Iraqi Kurdistan All in the Timing
GEO_ExPro_v12i6
GEO_ExPro_v12i6
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High quality analyses and consult<strong>in</strong>g services to <strong>the</strong> oil <strong>in</strong>dustry<br />
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collected from gas samples from <strong>the</strong> platform seemed to<br />
<strong>in</strong>dicate that <strong>the</strong> source was microbiological. Prelim<strong>in</strong>ary<br />
data <strong>the</strong>n seemed contradictory, and it was not clear what<br />
<strong>the</strong> source actually was. A more thorough <strong>in</strong>vestigation was<br />
authorised that <strong>in</strong>volved <strong>the</strong> collection and analysis of gas,<br />
water, and oil samples from multiple locations. This more<br />
comprehensive data set revealed that H 2 S of non-biological<br />
orig<strong>in</strong> was present <strong>in</strong> some production fluids obta<strong>in</strong>ed<br />
directly from wellhead and primary separator samples, but<br />
H 2 S of biological orig<strong>in</strong> was also present <strong>in</strong> many samples<br />
obta<strong>in</strong>ed from <strong>the</strong> topside water handl<strong>in</strong>g system.<br />
This case study demonstrated that only by obta<strong>in</strong><strong>in</strong>g<br />
comprehensive data from multiple samples that <strong>in</strong>cluded H 2 S<br />
quantification, sulphur isotopic ratios <strong>in</strong> gas and water samples,<br />
microbiological data from growth and genetic test<strong>in</strong>g, and<br />
water chemistry test<strong>in</strong>g to quantify organic acids was it possible<br />
to conclude that <strong>the</strong>re were two sources of H 2 S <strong>in</strong> samples<br />
from this offshore platform. The oil company now knows that<br />
<strong>the</strong>rmogenic H 2 S is migrat<strong>in</strong>g <strong>in</strong>to <strong>the</strong> oil production reservoir<br />
and that <strong>the</strong> topside water-handl<strong>in</strong>g system is vulnerable to<br />
microbial contam<strong>in</strong>ation, and it can plan accord<strong>in</strong>gly.<br />
Chemical or Biological?<br />
The confusion regard<strong>in</strong>g <strong>the</strong> source of <strong>the</strong> H 2 S resulted<br />
from sample collection by field production personnel who<br />
were not experienced <strong>in</strong> reservoir sour<strong>in</strong>g, geochemistry, or<br />
microbiology. After rout<strong>in</strong>e monitor<strong>in</strong>g of gas stream samples<br />
revealed detectable concentrations of H 2 S at a location on <strong>the</strong><br />
oil platform, <strong>the</strong> result was confirmed with additional field<br />
measurements. Management subsequently requested that <strong>the</strong><br />
oil production personnel should collect H 2 S samples us<strong>in</strong>g an<br />
Isotrap and <strong>the</strong>y should perform additional field measurements<br />
of H 2 S at various locations on <strong>the</strong> platform. The source of H 2 S<br />
(from chemical or from biological processes) can often be<br />
determ<strong>in</strong>ed by quantify<strong>in</strong>g <strong>the</strong> amounts of <strong>the</strong> stable isotopes<br />
of sulphur, chiefly 32 S and 34 S. Chemical processes generally do<br />
not discrim<strong>in</strong>ate between isotopes, whereas biochemical and<br />
microbiological processes have a preference for 32 S. Therefore,<br />
if a reaction product is depleted <strong>in</strong> 34 S as compared with <strong>the</strong><br />
start<strong>in</strong>g material, <strong>the</strong>n <strong>the</strong> reaction can be determ<strong>in</strong>ed to be<br />
biochemical.<br />
The analyses to quantify <strong>the</strong> various stable isotopes of<br />
sulphur require a sufficient mass of H 2 S, and <strong>the</strong> Isotrap device<br />
is designed to collect <strong>the</strong> necessary amount. When <strong>the</strong> Isotrap<br />
was placed on <strong>the</strong> gas outlet of <strong>the</strong> separator serv<strong>in</strong>g <strong>the</strong> well<br />
where H 2 S had been observed, it failed to completely fill <strong>the</strong><br />
device over a period of a few hours. However, dur<strong>in</strong>g that time it<br />
was determ<strong>in</strong>ed that higher H 2 S concentrations were detected at<br />
a nearby location <strong>in</strong> <strong>the</strong> water treatment system, which received<br />
water from this separator. When <strong>the</strong> Isotrap was moved to this<br />
location it filled quickly and was <strong>the</strong>n sent to <strong>the</strong> laboratory. The<br />
amount of 34 S present <strong>in</strong> this sample was 8.3‰, a value that is<br />
relatively low and was <strong>in</strong>terpreted to be possibly consistent with<br />
microbiologically produced H 2 S, foster<strong>in</strong>g concern with<strong>in</strong> <strong>the</strong><br />
GEOExPro November 2015 61