178[63] M.-F. Joubert. \Photon avalanche upconversion in <strong>rare</strong> <strong>earth</strong> laser materials."Opt. Mat., 11, 181, 1999.[64] D. S. Funk <strong>and</strong> J. G. Eden. \Glass-ber lasers in the ultraviolet <strong>and</strong> visible."IEEE J. Sel. Top. Quant. Elec., 1, 784, 1995.[65] J. P. van der Ziel, F. W. Ostermayer, <strong>and</strong> L. G. Van Uitert. \Inf<strong>rare</strong>d Excitation<strong>of</strong> Visible Luminescence in Y 1Rev. B., 2, 4432, 1970.x Er x F 3 via Resonant Energy Transfer." Phys.[66] R. Rolli, M. Montagna, A. Chiasera, G. C. Righini, S. Pelli, A. Jha, V. K.Tikhomirov, S. A. Tikhomirova, A. Monteil, S. Chaussedent, <strong>and</strong> M. Ferrari.\A comparative study <strong>of</strong> the spectroscopic properties at 1.5 m <strong>of</strong> erbiumactivateduoride <strong>and</strong> tellurite glasses." Phil. Mag. B., 82, 573, 2002.[67] T. Catunda, L. A. O. Nunes, A. Florez, Y. Messaddeq, <strong>and</strong> M. A. Aegerter.\Spectroscopic properties <strong>and</strong> upconversion mechanisms in Er 3+ -<strong>doped</strong> uoroindateglasses." Phys. Rev. B., 53, 6065, 1996.[68] M. D. Shinn, W. A. Sibley, M. G. Drexhage, <strong>and</strong> R. N. Brown. \Opticaltransitions <strong>of</strong> Er 3+ ions in uorozirconate glass." Phys. Rev. B., 27, 6635,1983.[69] C. Florea <strong>and</strong> K. A. Winick. \Ytterbium-<strong>doped</strong> glass waveguide laser fabricatedby ion exchange." J. Lightwave Technol., 17, 1593, 1999.[70] A. Florez, Y. Messaddeq, O. L. Malta, <strong>and</strong> M. A. Aegerter. \Optical transitionprobabilities <strong>and</strong> compositional dependence <strong>of</strong> Judd-Ofelt parameters <strong>of</strong> Er 3+ions in uoroindate glass." J. Alloys Compounds, 227, 135, 1995.[71] R. M. Martin <strong>and</strong> R. S. Quimby. \Experimental evidence <strong>of</strong> the validity <strong>of</strong> theMcCumber theory relating emission <strong>and</strong> absorption for <strong>rare</strong>-<strong>earth</strong> glasses." J.Opt. Soc. B, 23, 1770, 2006.
179[72] S. R. Bullock, B. R. Reddy, P. Venkateswarlu, S. K. Nash-Stevenson, <strong>and</strong> J.C. Fajardo. \Energy upconversion <strong>and</strong> spectroscopic studies <strong>of</strong> ZBLAN:Er 3+ ."Opt. Quant. Electron., 29, 83, 1997.[73] M. J. Weber. \Probabilities for radiative <strong>and</strong> nonradiative decay <strong>of</strong> Er 3+ inLaF 3 ." Phys. Rev., 157, 262, 1967.[74] W. T. Carnall, P. R. Fields, <strong>and</strong> K. Rajnak. \Electronic energy levels in thetrivalent lanthanide aquo ions. I. Pr 3+ , Nd 3+ , Pm 3+ , Sm 3+ , Dy 3+ , Ho 3+ , Er 3+ ,<strong>and</strong> Tm 3+ ." J. Chem. Phys., 49, 4424, 1968.[75] J. Yang, S. Dai, N. Dai, L. Wen, L. Hu, <strong>and</strong> Z. Jiang. \Investigation onnonradiative decay <strong>of</strong> 4 I 13=2 ! 4 I 15=2 transition <strong>of</strong> Er 3+ -<strong>doped</strong> oxide glasses."J. Lumin., 9, 106, 2004.[76] P. W. France, M. G. Drexhage, J. M. Parker, M. W. Moore, S. F. Carter, <strong>and</strong>J. V. Wright. Fluoride Glass Optical Fibres. Florida, 1990.[77] C. L. Pope, B. R. Reddy, <strong>and</strong> S. K. Nash-Stevenson. \Ecient violet upconversionsignal from a uoride ber <strong>doped</strong> with erbium." Opt. Lett., 22, 295,1997.[78] L. F. Johnson, J. E. Geusic, H. J. Guggenheim, T. Kushida, S. Singh, <strong>and</strong> L.G. van Uitert. \Comments on materials for ecient inf<strong>rare</strong>d conversion." Appl.Phys. Lett., 15, 48, 1969.[79] H. Xu <strong>and</strong> Z. Jiang. \Ultraviolet <strong>and</strong> violet upconversion luminescence in Er 3+ -<strong>doped</strong> yttrium aluminum garnet crystals." Phys. Rev. B., 66, 035103, 2002.[80] F. Vetrone, J.-C. Boyer, J. A. Capobianco, A. Speghini <strong>and</strong> M. Bettinelli. \980nm excited upconversion in an Er-<strong>doped</strong> ZnOTeO 2 glass." Appl. Phys. Lett.,80, 1752, 2002.
- Page 1 and 2:
OPTICAL CHARACTERISATION OF RARE-EA
- Page 3:
Table of ContentsAcknowledgementsLi
- Page 6 and 7:
AcknowledgementsThe work in this th
- Page 8 and 9:
viiiList of Publications[1] J. Ward
- Page 10 and 11:
xTo the best of our knowledge, this
- Page 12 and 13:
xiiWDMWGMZBNAZBLALiPZBLANWavelength
- Page 14 and 15:
xiv1.6 Fundamental light-matter int
- Page 16 and 17:
xvi3.8 Gain coecient for dierent po
- Page 18 and 19:
xviii4.9 Fluorescence slopes and sp
- Page 20 and 21:
xxList of Tables1.1 Rigorous select
- Page 22 and 23:
2device size (typically < 200 m dia
- Page 24 and 25:
4a wider range of materials can exh
- Page 26 and 27:
6in Chapter 2: angle-polished bres
- Page 28 and 29:
81.2 Whispering Gallery ModesWhispe
- Page 30 and 31:
10where j l (h (1)l) are spherical
- Page 32 and 33:
12(a)(b)Figure 1.2: Calculated inte
- Page 34 and 35:
14parameter, x nl , up to order =
- Page 36 and 37:
16coecient of water. There is an a
- Page 38 and 39:
18(a) Silica glass(b) ZBLALiP glass
- Page 40 and 41:
20eld (Eqn. 1.2) over a quantisatio
- Page 42 and 43:
221.7 Spectroscopy of Rare Earth Io
- Page 44 and 45:
241.9 Radiative Emission RatesIn th
- Page 46 and 47:
261.10 Material Loss Mechanisms in
- Page 48 and 49:
28Chapter 2Fabrication of and Coupl
- Page 50 and 51:
30Figure 2.1: Microsphere fabricati
- Page 52 and 53:
32Figure 2.3:Schematic of (a) taper
- Page 54 and 55:
34Figure 2.4: Calculated polish ang
- Page 56 and 57:
36bre, the exact electric eld equat
- Page 58 and 59:
38Figure 2.6: Poynting vector for a
- Page 60 and 61:
40a few dozen tapered bres.As an al
- Page 62 and 63:
42Figure 2.7: Schematic of the tape
- Page 64 and 65:
44Figure 2.8: Taper prole for a 3 m
- Page 66 and 67:
46taper angle, the light in the pro
- Page 68 and 69:
48Figure 2.10: Optical micrograph o
- Page 70 and 71:
50controlled. The discrete step-siz
- Page 72 and 73:
52In recent years, much eort has be
- Page 74 and 75:
543.2 ZBLALiP Material PropertiesWe
- Page 76 and 77:
56Figure 3.3: Er 3+ energy level di
- Page 78 and 79:
58(Avanex, 1998 PLM) with a spectra
- Page 80 and 81:
60Figure 3.6: 66 m diameter microsp
- Page 82 and 83:
62(a) C-band(b) Pump bandFigure 3.7
- Page 84 and 85:
64as Judd-Ofelt (JO) analysis [72]-
- Page 86 and 87:
66The total spontaneous radiative t
- Page 88 and 89:
68Table 3.2: Predicted radiative tr
- Page 90 and 91:
70Figure 3.9: Observed Er 3+ :ZBLAL
- Page 92 and 93:
72pumping at 637 nm [77]. The same
- Page 94 and 95:
74Figure 3.10: Calculated fraction
- Page 96 and 97:
76Figure 3.11: Light in-Light out l
- Page 98 and 99:
78representing the Q of the cavity.
- Page 100 and 101:
80Figure 3.13: Quality factor measu
- Page 102 and 103:
82Chapter 4Thermally Induced Optica
- Page 104 and 105:
84especially benecial for C-band la
- Page 106 and 107:
86note three distinct emission band
- Page 108 and 109:
88therefore a combination of the in
- Page 110 and 111:
90This is close to the value of 2.1
- Page 112 and 113:
92Figure 4.4: Lasing spectrum for a
- Page 114 and 115:
94Figure 4.6: Intensity bistability
- Page 116 and 117:
96Figure 4.7: Chromatic switching f
- Page 118 and 119:
98equation, given byl = 2n s d 1 +
- Page 120 and 121:
100Figure 4.9: Fluorescence slopes
- Page 122 and 123:
102and the Kerr eect immediately, b
- Page 124 and 125:
104a precise setting for each spher
- Page 126 and 127:
106Figure 4.11: Graphical descripti
- Page 128 and 129:
108explanation for the peak in the
- Page 130 and 131:
110and the associated wheatstone br
- Page 132 and 133:
112performance have made them an in
- Page 134 and 135:
114laser slightly above threshold.
- Page 136 and 137:
116range is shown in Fig. 5.3(a). S
- Page 138 and 139:
118Chapter 6ConclusionsThis project
- Page 140 and 141:
120work. The reason for choosing 80
- Page 142 and 143:
122Appendix ASpectral Characterisat
- Page 144 and 145:
In this paper we will give an overv
- Page 146 and 147:
1.:1.21.21.11.10.90.60.70.60.90.60.
- Page 148 and 149: ⎥⎦2.2 Mode matching between a m
- Page 150 and 151: Puill lengtln (iuniuncurrents or ot
- Page 152 and 153: 1.6x10 -71.4x10 -7IOG-2intensity (a
- Page 154 and 155: 134Appendix BA Heat-and-Pull Rig fo
- Page 156 and 157: 083105-2 Ward et al. Rev. Sci. Inst
- Page 158 and 159: 083105-4 Ward et al. Rev. Sci. Inst
- Page 160 and 161: 140Appendix CUpconversion Channels
- Page 162 and 163: 2 The European Physical Journal App
- Page 164 and 165: 4 The European Physical Journal App
- Page 166 and 167: 6 The European Physical Journal App
- Page 168 and 169: 8 The European Physical Journal App
- Page 170 and 171: 150
- Page 172 and 173: 152
- Page 174 and 175: JOURNAL OF APPLIED PHYSICS 102, 023
- Page 176 and 177: 023104-3 Ward et al. J. Appl. Phys.
- Page 178 and 179: 023104-5 Ward et al. J. Appl. Phys.
- Page 180 and 181: 023104-7 Ward et al. J. Appl. Phys.
- Page 182 and 183: 162
- Page 184 and 185: 164
- Page 186 and 187: 166
- Page 188 and 189: 168
- Page 190 and 191: Figure F.1: Electrical wiring diagr
- Page 192 and 193: 172[9] J. Z. Zhang and R. K. Chang.
- Page 194 and 195: 174[28] C. C. Lam, P. T. Leung and
- Page 196 and 197: 176[45] F. Le Kien, J. Q. Liang, K.
- Page 200 and 201: 180[81] A. Biswas, G. S. Maciel, C.
- Page 202 and 203: 182[98] M. Ajroud, M. Haouari, H. B
- Page 204: 184[116] L. Ricci, M. Weidemuller,