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Our scientific staff cover a wide range of expertise ga<strong>in</strong>ed from many parts of <strong>the</strong> globe, deal<strong>in</strong>g with many and varied<br />

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experience provides a competitive edge ito our services. We offer complete services with<strong>in</strong> <strong>the</strong> discipl<strong>in</strong>es of Petroleum<br />

Geochemistry, Biostratigraphy and Petroleum Systems Analysis, and our customers expect high standards of quality <strong>in</strong> both<br />

analysis and report<strong>in</strong>g.<br />

High quality analyses and consult<strong>in</strong>g services to <strong>the</strong> oil <strong>in</strong>dustry<br />

Geochemistry services<br />

In addition to provid<strong>in</strong>g a full range of geochemical<br />

analyses of unsurpassed quality analysis, APT also<br />

offers <strong>in</strong>sightful and tailor-made <strong>in</strong>terpretation,<br />

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and flexibility, and perform analyses and report<br />

results to our clients’ specifications.<br />

Biostratigraphic analysis and services<br />

APT delivers a full range of biostratigraphic services,<br />

rang<strong>in</strong>g from s<strong>in</strong>gle well reports and reviews of exist<strong>in</strong>g<br />

data to full-scale field or bas<strong>in</strong>-wide evaluations. We take<br />

no established truths for granted, and we turn every stone<br />

<strong>in</strong> <strong>the</strong> attempt to br<strong>in</strong>g <strong>the</strong> stratigraphic knowledge a few<br />

steps forward.<br />

Petroleum systems analysis<br />

APT has ga<strong>in</strong>ed extensive experience <strong>in</strong> Petroleum<br />

Systems Analysis us<strong>in</strong>g <strong>the</strong> ”PetroMod” suite of programs.<br />

Projects range from simple 1d model<strong>in</strong>g of a set of wells to<br />

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expulsion, and migration and accumulation issues to be<br />

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Geochemistry services<br />

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• 24 hours Hot Shot analysis<br />

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Petroleum System Analysis<br />

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• PetroMod or o<strong>the</strong>r tools<br />

APT- Applied Petroleum Technology Group<br />

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collected from gas samples from <strong>the</strong> platform seemed to<br />

<strong>in</strong>dicate that <strong>the</strong> source was microbiological. Prelim<strong>in</strong>ary<br />

data <strong>the</strong>n seemed contradictory, and it was not clear what<br />

<strong>the</strong> source actually was. A more thorough <strong>in</strong>vestigation was<br />

authorised that <strong>in</strong>volved <strong>the</strong> collection and analysis of gas,<br />

water, and oil samples from multiple locations. This more<br />

comprehensive data set revealed that H 2 S of non-biological<br />

orig<strong>in</strong> was present <strong>in</strong> some production fluids obta<strong>in</strong>ed<br />

directly from wellhead and primary separator samples, but<br />

H 2 S of biological orig<strong>in</strong> was also present <strong>in</strong> many samples<br />

obta<strong>in</strong>ed from <strong>the</strong> topside water handl<strong>in</strong>g system.<br />

This case study demonstrated that only by obta<strong>in</strong><strong>in</strong>g<br />

comprehensive data from multiple samples that <strong>in</strong>cluded H 2 S<br />

quantification, sulphur isotopic ratios <strong>in</strong> gas and water samples,<br />

microbiological data from growth and genetic test<strong>in</strong>g, and<br />

water chemistry test<strong>in</strong>g to quantify organic acids was it possible<br />

to conclude that <strong>the</strong>re were two sources of H 2 S <strong>in</strong> samples<br />

from this offshore platform. The oil company now knows that<br />

<strong>the</strong>rmogenic H 2 S is migrat<strong>in</strong>g <strong>in</strong>to <strong>the</strong> oil production reservoir<br />

and that <strong>the</strong> topside water-handl<strong>in</strong>g system is vulnerable to<br />

microbial contam<strong>in</strong>ation, and it can plan accord<strong>in</strong>gly.<br />

Chemical or Biological?<br />

The confusion regard<strong>in</strong>g <strong>the</strong> source of <strong>the</strong> H 2 S resulted<br />

from sample collection by field production personnel who<br />

were not experienced <strong>in</strong> reservoir sour<strong>in</strong>g, geochemistry, or<br />

microbiology. After rout<strong>in</strong>e monitor<strong>in</strong>g of gas stream samples<br />

revealed detectable concentrations of H 2 S at a location on <strong>the</strong><br />

oil platform, <strong>the</strong> result was confirmed with additional field<br />

measurements. Management subsequently requested that <strong>the</strong><br />

oil production personnel should collect H 2 S samples us<strong>in</strong>g an<br />

Isotrap and <strong>the</strong>y should perform additional field measurements<br />

of H 2 S at various locations on <strong>the</strong> platform. The source of H 2 S<br />

(from chemical or from biological processes) can often be<br />

determ<strong>in</strong>ed by quantify<strong>in</strong>g <strong>the</strong> amounts of <strong>the</strong> stable isotopes<br />

of sulphur, chiefly 32 S and 34 S. Chemical processes generally do<br />

not discrim<strong>in</strong>ate between isotopes, whereas biochemical and<br />

microbiological processes have a preference for 32 S. Therefore,<br />

if a reaction product is depleted <strong>in</strong> 34 S as compared with <strong>the</strong><br />

start<strong>in</strong>g material, <strong>the</strong>n <strong>the</strong> reaction can be determ<strong>in</strong>ed to be<br />

biochemical.<br />

The analyses to quantify <strong>the</strong> various stable isotopes of<br />

sulphur require a sufficient mass of H 2 S, and <strong>the</strong> Isotrap device<br />

is designed to collect <strong>the</strong> necessary amount. When <strong>the</strong> Isotrap<br />

was placed on <strong>the</strong> gas outlet of <strong>the</strong> separator serv<strong>in</strong>g <strong>the</strong> well<br />

where H 2 S had been observed, it failed to completely fill <strong>the</strong><br />

device over a period of a few hours. However, dur<strong>in</strong>g that time it<br />

was determ<strong>in</strong>ed that higher H 2 S concentrations were detected at<br />

a nearby location <strong>in</strong> <strong>the</strong> water treatment system, which received<br />

water from this separator. When <strong>the</strong> Isotrap was moved to this<br />

location it filled quickly and was <strong>the</strong>n sent to <strong>the</strong> laboratory. The<br />

amount of 34 S present <strong>in</strong> this sample was 8.3‰, a value that is<br />

relatively low and was <strong>in</strong>terpreted to be possibly consistent with<br />

microbiologically produced H 2 S, foster<strong>in</strong>g concern with<strong>in</strong> <strong>the</strong><br />

GEOExPro November 2015 61

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