Catalytic Reductive Coupling Reactions - Michigan State University
Catalytic Reductive Coupling Reactions - Michigan State University
Catalytic Reductive Coupling Reactions - Michigan State University
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Hydrogen-Mediated C-C Bond FormationHomolytic activation of H 2HH MLnH HHC-H reductiveXR 1 MLn eliminationR 1 HR 2 X R 2R 1 LnM XH 2 (1atm)R 2 M X (cat)Heterolytic activation of H 2H XHXR 1 MLnR 1H MLnR 2 R 2(H-X, base)H R 3 H 2ConventionalreductionMLnR 3XR 1 LnM XH R 3 R 3R 2MLnR 1R 2Homolytic activation of H 2H 2H MLnR 1 HR 2 XHR 3C-C bondformationMLnJang, H.; Krische, M. Acc. Chem. Res. 2004, 37, 653—661.
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