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“It also simplifies things. There are less<br />

solids moving through the plant be<strong>ca</strong>use<br />

you’ve added less salt that precipitates<br />

those solids.”<br />

The precipitated particles are recycled<br />

and used again and again until they<br />

reach their phosphate removal <strong>ca</strong>pacity.<br />

Recycling with shear to break the particles<br />

apart and expose the inner surfaces<br />

binds even more phosphate. A solid/<br />

liquid separation completes the process.<br />

“Smaller particles have a greater<br />

surface area,” Smith points out.<br />

“Nanoparticles would work great for<br />

treatment, except that they are a lot<br />

harder to separate. He adds that if the<br />

only change treatment plants made was to<br />

increase mixing during chemi<strong>ca</strong>l addition,<br />

there would already be a potential 50%<br />

to 80% increase in phosphate removal.<br />

Recycling and shearing would bring it<br />

down another 10% to 20%, an important<br />

consideration when trying to meet strict<br />

discharge limits such as those set for<br />

particularly sensitive water bodies such<br />

as Lake Simcoe.<br />

The fundamental challenge is to<br />

get the word out and convince both<br />

engineers and operators that surface<br />

complexation is in fact at the centre for<br />

the chemi<strong>ca</strong>l phosphate removal process.<br />

Smith believes that the WEAO has an<br />

important role to play in meeting that<br />

challenge. In 2012, the Association<br />

invited him to its Nutrient Removal<br />

Conference to present his findings.<br />

“It’s basi<strong>ca</strong>lly about letting people know<br />

that you <strong>ca</strong>n do things slightly differently<br />

than you have been doing them and get<br />

good returns,” he explains. “Those types<br />

of communi<strong>ca</strong>tion efforts are huge.”<br />

He adds that it is important to expose<br />

young highly qualified personnel (HQP)<br />

to cutting edge science so that when they<br />

are in the role of operating, designing<br />

WWTPs or writing permit appli<strong>ca</strong>tions,<br />

they <strong>ca</strong>n apply this knowledge.<br />

At the same time, members of the<br />

EnviroSim/Laurier team, including<br />

Smith, have been involved in workshops<br />

in Baltimore, Dallas, Chi<strong>ca</strong>go, Miami,<br />

Seattle and Waterloo, attended by<br />

world-renowned a<strong>ca</strong>demic experts and<br />

consulting engineers. The team’s past<br />

10 years of work has also yielded 11<br />

conference proceedings, 10 conference<br />

presentations, four techni<strong>ca</strong>l reports,<br />

nine workshop presentations, eight<br />

invited presentations (including several<br />

international requests), three peerreviewed<br />

papers, one non-peer reviewed<br />

article (in the Summer 2011 issue of<br />

INFLUENTS) and one book chapter<br />

in a widely used wastewater manual<br />

of practice.<br />

All these results have been gratifying,<br />

but the greatest reward, says Smith, has<br />

been the appli<strong>ca</strong>tion of his research.<br />

“When you look back on your <strong>ca</strong>reer,”<br />

he explains, “you don’t simply want to<br />

count papers and research dollars. You<br />

want to think you had some real impact.<br />

As an applied chemist, you want to<br />

apply your chemistry to finding solutions<br />

that are useful and worthwhile.”<br />

That has certainly been the <strong>ca</strong>se so<br />

far, and Smith’s research in this area is<br />

far from over.<br />

The mid-<strong>ca</strong>reer chemist plans to<br />

continue his quest to achieve ever-lower<br />

concentrations of phosphorus in<br />

treated effluent. His current work<br />

includes not only research on enzymes<br />

and nano-particles, but also the<br />

removal of non-reactive phosphorus.<br />

Phosphorus occurs in many<br />

different forms. To achieve lower total<br />

phosphorus levels, it is necessary to<br />

convert non-reactive phosphorus into<br />

reactive phosphorus so it <strong>ca</strong>n be removed<br />

using conventional tertiary treatment<br />

methods, where such methods <strong>ca</strong>n now<br />

be optimized using our new knowledge<br />

of surface complexation mechanisms<br />

As new legislation requires WWTPs<br />

to meet increasingly lower discharge<br />

criteria for phosphorus, this research<br />

will become even more criti<strong>ca</strong>l. There is<br />

no doubt that the work of Smith and<br />

his team will continue to have an<br />

impact on the wastewater industry<br />

– and on protecting our environment –<br />

for many years to come.<br />

It is difficult to overestimate the impact this large project<br />

and specifi<strong>ca</strong>lly Scott’s contribution for the environmental<br />

industry – the use [of] proper chemi<strong>ca</strong>l equilibrium is now<br />

the standard in wastewater treatment plant modelling.<br />

[C]hemi<strong>ca</strong>l dosage points and dose <strong>ca</strong>n be optimized,<br />

saving millions of dollars in design and operations costs<br />

and reducing <strong>ca</strong>rbon foot print of these utilities.<br />

– Dr. Imre Takács, CEO of Dynamita SARL,<br />

a leading environmental process modeling company from France.<br />

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Click HERE to return to Table of contents<br />

INFLUENTS<br />

Fall 2015<br />

9

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