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Evaluation of Bioassays and Wastewater Quality ... - Oekotoxzentrum

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Table 9: Saccharomyces cerevisiae, estrogen receptor binding: Estradiol equivalent concentration, EEQ [ng/L] (SD in brackets), elimination efficiency [%] <strong>and</strong> change index<br />

(CITEQ) for the respective treatment steps. EN Entrée STEP, SB Sortie biologie (1 st MC), LF Lit fluidisé (2 rd - 4 th MC), OZ Sortie O3, CAG Sortie charbon actif granulé (1 st - 2 nd<br />

MC), SF Sortie filtre à sable (3 rd - 4 th MC), PAC-UF Sortie charbon actif en poudre - Ultrafiltration (2 nd - 4 th MC). n.m. not measured.<br />

Date<br />

Ozone<br />

dosage<br />

(mgO3<br />

gDO C -1 )<br />

PAC conc.<br />

(mg PAC/L<br />

wastewater)<br />

EN<br />

SB<br />

LF<br />

Elimination<br />

Biology<br />

(%)<br />

Effect<br />

Biology<br />

Swiss Centre for Applied Ecotoxicology, Eawag/EPFL · Überl<strong>and</strong>strasse 133 · CH-8600 Dübendorf www.oekotoxzentrum.ch<br />

OZ<br />

Elimination<br />

OZ (%)<br />

Effect<br />

OZ<br />

CAG<br />

SF<br />

Elimination<br />

OZ + SF<br />

(%)<br />

Effect<br />

OZ +<br />

SF<br />

PAC-<br />

UF<br />

Elimination<br />

PAC-UF<br />

(%)<br />

Effect<br />

PAC-<br />

UF<br />

Overall<br />

Elimination<br />

Ozonation<br />

20.-27.07.09 0.5 No PAC 48.68 12.00 75% 4.06 0.27 98% 44.87 3.08 74% 3.89 n.m. - - 99% -<br />

(4.25) (0.88) (0.09) (0.59)<br />

30.10.-05.11.09 0.7 10 (Norit) 100.55 0.68 99% 147.04 0.10 85% 6.53 11.43 -1571% 0.06 0.29 58% 2.35 100% 100%<br />

(12.03) (0.12) (0.05) (0.56) (0.09)<br />

10.-17.03.10 0.8 12 (Sorbopor) 61.68 8.34 86% 7.39 0.65 92% 12.77 3.26 61% 2.56 1.32 84% 6.31 99% 98%<br />

(6.82) (0.47) (0.12) (0.33) (0.28)<br />

25.05.-02.06.10 0.11 20 (Sorbopor) 37.15 3.03 92% 12.25 0.27 91% 11.34 0.23 92% 13.04 0.29 90% 10.32 99% 99%<br />

(2.42) (0.51) (0.01) (0.08) (0.08)<br />

Overall<br />

Elimination<br />

PAC-UF<br />

Table 10: ER CALUX, estrogen receptor binding: Estradiol equivalent concentration, EEQ [ng/L] (SD in brackets), elimination efficiency [%] <strong>and</strong> change index (CITEQ) for the<br />

respective treatment steps. LOD agonism = 0.03 ng 17ß-estradiol equivalents/l water. EN Entrée STEP, SB Sortie biologie (1 st MC), LF Lit fluidisé (2 nd - 4 th MC), OZ Sortie<br />

O3, CAG Sortie charbon actif granulé (1 st - 2 nd MC), SF Sortie filtre à sable (3 rd - 4 th MC), PAC-UF Sortie charbon actif en poudre - Ultrafiltration (2 nd - 4 th MC). n.m. not<br />

measured.<br />

Date<br />

Ozone<br />

dosage<br />

(mgO3<br />

gDOC -1 )<br />

PAC conc.<br />

(mg PAC/L<br />

wastewater)<br />

EN<br />

SB<br />

LF<br />

Elimination<br />

Biology<br />

(%)<br />

Effect<br />

Biology<br />

OZ<br />

Eliminatio<br />

n OZ (%)<br />

Effect<br />

OZ<br />

CAG<br />

SF<br />

Eliminatio<br />

n OZ +<br />

SF (%)<br />

Effect<br />

OZ +<br />

SF<br />

PAC<br />

-UF<br />

Elimination<br />

PAC-UF<br />

(%)<br />

Effect<br />

PAC-<br />

UF<br />

Overall<br />

Elimination<br />

Ozonation<br />

Overall<br />

Elimination<br />

PAC-UF<br />

20.-27.07.09 0.5 No PAC 24.50 6.70 73% 3.66 0.14 98% 47.86 1.45 78% 4.62 n.m. - - 99% -

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