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8 Literatur Peter Warneck, Chemistry of the Natural Atmosphere, Acadamic Press, Inc., 1988 E. Meszaros, Atmospheric Chemistry, Elsevier, 1981 John Seinfeld and Spyros Pandis, Atmospheric Chemistry and Physics, John Wileyd Sons, 1998 Detlev Möller, Luft, Chemie Physik Biologie Reinhaltung Recht, Walter de Gruyter, 2003 Richard Wayne, Chemistry of Atmospheres, Clarendon Press, 1993 Peter Hobbs, Basic physical Chemistry for the Atmospheric Sciences, Cambridge Univ. Press, 1995 Junge, Air Chemistry and Radioactivity, Academic Press, 1963 Block-Kurs Luftchemie <strong>Berlin</strong>, 19-23 März 2007
9 Block-Kurs Luftchemie <strong>Berlin</strong>, 19-23 März 2007
Page 1 and 2: Block-Kurs Luftchemie 19 - 23 März
Page 3 and 4: 3 Ziel von der Block-Kurs Einführu
Page 5 and 6: 5 Struktur des Kurses (2) Donnersta
Page 7: 7 I) Entwicklung der Zusammensetzun
Page 11 and 12: 11 Formation and evolution of the a
Page 13 and 14: 13 Block-Kurs Luftchemie Berlin, 19
Page 17 and 18: 17 Development of the earth atmosph
Page 19 and 20: 19 Averaged composition of volcanic
Page 21 and 22: 21 Formation of O 2 in the atmosphe
Page 25 and 26: 25 Live on earth started in a reduc
Page 27 and 28: 27 Respiration: C n H m O p + O 2
Page 29 and 30: 29 Air Ocean Block-Kurs Luftchemie
Page 31 and 32: 31 Figures from: The revenge of Gai
Page 33 and 34: 33 Block-Kurs Luftchemie Figure 2:
Page 35 and 36: 35 Doom-scenario II New micro-organ
Page 37 and 38: 37 Wissenschaftliche Frage Wie wahr
Page 39 and 40: 39 Aerosols and Cloud Condensation
Page 41 and 42: 41 Also used, especially in air qua
Page 43 and 44: 43 Emission : Anthropogenic and/or
Page 47 and 48: 47 Relative Standard Deviation 10 2
Page 51 and 52: 51 Turbulent diffusion / Eddy diffu
Page 57 and 58: 57 Chemical reactions occur by addi
Page 59 and 60:
59 Block-Kurs Luftchemie Berlin, 19
Page 61 and 62:
Page 63 and 64:
63 σ ab (λ) : Absorption cross-se
Page 65 and 66:
Page 67 and 68:
Page 69 and 70:
Page 71 and 72:
71 At 55 ° N January 360 DU Block-
Page 73 and 74:
73 Formation of stratosphere O 3 O
Page 75 and 76:
75 n 1 : conc. O n 2 : conc. O 2 n
Page 77 and 78:
77 Theory of Chapman (1932) From th
Page 79 and 80:
79 O 3 “residence time” Block-K
Page 81 and 82:
81 Block-Kurs Luftchemie N 2 O (ca.
Page 83 and 84:
83 Impact of NO and NO 2 , but also
Page 85 and 86:
85 H 2 O troposphere: 0.2 - 4% stra
Page 87 and 88:
Page 89 and 90:
89 Followed by: Cl + O 3 ClO + O 2
Page 91 and 92:
91 Loss reactions for Cl Cl + CH4 H
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Page 95 and 96:
95 Stratospheric ozone budget Block
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97 Block-Kurs Luftchemie F 11: DuPo
Page 99 and 100:
99 British Antartic Survey; 1982 TO
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101 Block-Kurs Luftchemie ‘Om het
Page 103 and 104:
103 Situation Polar night: polar vo
Page 105 and 106:
105 Block-Kurs Luftchemie PSC: Pola
Page 107 and 108:
107 Stratospheric ozone worldwide S
Page 109 and 110:
109 Increase of UV-B leads to Incre
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Page 113 and 114:
Page 115 and 116:
Page 117 and 118:
(WMO, 2007) 117 Block-Kurs Luftchem
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119 Block-Kurs Luftchemie (WMO, 200
Page 121 and 122:
121 Block-Kurs Luftchemie ODP and G
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123 Block-Kurs Luftchemie Ozone in
Page 125 and 126:
125 Koplung Klima-änderung und Str
Page 127 and 128:
127 Tropospheric ozone 90 % of all
Page 129 and 130:
129 Surface-near ozone at Montsouri
Page 131 and 132:
Page 133 and 134:
133 Increase of tropospheric ozone:
Page 135 and 136:
135 Netto: CH 4 + 8 O 2 → CO + 4
Page 137 and 138:
137 RH : Reactive Hydrocarbons VOC
Page 139 and 140:
139 Block-Kurs Luftchemie O 2 ην
Page 141 and 142:
141 Policy for tropospheric O 3 RH
Page 143 and 144:
Page 145 and 146:
145 The formation of the OH-radical
Page 147 and 148:
147 OH-radical 'discovered' by Levy
Page 149 and 150:
149 Trends in the OH-concentration
Page 151 and 152:
151 Dry Deposition Flux = Fs [conc.
Page 153 and 154:
153 Block-Kurs Luftchemie Dry depos
Page 155 and 156:
155 Dg, Dl = Moleculair Diffusion C
Page 157 and 158:
157 Wet Deposition Two processes: I
Page 159 and 160:
159 Loss term CH 4 + OH ~ 400 Tg/ y
Page 161 and 162:
Page 163 and 164:
Page 165 and 166:
Page 167 and 168:
167 I) Eiszeit Methan Vor 38.000/14
Page 169 and 170:
169 Tropospheric O 3-budget A. Infl
Page 171 and 172:
171 ad B. Deposition flux V d depos
Page 173 and 174:
173 Chem. Prod. Chem. Destr. Netto
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175 Emissions Anthropogenic Biogeni
Page 177 and 178:
177 Contained in fuels S → SO 2 H
Page 179 and 180:
179 Emissie benzine-auto’s N 2 78
Page 181 and 182:
181 Natural emissions Sea-salt (NaC
Page 183 and 184:
183 Resolution needed? Emission Tes
Page 185 and 186:
185 A more refined Budget Analysis
Page 187 and 188:
187 Block-Kurs Luftchemie Examples
Page 189 and 190:
189 Increase in surface ozone from
Page 191 and 192:
191 Block-Kurs Luftchemie ECHAM Ber
Page 193 and 194:
193 Block-Kurs Luftchemie Radiative
Page 195 and 196:
195 Block-Kurs Luftchemie MOGUNTIA
Page 197 and 198:
197 3-D Eulerian grid modelling Glo
Page 199 and 200:
199 Model calculations hour-by-hour
Page 201 and 202:
Page 203 and 204:
Page 205 and 206:
Page 207 and 208:
207 Block-Kurs Luftchemie Waldhof:
Page 209 and 210:
209 Acidification / Eutrophication
Page 211 and 212:
211 Policy based on − Average Acc
Page 213 and 214:
Page 215 and 216:
Page 217 and 218:
Page 219 and 220:
219 Data assimilation by combining
Page 221 and 222:
221 Ensemble using different CTM’
Page 223 and 224:
223 Yearly mean diurnal cycle of oz
Page 225 and 226:
225 Block-Kurs Luftchemie DEM with
Page 227 and 228:
Page 229 and 230:
229 Block-Kurs Luftchemie Radiative
Page 231 and 232:
231 Aitken particles : r < 0.1 µm
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Page 235 and 236:
Page 237 and 238:
237 Removal of aerosols by: Coagula
Page 239 and 240:
239 Wet deposition and aqueous phas
Page 241 and 242:
241 Cloud-drops can evaporate Aeros
Page 243 and 244:
Page 245 and 246:
Berlin, 19-23 März 2007 Block-Kurs
Page 247 and 248:
247 Messungen von Aerosolen Zusamme
Page 249 and 250:
249 Satelliet-messungen von Aerosol
Page 251 and 252:
251 Mean Ångström coefficient (a)
Page 253 and 254:
253 Secondary inorganic aerosol NO
Page 255 and 256:
255 Erste Ergebnisse Modellierung v
Page 257 and 258:
257 Average BSOA 28 July - 13 Augus
Page 259 and 260:
259 Average computed (LOTOS) wind b
Page 261 and 262:
261 Soot ( Russ) is the same as Bla
Page 263 and 264:
263 Block-Kurs Luftchemie Figure 2
Page 265 and 266:
265 Block-Kurs Luftchemie Figure 4
Page 267 and 268:
267 Block-Kurs Luftchemie SO 3 Scat
Page 269 and 270:
269 Block-Kurs Luftchemie BC to mea
Page 271 and 272:
Model 271 60 50 40 30 20 10 0 Verif
Page 273 and 274:
Modelled concentration ( µg/m 3 Mo
Page 275 and 276:
275 Die EU-Rahmenrichtlinien und an
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277 Grenzwerte NO 2 40 µg/m 3 Jahr
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Page 281 and 282:
CALCULATED RCG 281 80 70 60 50 40 3
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283 RCG: Zartau: PM10 COMPOSITION 1
Page 285 and 286:
RCG modelling domains. Upper left:
Page 287 and 288:
287 Many problems in understanding
Page 289 and 290:
289 Aerosols are also relevant for
Page 291 and 292:
291 M.Schaap et al. “Anthropogeni
Page 293 and 294:
293 Block-Kurs Luftchemie PM10 MEAN
Page 295 and 296:
295 Block-Kurs Luftchemie Validatie
Page 297 and 298:
297 Diplomthermen TRUMF (2) Verwend
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