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An overview of vis-nir-swir field spectroscopy - Spectral International

An overview of vis-nir-swir field spectroscopy - Spectral International

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concentration, water content and environmental considerations. For mineral<br />

identification, that signature is compared against characterized references for a<br />

validated identification. This can be done manually by using wavelength tables<br />

and overlaying references on the unknown or it can be done using computer<br />

algorithms operating against a database <strong>of</strong> references (i.e., a spectral library).<br />

For best results these libraries must be set up for specific deposit types, and not<br />

allow the algorithm to make a wrong choice.<br />

Figure 2 – Example absorption spectrum. The units for the horizontal scale are in<br />

nanometers or microns while the vertical scale is percent reflectance. The absorption<br />

figure shown is a doublet, with two minima or lowest points <strong>of</strong> the feature. Each<br />

minimum has a distinctive wavelength, which is a function <strong>of</strong> the chemical<br />

composition. “FWHM” means Full Width at Half Maximum. It can be used for<br />

symmetry determinations that are related to crystallinity.<br />

Although the computer algorithms are useful for data management and<br />

organization, care must be taken when using them for phase identification and<br />

quantification. There are many unaddressed variables and non-user chosen<br />

identifications are not always accurate. Additionally, important information on<br />

crystallinity, water, organics, and iron, among other things, is lost.<br />

VISIBLE RANGE SIGNATURES<br />

There is an abundance <strong>of</strong> information to be gained from the <strong>vis</strong>ible region <strong>of</strong> the<br />

EMS. This is one <strong>of</strong> the features that makes the full-range spectrometers so<br />

valuable. Figure 3 shows some <strong>of</strong> the cations that are recognizable by colors<br />

and corresponding minerals. Although the <strong>vis</strong>ible range is constrained from 300-<br />

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