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An overview of vis-nir-swir field spectroscopy - Spectral International

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2003, for Shea Creek; and Bruneton, 1993, for Cigar Lake). This alteration<br />

typically envelops the main ore-controlling structures, forming plume-shaped or<br />

flattened elongate bell-shaped halos that taper gradually upward from the base <strong>of</strong><br />

the sandstone (Hoeve and Quirt, 1987) Figure 70. Potassium, magnesium and<br />

aluminum ratios are diagnostic <strong>of</strong> the different clay types.<br />

Hydrothermal, ore-related alteration effects are superimposed on pre-existing<br />

alteration assemblages, including the paleo-weathering alteration recorded by<br />

the red-green pr<strong>of</strong>ile below the basal unconformity, and the initial detrital clay<br />

mineralogy that is locally preserved in silicified zones (Mwenifumbo et al., 2005).<br />

This has led to confusion as to which process generated the red-green transition<br />

at the basement-sandstone unconformity. Ore-related white clay alteration is<br />

superimposed on the red hematitic paleo-weathering alteration (McDonald,<br />

1980). Very dark coarse grained hematite alteration forms a cap over ore<br />

deposits such as Cigar Lake (<strong>An</strong>drade 2002).. This very dense, crystalline,<br />

hydrothermal hematite alteration contrasts with the brick red, fine-grained<br />

hematite that is interpreted as a detrital or very early diagenetic mineral, and is<br />

intimately interlayered with clay minerals to form micro-laminae in oncoidal<br />

hematite beds (Yeo et al., 2005a).<br />

Figure 71 - Simplified mineral paragenesis <strong>of</strong> the Paleo- to Mesoproterozoic Athabasca, Thelon<br />

and Kombolgie basins, after Figure 10.21 <strong>of</strong> Kyser et al. (2000). The ages <strong>of</strong> primary uraninite,<br />

the first deposition <strong>of</strong> U in a given deposit, may be different for different deposits, hence U1<br />

(~1500-1600) and U1' (~1350-1400) might both be primary in the Athabasca Basin. Depositional<br />

ages in the Athabasca Group are Zv: U-Pb on volcanic zircon in Wolverine Point Formation, and<br />

Os-Re: primary organic matter in Douglas Formation.<br />

57

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