Freudenberg</strong><br />

<strong>Forschungsdienste</strong> <strong>KG</strong><br />

u Batteries at <strong>FFD</strong> – under scrutiny


Table of contents<br />

2 Table of contents<br />

1. Editorial P. 3<br />

2. Innovative lithium ion battery separators P. 4<br />

3. RFID P. 9<br />

4. RSSR tribometer P. 14<br />

5. News from the Senior Scientists P. 17<br />

6. Seminars P. 20<br />

CT cut-away view of a winding cell (recorded at <strong>FFD</strong> Microscopy)


Editorial<br />

Dear Business Partners,<br />

To the great surprise of its competitors, BMW succeeded in driving<br />

home a victory already in the second race after joining in the German<br />

Touring Car Championship again. This permits a number of conclusions<br />

as regards the success factors in this fiercely contested race:<br />

To enter a new field of work, it is imperative to have a high level<br />

of knowledge and quality for known components.<br />

In the face of changed underlying conditions, it is decisive to<br />

adjust to them as quickly as possible.<br />

Innovative approaches, possibly merely innovative details, are<br />

instrumental in gaining a leading edge over competitors.<br />

Thanks to a capable, experienced and committed team, a product<br />

can rapidly become a success – whether in the preparatory<br />

phase, in the pits or in the race for victory.<br />

Some of these factors are repeatedly encountered at <strong>Freudenberg</strong>.<br />

For <strong>FFD</strong>, we will be presenting a number of examples in this issue<br />

of “<strong>FFD</strong> Dialogue”.<br />

The process of generating and saving energy will be one of the<br />

continuing challenges of the future. With its newly developed battery<br />

components, <strong>Freudenberg</strong> can play a very important role on<br />

the market (page 4). The use of what is, to all intents and purposes,<br />

known technology in other applications helps to save both<br />

costs and development time. <strong>FFD</strong> has applied RFID technology to<br />

safe work on rotating machinery (page 9). A high-speed method<br />

for selecting suitable materials and mating materials enables the<br />

developer to achieve products with a high level of operational stability<br />

within a relatively short time (page 14). Our committed team<br />

of experienced experts (page 17) and well trained organisers,<br />

engineers and scientists (page 20) ensures long-term success.<br />

I trust that you will find reading this issue both exciting and stimulating.<br />

Yours sincerely,<br />

Dr. Gerd Eßwein<br />

Editorial<br />

3


Batteries at <strong>FFD</strong> – under scrutiny<br />

InnOvAtIve LIthIuM IOn<br />

bAttery sepArAtOrs<br />

4<br />

Innovative lithium ion battery separators<br />

Introduction<br />

Battery separators are porous surface-type components which<br />

prevent electrical contact between the positive and negative elec-<br />

trodes of a battery cell yet, at the same time permit an unobstructed<br />

transport of ions between the electrodes. Ideally, separators are<br />

not involved in electrochemical reactions inside a battery, although<br />

they influence battery properties such as energy density, power<br />

density, lifetime and operational reliability to a very considerable<br />

extent. In the case of lithium ion batteries for classic applications<br />

in the 4C market (computers, cameras, cellular phones, cordless<br />

tools), separators are primarily microporous polyolefin-based<br />

(PP and / or PE) membranes. The ten largest lithium ion battery<br />

manufacturers alone need more than 450 million m 2 of separators<br />

per year (2011), with growth rates of more than 10%. The<br />

advantages of microporous membranes are their thickness (25 µm<br />

or less) and their small pore sizes (< 1 µm). The disadvantages of<br />

these membranes are their low melting point (approx. 120°C for<br />

PE and 160°C for PP), their high shrinkage rate and, in particular,<br />

their low puncture resistance with regard to electrode particles, for<br />

example. In 2011, on behalf of the French Ministry of the Environment,<br />

the French institute INERIS established that conductive particles<br />

which force their way through a separator have been one of


the main causes for internal short-circuits of lithium ion batteries.<br />

This has resulted in very cost-intensive recall campaigns by battery<br />

manufacturers. Since conventional polyolefin-based separators<br />

have the weaknesses described above, <strong>FFD</strong>, in cooperation with<br />

<strong>Freudenberg</strong> Vliesstoffe <strong>KG</strong>, has since 2007 been developing separators,<br />

particularly for large-volume lithium ion batteries. Due to<br />

their high energy content, these impose totally new requirements<br />

on the safety of batteries and thus also of separators.<br />

<strong>Freudenberg</strong>’s technology<br />

With <strong>Freudenberg</strong>’s approach (see Figure 1), an ultra-thin<br />

temperature-stable PET wet nonwoven is coated with anorganic<br />

particles and an organic bonding agent. The anorganic particles<br />

ensure excellent temperature stability and the organic bonding<br />

agents create a level of flexibility which, despite the anorganic<br />

particles, does not make the materials brittle but highly flexible.<br />

Figure 1: <strong>Co</strong>ating of a nonwoven<br />

Due to temperature stability, the separators developed by <strong>Freudenberg</strong><br />

feature a very low shrinkage rate. Figure 2 depicts a comparison<br />

between a <strong>Freudenberg</strong> separator and commercial PO membranes<br />

after a storage period of one hour at 160°C. What can be<br />

clearly seen is the shrinkage rate of the wet membrane (1, PE) and<br />

the unidirectionally stretched dry membranes (2, PP and 3, PE / PP<br />

multilayer). In both cases, the stress levels of the membranes which<br />

are frozen at room temperature are increasingly released, resulting in<br />

shrinkage and thus in a high safety risk. In contrast to conventional PO<br />

separators, <strong>Freudenberg</strong>’s products do not show any detectable shrinkage,<br />

a fact which predestines them for safety-related applications.<br />

Figure 2: <strong>Co</strong>mparison of the shrinkage rates of different lithium ion separators<br />

puncture resistance of separators – resistance desired<br />

In order to be able to determine and assess the relevant safety<br />

properties of separators, the Physical Testing Department has, over<br />

the last few years, developed and improved a series of specific test<br />

methods, including the mixed penetration test (see Figure 3), with<br />

which the puncture resistance of a separator can be determined.<br />

Innovative lithium ion battery separators<br />

5


Figure 3: Mixed penetration test<br />

Innovative lithium ion battery separators<br />

6 Innovative lithium ion battery separators<br />

In this test, the separator is located<br />

between the anode and<br />

the cathode in order to better<br />

simulate the set-up of a battery.<br />

A voltage is applied at the electrodes<br />

and then a mandrel with a<br />

semi-spherical tip is used to exert<br />

pressure on the battery component<br />

with force being continuously<br />

increased until a short-circuit<br />

results, the separator is thus damaged<br />

and the anode and the<br />

cathode come into direct contact<br />

with each other. The relevant<br />

force is measured at which the electrical resistance very suddenly<br />

falls from “infinite” to less than 100 kΩ. Figure 4 shows the results<br />

of the mixed penetration test as an example using two <strong>Freudenberg</strong><br />

samples (FV-1 and FV-2) and two conventional commercially<br />

available PO separators.<br />

Cyclical lifetime – batteries under scrutiny<br />

For purposes of everyday suitability, lithium ion batteries need not<br />

only the above-referenced safety-related properties but also a long<br />

Figure 4: <strong>Co</strong>mparison of the puncture resistance of different separators


cyclical lifetime and a high current-carrying capacity. The Applied<br />

Physics Department has developed test methods for investigating<br />

the cyclical lifetime and the current-carrying capacity and provides<br />

the necessary measuring systems. For this purpose, <strong>FFD</strong> has<br />

a multi-channel battery test system which enables the characterisation<br />

of separators in battery cells of different designs and sizes.<br />

Due to programmable application software for automated test<br />

procedures and data evaluation, measurements can be efficiently<br />

performed at the battery test bay. In addition to the standardised<br />

test processes from the available test catalogue, customer-specific<br />

test requirements, e.g. battery tests in climatic chambers, are also<br />

taken into consideration.<br />

A large number of factors determine whether the nominal cyclical<br />

lifetime is reached. The temperature and discharge current (also<br />

referred to as “C rate”) apply as the most important contributory<br />

parameters. The C rate specifies the electrical load relative to nominal<br />

capacitance. At a C rate of 0.5, a rechargeable battery with<br />

a nominal capacitance of 2000 mAh is discharged at a current of<br />

1000 mA. Under ideal conditions (temperature of 20°C, current<br />

of 1C nominal ), commercially available series cells should have at<br />

least 75% of their initial capacitance after more than 500 complete<br />

charging / discharging cycles. Figure 5 shows the cyclical<br />

lifetime of type 18650 winding cells with <strong>Freudenberg</strong> separators.<br />

Figure 5: Determination of cyclical lifetime<br />

To ensure effective usage of the overall capacitance of a rechargeable<br />

battery, battery manufacturers recommend a defined<br />

electrical load at approx. one fifth of the nominal current, i.e. at<br />

approx. 0.2 C. When increasing the current load to many times the<br />

nominal capacitance, the actually usable capacitance decreases<br />

significantly, this being due to the load-dependent increase in<br />

internal battery resistance. Due to its material properties and<br />

coating topology, the separator in use makes a by no means<br />

negligible contribution to a cell’s internal resistance.<br />

Figure 6 shows the load-dependent capacitance of lithium ion<br />

batteries with identical electrodes but different separators which<br />

means that differences in capacitance are attributable to the se-<br />

Innovative lithium ion battery separators<br />

7


Figure 6: <strong>Co</strong>mparison of discharge rate-dependent capacitance of different<br />

lithium ion batteries<br />

Innovative lithium ion battery separators<br />

8<br />

Innovative lithium ion battery separators<br />

parator. The influence of the separator<br />

on capacitance is easily<br />

discernible, with FV2A being the<br />

first developed separator and<br />

FV2B, FV2B2 and FV1C the separators<br />

which have been optimised<br />

in terms of internal resistance.<br />

<strong>Co</strong>mparison of the capacitances<br />

shows that, due to a continuous<br />

improvement in coating recipes<br />

for separators, the actually usable<br />

battery capacitance has<br />

been increased.<br />

<strong>Co</strong>nclusion<br />

It has been shown that innovative lithium ion battery separators<br />

have been developed featuring not only good electrochemical behaviour<br />

but also, in particular, considerably improved safety properties<br />

which distinguish them from conventional PO separators.<br />

In addition to their very low shrinkage rate, these separators have<br />

a very high puncture resistance which particularly recommends<br />

them for large-surface, safety-related lithium ion cells in both<br />

stationary and mobile applications. Alongside separator development,<br />

over the last few years an almost complete test catalogue<br />

for the characterisation of separators and lithium ion batteries<br />

has been put together at <strong>FFD</strong>. In 2011, the market for lithium ion<br />

separators was more than 450 million m 2 with a continued high<br />

growth rate in which <strong>Freudenberg</strong> wishes to participate.<br />

your contacts:<br />

Marina Senina<br />

Physical Testing<br />

Tel.: +49 (0)6201 - 80 38 27<br />

Fax: +49 (0)6201 - 80 38 27<br />

marina.senina@<br />

freudenberg.de<br />

Süleyman Altuncu<br />

Tel.: +49 (0)6201 - 80 49 55<br />

Fax: +49 (0)6201 - 80 30 63<br />

sueleyman.altuncu@<br />

freudenberg.de<br />

Dr. Michael Roth<br />

Tel.: +49 (0)6201 - 80 52 60<br />

Fax: +49 (0)6201 - 80 52 60<br />

michael.rath@freudenberg.de


As non-contact machine guards<br />

rFID<br />

Introduction:<br />

In many processes, it is still imperative to move items to be processed<br />

to the processing point by hand. Classic examples to this<br />

effect may be found in mechanical workshops. Circular and band<br />

saws, chamfering benches and sheet-metal bending machines<br />

may be primarily referred to as examples. However, in typical processes<br />

at <strong>Freudenberg</strong>, such as the mixing and rolling of rubber<br />

compounds or foularding, manual handling is required in some<br />

cases. In all these specified processes, staff are inevitably exposed<br />

to a potential hazard.<br />

As conventional protection of staff in danger zones, three possibilities<br />

are available, although they are subject to restrictions:<br />

Permanent separating machine guards. In this case, production<br />

items cannot be moved to the processing point by hand.<br />

Movable separating machine guards. If a guard door is used,<br />

the machine is emergency-stopped. Movable machine guards<br />

with an approach function generally have recesses through<br />

which the production item can pass. If the guard is moved by<br />

part of the operator’s body, an emergency stop is triggered. The<br />

disadvantage is that, for many production items, the recess has<br />

RFID<br />

9


RFID<br />

10 RFID<br />

to be so large that the operator’s arm, for example, can also<br />

access the danger zone or the recess has to be dimensioned<br />

sufficiently small so that an emergency stop is triggered by a<br />

production item when passed through.<br />

Non-contact machine guards. Such available guards, such as<br />

light curtains, cannot distinguish between a production item and<br />

part of an operator’s body.<br />

For some applications, RFID (radio-frequency identification) technology<br />

is suitable for the installation of a machine guard. RFID<br />

uses electromagnetic waves for identification purposes.<br />

This technology is actually familiar to everyone as it is used in antitheft<br />

tagging systems in department stores. Articles of clothing are<br />

often fitted with a transponder (or radio tag). Devices which create<br />

an electrical field are positioned at the entrances to department<br />

stores. The transponder detects the electrical field on approaching<br />

it and sends a signal to an evaluation unit which generates an<br />

acoustic signal prompting the customer with an unpaid-for item to<br />

think twice before leaving the premises and to pay for the article<br />

in question.<br />

This principle can also be used on a machine guard.<br />

Function and elements of an rFID machine guard<br />

For the reasons outlined above, <strong>FFD</strong> decided in 2010 to introduce<br />

a RFID machine guard on a laboratory roller mill. This system comprises<br />

a limited number of components. The antenna is the core<br />

element of the system. It generates the electrical field (protective<br />

field) and consists of an extended conductor through which a current<br />

flows. Using a low-frequency AC current (9 kHz), a cylindrical<br />

magnetic field is generated which has a very high level of penetration<br />

through almost all materials. The antenna is positioned in<br />

parallel to the roller clearance above the rollers.<br />

To protect the operator’s hands, two transponders have to be worn<br />

on his or her wrists. Each transponder detects the field and sends<br />

a signal to the evaluation unit. In the X, Y and Z directions, the<br />

transponders are fitted with a coil which means that it is irrelevant<br />

how a transponder enters the field.


In our case, active transponders are used which draw the energy<br />

needed for signal transmission from a battery.<br />

The evaluation unit receives the signals sent by the transponders<br />

and the self-test module. These signals are redundantly processed<br />

by the control unit. The evaluation unit supplies the signal for triggering<br />

an emergency stop to the machine’s control unit.<br />

These imperative functional units are supplemented by different<br />

additional devices which are to ensure that functionality is permanently<br />

monitored. For visual display of the protective field boundary,<br />

a linear laser is used to project a mark on the roller. Since it is<br />

absolutely necessary for the machine guard to continuously check<br />

whether the protective field is available, a self-test module is used.<br />

This module is positioned in the protective field which it monitors.<br />

As soon as the protective field is no longer available, the self-test<br />

module sends a signal to the evaluation unit and the machine is<br />

emergency-stopped. This could, for example, be the case due to a<br />

broken cable or a power failure.<br />

To ensure that the transponders are applied, they have to be<br />

logged on at a log-on unit. It is only then that the system can be<br />

started. Successful log-on provides the operator with the information<br />

that the battery still has a lifetime of at least eight hours. In the<br />

case of our roller mill, log-on has to be repeated after a pre-set<br />

time in order to ensure that rolling is continuously monitored by a<br />

member of staff. The roller mill is then emergency-stopped upon<br />

expiry of this time.<br />

The objective was to achieve a finalised safety concept with a very<br />

high level of protection in the system. For this reason, traditional<br />

machine guards were also kept. <strong>FFD</strong>’s roller mill continues to be<br />

equipped with emergency stop pushbuttons, toggle triggers and<br />

a cut-off rocker. The rocker as a machine guard with an approach<br />

function has, however, been modified so that the roll of uncured<br />

rubber can be rolled and turned out and the additives dosed in<br />

an ergonomically favourable manner, providing optimum process<br />

possibilities.<br />

rFID workshop<br />

<strong>FFD</strong> invited colleagues interested in this subject to participate in<br />

the RFID workshop<br />

to present the mode of operation of an RFID machine guard<br />

to discuss the possibilities and limits of application<br />

to develop suitable decision-making aids for usage<br />

and thus to define underlying conditions for usage at <strong>Freudenberg</strong><br />

At this workshop, RFID technology was presented by the manufacturer.<br />

During the talk given, if became clear that a wide range of<br />

different possible applications are conceivable.<br />

RFID 11


RFID<br />

12 RFID<br />

The theory block was rounded off by a close look at the laboratory<br />

roller mill in <strong>FFD</strong>’s Elastomers Pilot Plant . All participants had the<br />

possibility of seeing for themselves the different functional elements.<br />

They found it particularly interesting to talk with colleagues on site<br />

who already work with the RFID machine guard. It was in this connection<br />

that a specially positive aspect became clear. Although the<br />

machine guard is not mandatory since the transponders have to<br />

be worn by staff, a high level of motivation to do so is apparent<br />

since the RFID machine guard permits considerably more ergonomic<br />

work than was previously the case. The roll of uncured rubber is<br />

now rolled in an ergonomically more favourable working position<br />

and, in order to be turned out into the clearance between the rollers,<br />

it need not be lifted over a separating machine guard.<br />

Finally, there was an intensive discussion about which technical<br />

and organisational basic conditions have to exist for suitable<br />

usage of this technology.<br />

basic conditions for application of rFID technology as machine guards<br />

The relevant workplaces have to be continuously manned by a<br />

limited number of staff. Machinery which is used by many<br />

persons for brief activities is not suitable. For example, it is not<br />

very likely that staff who use a band saw in a workshop for short<br />

periods only always think of wearing the transponders.<br />

Only machinery should be considered on which process items<br />

are currently moved to the processing point by hand. Machinery<br />

on which a fixed or movably separating or non-contact machine<br />

guard is suitable without restricting the process possibilities is<br />

unsuitable for the use of RFID. Such examples include injection<br />

moulding machines and presses.<br />

The technology must be “just right”. For example, the switching<br />

times and the braking distances of the machine have to be<br />

designed in such a way as to permit safe braking before the<br />

hazard point can be reached.


examples of suitable machinery<br />

Old machinery, e.g. old roller mills which have not yet been<br />

fitted with machine guards or which are only protected by a<br />

Bowden cable emergency stop above the clearance between<br />

the rollers<br />

Bale openers, waste presses<br />

basic conditions for organisation<br />

Hazard evaluation with an analysis of the residual hazards<br />

Limitation of the number of staff to a minimum<br />

Operating instructions and briefing<br />

Regular adjusted checking of the emergency stop function<br />

<strong>Co</strong>nclusion<br />

<strong>FFD</strong>’s experience shows that, under certain defined conditions and<br />

constraints, an RFID machine guard can make a very positive contribution<br />

to machine safety. A key factor is the readiness of staff<br />

to move over from a “visible” separating machine guard to an<br />

“invisible” one. Active staff involvement from the very beginning is<br />

a basic condition for the usage of such systems.<br />

your contact:<br />

Ulrich Freund<br />

Tel.: +49 (0)6201 - 80 42 74<br />

Fax: +49 (0)6201 - 80 30 63<br />

ulrich.freund@<br />

freudenberg.de<br />

RFID 13


Establishment of a test method…<br />

rssr trIbOMeter<br />

14 RSSR Tribometer<br />

… required for rapid assessment of elastomer / lubricant combinations<br />

Introduction<br />

For the design of dynamic seals with radial shaft sealing rings<br />

(RSSR), not only a large number of other influencing factors but<br />

also the selection of suitable elastomer / oil combinations plays<br />

a decisive role. At present, no standardised test method exists for<br />

the purpose of recording the wear and friction of simple material<br />

samples, taking into consideration operating conditions such as<br />

sealing geometry, contact force, circumferential speed and temperature.<br />

For investigations of elastomer / oil combinations on radial<br />

shaft sealing rings, it is, due to different shrinkage behaviour,<br />

frequently imperative to produce a separate sample tool for each<br />

elastomer compound.<br />

In order to exclude material combinations which are unsuitable at<br />

an early stage, the RSSR tribometer was developed and tested as<br />

a dynamic test method within the context of project 664 of DGMK<br />

(German Society for Petroleum and <strong>Co</strong>al Science and Technology),<br />

enabling a preselection of suitable materials on the basis of<br />

easy-to-manufacture elastomer samples. In order to establish this


test method as a standard, we are currently searching for partners<br />

who are interested in jointly implementing such a solution.<br />

Design and mode of operation<br />

The basic design of the RSSR<br />

tribometer is depicted in Figure<br />

1. A circular ring-shaped ela-<br />

stomer test specimen is pressed,<br />

at a defined force, against a<br />

truncated-cone shaft test specimen.<br />

The contact area between<br />

both test specimens represents<br />

the contact between the radial<br />

shaft sealing ring and the shaft<br />

itself.<br />

The shaft test specimen is dri-<br />

Figure 1: Mode of operation of the RSSR tribometer<br />

ven via a shaft and the moment<br />

transferred to the elastomer test<br />

specimen is recorded. The contact area is located in a container<br />

filled with the test oil. The area below the elastomer test specimen<br />

can be filled with air.<br />

In addition to selecting the<br />

materials for the elastomer test<br />

specimen, shaft test specimen<br />

and test oil, the parameters oil<br />

sump temperature, circumferential<br />

speed and contact force<br />

can be set. Figure 2 shows the<br />

course of the friction moment<br />

for different test oils when<br />

using a test specimen made<br />

of nitril butadiene rubber during<br />

the 20-day standard test<br />

Figure 2: Tests with RSSR and RSSR tribometer<br />

procedure. Furthermore, the<br />

influence of the three cycles<br />

(see Figure 2) in which the circumferential speed is varied can be<br />

clearly seen.<br />

results from investigations on radial shaft sealing rings and<br />

rssr tribometer in comparison<br />

The basic suitability of the RSSR tribometer is examined by investigations<br />

of a sample elastomer / oil combination of a nitril butadiene<br />

rubber with a conventional mineral oil, and the results of the<br />

RSSR tribometer are compared with those of radial shaft sealing<br />

rings of the same material. Figure 3 shows the influence of the parameters<br />

oil sump temperature and circumferential speed at the sti-<br />

RSSR Tribometer 15


Figure 3: Test procedure: a NBR with five oils in comparison<br />

RSSR Tribometer<br />

Figure 4: <strong>Co</strong>mparison of wear sustained by the RSSR and the RSSR tribometer<br />

16 RSSR Tribometer<br />

realisation<br />

pulated linear load. In the case<br />

of the RSSR tribometer and the<br />

radial shaft sealing ring, the<br />

influence on wear (see Figure<br />

4) is comparable. Due to the<br />

radial force which, during the<br />

test, decreases in the case of<br />

the radial shaft sealing ring as<br />

a result of the change in temperature<br />

and wear, the RSSR<br />

tribometer, however, causes<br />

wear to increase at about<br />

twice the rate.<br />

The investigations show that<br />

testing with the RSSR tribometer<br />

is highly suitable for the<br />

purpose of comparing material<br />

combinations. Further standardisation<br />

of the test method is<br />

currently the subject of DGMK<br />

project 738.<br />

Investigations performed so far are taking place at ten prototype test<br />

bays of TUHH. Partners from the DGMK project have approached<br />

us in order to assume responsibility for the construction, sales and<br />

servicing of such dual test bays.<br />

At present, on the basis of these prototypes, marketable test bays<br />

are being realised in the form of dual test bays. In order to esta-<br />

blish the new method on as broad a basis as possible, we are currently<br />

searching for further partners and potential customers who<br />

wish to use such a method within the context of development and<br />

selection of elastomer seals and / or lubricants and participate in<br />

the realisation of test bays or who are interested in acquiring RSSR<br />

tribometer test bays.<br />

your contacts:<br />

Dr. Stefan Sindlinger<br />

Tel.: +49 (0)6201 - 80 36 90<br />

Fax: +49 (0)6201 - 80 36 90<br />

stefan.sindlinger@<br />

freudenberg.de<br />

Dr. Ravindrakumar Bactavatchalou<br />

Tel.: +49 (0)6201 - 80 24 36<br />

Fax: +49 (0)6201 - 88 51 91<br />

ravindrakumar.bactavatchalou@<br />

freudenberg.de


News from the Senior Scientists<br />

Figure 1: Input of the major stretches in the “invariant” app<br />

Mobile engineering by “app” no longer a dream of the future<br />

… was the headline in the newspaper published by the Association<br />

of German Engineers “VDI-Nachrichten” in April 2011 and<br />

was repeated in a similar form in April 2012. <strong>FFD</strong>, too, is facing<br />

up to this challenge and is currently investigating possibilities of<br />

providing appropriate services for mobile technical applications.<br />

Within this context, Dr. Baaser has, together with two students<br />

from Bingen University of Applied Sciences, developed an app<br />

which maps his basic investigations for representing possible deformation<br />

modes of elastomers onto the plane of invariants.<br />

Figure 2: Graphic output of deformation on the plane of invariants I 1 -I 2<br />

The classic material models for<br />

elastomers are based on the<br />

deformation invariants; exten-<br />

sions of these models are at least<br />

based on these classic descriptions.<br />

This raises the question,<br />

also in discussions with customers,<br />

regarding a suitable visualisation<br />

of current deformations<br />

in rubber components. As early<br />

as in the mid-20th century, Prof.<br />

L.R.G. Treloar was concerned<br />

with this task and, to this effect,<br />

suggested the representation<br />

of all possible deformations of<br />

rubber materials on the plane<br />

of invariants. Thus, it is very<br />

impressively possible to classify<br />

all deformations between the<br />

uni-axial and bi-axial prototype<br />

modes.<br />

The assessment of these modes<br />

is a crucial aspect of [1] and<br />

[2] and aims later at lifetime<br />

estimation for elastomers. The<br />

Adjunct professor Dr.-Ing. habil.<br />

herbert baaser<br />

Senior Engineer for Physical<br />

Material Properties and Life<br />

Cycle<br />

Tel.: +49 (0)6201 - 80 68 82<br />

Fax: +49 (0)6201 - 88 30 84<br />

News from the Senior Scientists 17


Figure 3: LEVITEX crankshaft seal, 1999 –<br />

2003<br />

News from the Senior Scientists<br />

18 News from the Senior Scientists<br />

user interface of this app currently comprises two screens<br />

on a mobile device with Android or the Apple operating<br />

system. The first page (see Figure 1) is primarily for the<br />

purpose of entering two stretches of the material. This deformation<br />

is then visualised in the graphic output of the<br />

second page (Figure 2) on the plane of invariants for incompressible<br />

materials.<br />

If you have any suggestions or other ideas on this complex<br />

subject, please contact Dr. Baaser who would be delighted<br />

to provide you with this application as a “tool” and for<br />

demonstration purposes.<br />

<strong>FFD</strong>’s CAe supports LevIteX developments for Fst-Ape and burgmann-<br />

Automotive<br />

An idea and development of Burgmann Automotive<br />

for gas-lubricated crankshaft seals, now ten<br />

years old, have been picked up at FST again.<br />

This sealing concept is currently being refined at<br />

FST under the aspect of CO2 savings within the<br />

context of the LESS (Low Emissions Sealing Solution)<br />

package. A new approach in which an elastomer<br />

spring is to be used in combination with<br />

megaseries-suitable face geometries is shown<br />

as a cross-section in Figure 4. It is thus possible<br />

to reduce manufacturing costs to such an extent<br />

that cost-effective usage is directly worthwhile. In<br />

addition, benefits result due to the elastomer<br />

spring since the friction-prone ancillary seal , as<br />

used in conventional crankshaft seals, is no longer<br />

needed. The first few studies on this concept<br />

have evolved with Burgmann’s calculation program<br />

for crankshaft seals in cooperation with<br />

Dr. Klaus Lang of Burgmann (Wolfratshausen).<br />

Figure 4: Design and refinement of Burgmann’s LEVITEX<br />

The first design of the elastomer spring was re-<br />

seal<br />

alised using <strong>FFD</strong>’s WebFEM program. For complete<br />

optimisation of the functionality and harmonisation of the<br />

components, Burgmann’s calculation program is now being linked<br />

to Dr. Baaser’s developments. This enables a computer-aided structural<br />

optimisation of the overall concept. At this point, there is also


Figure 5: Axi-symmetrical FE model of an elastomer spring<br />

Figure 6: Axial stress in the cross-section of the elastomer spring<br />

close cooperation with Frank<br />

Schönberg who analyses such<br />

optimisation procedures within<br />

the context of robust design in<br />

cooperation between FST, <strong>FFD</strong>’s<br />

CAE and the University of Technology,<br />

Darmstadt.<br />

For structural optimisation of the<br />

elastomer spring, in this project,<br />

a special element formulation<br />

including material behaviour for<br />

elastomers has been implement-<br />

ed on the basis of a separate<br />

FEM program system DAEdalon<br />

which is freely available on the<br />

internet as open-source software<br />

under www.DAEdalon.org. The<br />

possibilities offered by such a<br />

software package have already<br />

been presented in a book (Figure<br />

7) authored by Dr. Baaser and<br />

have now been used for a development<br />

at FST for the first time.<br />

Figure 5 shows the axi-symmetrical<br />

model of the crankshaft seal’s<br />

elastomer spring; a calculation<br />

result obtained in the course of<br />

structural optimisation is specified<br />

in Figure 6. The resulting axial<br />

stress (in N/m²= Pa) is shown.<br />

(1) Baaser, H.: FEM-Simulation von Elastomerbauteilen. ATZ – Automobiltechnische<br />

Zeitschrift, April 5, 2010<br />

(2) Baaser, H., Schobel, A., Michaeli, M., Masberg, U.: Vergleich von äquibiaxia-<br />

len Prüfständen zur Kalibrierung von Werkstoffmodellen, Kautschuk Gummi Kunststoffe,<br />

May 2011<br />

(3) Baaser, H.: Development and Application of the Finite Element Method based<br />

on MatLab, Springer, 2010<br />

<strong>Co</strong>ntact:<br />

Adjunct Professor Dr.-Ing. habil. Herbert Baaser<br />

Senior Engineer for Physical Material Properties and Life Cycle<br />

Tel.: +49 (0)6201 - 80 68 82<br />

Fax: +49 (0)6201 - 88 30 84<br />

herbert.baaser@freudenberg.de<br />

Figure 7: Book on DAEdalon<br />

News from the Senior Scientists 19


to register, please contact:<br />

Ms. Ulrike Kast<br />

Tel.: +49 (0)6201 - 80 48 80<br />

Fax: +49 (0)6201 - 88 30 63<br />

ulrike.kast@freudenberg.de<br />

Seminars at <strong>Freudenberg</strong> <strong>Forschungsdienste</strong> <strong>KG</strong><br />

Location: <strong>FFD</strong>,<br />

Höhnerweg 2–4,<br />

69465 Weinheim<br />

Fee: EUR 1,350<br />

plus VAT<br />

Date: 07. - 08.11.2012<br />

Location: <strong>FFD</strong>,<br />

Höhnerweg 2–4,<br />

69465 Weinheim<br />

Fee: EUR 1,050<br />

plus VAT<br />

Date: 20. - 21.11. 2012<br />

20 Seminars<br />

r&D Funding by the German state –<br />

non-repayable Grants for your <strong>Co</strong>mpany<br />

Target group: This seminar is aimed at all project managers who<br />

wish to submit a funding application or who have already applied<br />

for/been granted funding for their R&D project. This is of relevance<br />

to anyone wishing to round off their knowledge about ruleconformant<br />

processes and requiring decision-making assistance.<br />

<strong>Co</strong>ntents: The participants find out how their company can profit<br />

from state R&D funding. Knowledge about formal processes from<br />

the preparation of an outline through to project close-out including<br />

price checking is provided. Important elements of the prescribed<br />

cooperation agreement, e.g. know-how protection, are presented.<br />

The experienced speakers provide tips from everyday administration<br />

practice in which they have successfully implemented numerous<br />

R&D funding projects.<br />

seminar on Failure Analysis in plastic <strong>Co</strong>mponents<br />

Seminar management: Siljana Lietz, <strong>FFD</strong> / Dr.-Ing. habil. Sonja Pongratz, VW<br />

This seminar is aimed at engineers and technicians who wish to<br />

gain a thorough understanding of failure mechanisms in plastic<br />

components and become familiar with methods of systematic causal<br />

analysis. At this seminar, possible causes of failure in moulded<br />

parts and the methods of investigation used in failure analysis will<br />

be presented. The systematic processing of instances of failure will<br />

be demonstrated using a guideline.<br />

seminar on rubber / Metal bonding<br />

Seminar management: Dr. Michael Ballhorn<br />

This seminar is aimed at engineers, chemists, technicians and machine<br />

operators involved in the area of rubber / metal bonding.<br />

<strong>Co</strong>ntents: rubber: classes, processing and bonding capacity; metal:<br />

cleaning, pretreatment (mechanical, chemical, phosphating),<br />

wetting; bonding agents: composition and effects, application,<br />

adhesion mechanisms, rubber and surface analytics, approaches<br />

and remedial measures in cases of failure, practical demonstrations<br />

and exercises.<br />

to register, please contact:<br />

Ms. Sonja Heinzelbecker, tel. +49 (0)6201 - 80 55 63,<br />

fax +49 (0)6201 - 88 55 63, sonja.heinzelbecker@freudenberg.de<br />

Location: <strong>Freudenberg</strong>,<br />

Building 23,<br />

Höhnerweg 2-4<br />

69469 Weinheim,<br />

Fee: EUR 500 plus<br />

VAT for<br />

<strong>Freudenberg</strong> staff,<br />

EUR 750 plus<br />

VAT for<br />

external participants<br />

Date: 15.11.2012,<br />

8.45 a.m. - 5 p.m.


Location: FST Academy<br />

Building 75<br />

Fee: Euro 690 plus VAT<br />

Date: 09./10.10.2012<br />

Location: FST Academy<br />

Building 75<br />

Fee: Euro 690 plus VAT<br />

Date: 23./24.10.2012<br />

Location: FST Academy<br />

Building 75<br />

Fee: Euro 690 plus VAT<br />

Date: 20./21.11.2012<br />

Location: FST Academy<br />

Building 75<br />

Fee: Euro 690 plus VAT<br />

Date: 11./12.12.2012<br />

Location: <strong>FFD</strong> Building 32<br />

Fee: Euro 690 plus VAT<br />

Date: 18./19.12.2012<br />

Location: <strong>FFD</strong> Building 32<br />

Fee: Euro 690 plus VAT<br />

Date: 06./07.11.2012<br />

seminar series “elastomers processing at <strong>Freudenberg</strong>“<br />

Seminar management: Dr.-Ing. Andreas Kammann<br />

The seminars are aimed principally at participants with a technical<br />

or scientific background and are especially suitable for those<br />

employees new to the company in the areas of production, development<br />

and marketing, etc. The aim of the seminars is to enable<br />

them to familiarise themselves quickly and in a targeted way with<br />

what for most is an unknown field.<br />

Module 1: Materials 1<br />

Principles of polymer chemistry; what is “rubber”? deterioration<br />

protection and fillers; plasticisers and auxiliary products; general-<br />

purpose rubber; high-performance rubbers and specialities; technical<br />

thermoplastics as metal substitutes; thermoplastic elastomers (TPE).<br />

In cooperation with the FDS Academy<br />

Module 2: Materials 2<br />

Dynamic-mechanical behaviour of polymers; bonding of rubber;<br />

practical; surface modification and tribology; liquid silicone rubber;<br />

REACH; threats and opportunities of nanotechnology; formula<br />

optimisation; technical thermoplastics as metal substitute; polyurethanes.<br />

In cooperation with the FDS Academy<br />

Module 3: processes 1<br />

Technology of mixing; visit to the rubber mixing facility, mixing<br />

process in internal mixers, alternative mixing processes; development<br />

of the mixing process; principles of vulcanisation; vulcanisation<br />

process; special processes; TPE fabrication; moulding preparation;<br />

process data processing.<br />

In cooperation with the FDS Academy<br />

Module 4: processes 2<br />

Processing following the internal mixer; scale-up; influence of the<br />

mixing process on constituent characteristics; approaches to mix-<br />

ing process optimisation; manufacture of natural rubber flooring;<br />

process optimisation in elastomers processing; finishing of mould-<br />

ed rubber parts; thorough examination of processing processes;<br />

rapid prototyping.<br />

In cooperation with the FDS Academy<br />

Module 5: products<br />

In this seminar, the developers of various product areas deal with<br />

the basic physical properties of their product groups. The participants<br />

are given a broad outline of the entire range of products<br />

of <strong>Freudenberg</strong> Seals and Vibration <strong>Co</strong>ntrol Technology and of<br />

Vibracoustic.<br />

Module 6: Mould technology and Mould Cleaning<br />

Mould steel, cold runner technology, mould coatings, physicaltechnical<br />

principles of mould cleaning, microblasting, cleaning<br />

with dry ice (including practical demonstration), laser cleaning<br />

(including practical demonstration), ultrasonic cleaning, separa-<br />

Seminars<br />

21


Location: <strong>FFD</strong> Building 32<br />

Fee: Euro 690 plus VAT<br />

Date: 16./17.10.2012<br />

Location: <strong>FFD</strong> Building 32<br />

Fee: Euro 450 plus VAT<br />

Date: 19.10.2012<br />

Location: <strong>FFD</strong> Building 32<br />

Fee: Euro 950 plus VAT<br />

Date: 22./23.01.2013<br />

Location: <strong>FFD</strong> Building 32<br />

Fee: Euro 950 plus VAT<br />

Date: 06./07.12.2012<br />

Location: <strong>FFD</strong> Building 32<br />

Fee: Euro 450 plus VAT<br />

Date: 16.11.2012<br />

22 Seminars<br />

ting agents for elastomers processing, fundamentals of mould technology,<br />

rapid tooling, design of injection molds, laser structuring.<br />

Module 7: test Methods and Analytics<br />

Static test methods, dynamic test methods, lifetime prediction,<br />

consistency tests, caloric properties, optical microscopy, scanning<br />

electron microscopy, elastomer analytics, failure analysis.<br />

seminars on Other subjects<br />

Seminar management: Dr.-Ing. Andreas Kammann<br />

From Caoutchouc to rubber – a starter seminar<br />

This seminar answers a number of basic questions on elastomer<br />

chemistry: What is rubber at all and what is caoutchouc? How is<br />

caoutchouc made into rubber? Why do so many different components<br />

become part of a rubber compound? What actually happens<br />

during moulding and vulcanisation? Why are there so many<br />

different types of caoutchouc?<br />

polyurethanes – Materials and processing<br />

Basics of polymer chemistry, raw materials for polyurethanes,<br />

processing methods (casting, R<strong>IM</strong>, injection moulding, extrusion,<br />

foaming, impregnation, etc.); mechanical and chemical properties;<br />

analytical investigations.<br />

practical seminar: Installation of an Injection-Moulding Machine and<br />

troubleshooting<br />

This seminar is aimed at all machine operators who have al-<br />

ready gained initial experience in the processing of elastomers and<br />

are, in future, to work more independently due to a more in-depth<br />

understanding of the process and assume tool setter duties. <strong>Co</strong>ntent:<br />

basics of elastomer injection moulding, practical set-up of an<br />

injection-moulding machine, fault detection and remedial measures.<br />

Industrial property rights – patents, trademarks and Designs<br />

This seminar is aimed at anyone who is involved in the development<br />

and marketing of technical products (chemical engineers,<br />

chemists, engineers, technical specialists, material developers,<br />

purchasers, sales staff and commercial administrators). <strong>Co</strong>ntent:<br />

patents, utility models, trademarks, designs, protective range of a<br />

patent or design, patent strategy.<br />

Further information<br />

on our range of seminars may be found at any time under:<br />

www.forschungsdienste.info<br />

to register, please contact:<br />

Ms. Simone Horn, tel. +49 (0)6201 - 80 48 80,<br />

fax +49 (0)6201 - 88 30 63, simone.horn@freudenberg.de<br />

We reserve the right to reject requests for registration submitted by staff from<br />

the competitors of the <strong>Freudenberg</strong> Group.


Impressum<br />

<strong>Freudenberg</strong><br />

<strong>Forschungsdienste</strong> <strong>KG</strong><br />

Published by: <strong>Freudenberg</strong> <strong>Forschungsdienste</strong> <strong>KG</strong>,<br />

69465 Weinheim<br />

Germany<br />

Editor-in-Chief: Martin Gramlich<br />

Editorial Staff: Dr. Katharina Müller, Andrea Deis,<br />

Ulrike Kast, Sabrina Lemke,<br />

Dr. Christof Schmitz,<br />

Dr. Ulrike Herrlich, Dr. Franka Geiß<br />

Layout: Ehret Design, www.ehretdesign.de<br />

<strong>Freudenberg</strong> <strong>Forschungsdienste</strong> <strong>KG</strong><br />

69465 Weinheim (an der Bergstraße)<br />

Telefon +49(0)6201 80-5123<br />

E-Mail ffd@freudenberg.de<br />

www.forschungsdienste.de<br />

23

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