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Catalytic Reductive Coupling Reactions - Michigan State University

Catalytic Reductive Coupling Reactions - Michigan State University

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<strong>Reductive</strong> Condensation ContinuedPredictedOPhOPhOPhOHPhExperimentalPhOOPhRh(COD) 2 OTf (5 mol%)BIPHEP (5 mol%)DCE (0.1 M), 25 o CD 2 (1 atm)DPhOHOPhNo Basic Additives Needed--Heterolytic Hydrogen Activation??Jang, H.; Huddleston, R.; Krische, M. J. Am. Chem. Soc. 2004, 126, 4664—4668.

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