13.07.2015 Views

Catalytic Reductive Coupling Reactions - Michigan State University

Catalytic Reductive Coupling Reactions - Michigan State University

Catalytic Reductive Coupling Reactions - Michigan State University

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

<strong>Reductive</strong> Cyclization of DiynesXR 1R 2Rh(COD) 2 OTf (3 mol%)rac-BINAP or BIPHEP (3 mol%)DCE (0.1M), 25 o CH 2 (1 atm)XR 1R 2PhPhPhCH 3H 3 CO 2 CH 3 CO 2 COPhPhPh1b, 85% 2b, 78% 3b, 89%TsN4b, 62%CH 3EEPhPhRh(COD) 2 OTf (5 mol%)BIPHEP (5 mol%)DCE (0.1 M), 25 o CD 2 (1 atm)EEPhDDPhJang, H.; Krische, M. J. Am. Chem. Soc. 2004, 126, 7875—7880.

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!