Handbook of Functionalized Organometallics Applications in S

References
Nickel-catalyzed hydroamination of conjugated dienes at room temperature has
been shown to be an efficient synthesis of allylamines in excellent yields [262].
10.10
Conclusion
+ HNMeBn Ni(COD) 2/DPPF, TFA
94%
NMeBn
Over the past two decades,the use of organonickel chemistry in organic synthesis
has evolved into a new era. A wealth of fascinating work has attested to the wide
popularity using this metal in organic synthesis. Not only have the traditional
cross-coupling reactions reached a new stage,but also new multi-component coupling
processes have provided powerful arsenal for the synthesis of complex molecules.
The mechanistic insight of these reactions can pave the way to make predictions
of other opportunities for new transformations and room for new inventions
emanating from the present results abound. In particular,given the reactivity
trends of nickel reagents or catalysts and functional-group tolerance,such a prospect
provides a major impetus for continuing the use of organonickel compounds
in organic synthesis.
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