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Substitution of PFOS for use in nondecorative hard chrome plating

Substitution of PFOS for use in nondecorative hard chrome plating

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2.2.1 Denmark<br />

As described above <strong>in</strong> section 2.1 ”Use <strong>of</strong> <strong>PFOS</strong> <strong>in</strong> Denmark”, the<br />

<strong>in</strong><strong>for</strong>mation from the Danish non-decorative <strong>hard</strong> <strong>chrome</strong> <strong>in</strong>dustry together<br />

with <strong>in</strong><strong>for</strong>mation from suppliers <strong>of</strong> mist suppressant chemicals to the Danish<br />

<strong>in</strong>dustry <strong>in</strong>dicates that the total <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> <strong>for</strong> one year is between 10 and<br />

28 kg calculated as pure <strong>PFOS</strong>. The concentration <strong>of</strong> <strong>PFOS</strong> <strong>in</strong> the mist<br />

suppressant chemical <strong>for</strong>mulation is typically 1-15% depend<strong>in</strong>g on the<br />

<strong>for</strong>mulation (supplier).<br />

The low value is the <strong>use</strong> estimated by the <strong>in</strong>dustry and the high value is<br />

amounts sold by suppliers to Danish companies. Both numbers are calculated<br />

by multiply<strong>in</strong>g the estimated/sold amount with the content <strong>of</strong> <strong>PFOS</strong> <strong>in</strong>dicated<br />

by percentage range on the material safety data sheet.<br />

2.2.2 Nordic countries<br />

When <strong>in</strong><strong>for</strong>mation was obta<strong>in</strong>ed from suppliers about the <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> <strong>in</strong><br />

Denmark, the Nordic suppliers were at the same time asked about<br />

<strong>in</strong><strong>for</strong>mation on sold amounts <strong>of</strong> <strong>PFOS</strong> to Nordic countries. The contacted<br />

suppliers reported a total amount <strong>of</strong> 90 kg calculated as pure <strong>PFOS</strong> <strong>for</strong> the<br />

years 2007/2008 or 2009 (depend<strong>in</strong>g on the supplier). In all, three <strong>of</strong> the<br />

contacted suppliers sold <strong>PFOS</strong> mist suppressant chemicals to the Nordic<br />

countries dur<strong>in</strong>g this time period. The total amount (calculated as pure<br />

<strong>PFOS</strong>) was 90 kg. There could be other suppliers <strong>of</strong> <strong>PFOS</strong> <strong>for</strong> <strong>use</strong> as mist<br />

suppressants <strong>for</strong> non-decorative <strong>hard</strong> <strong>chrome</strong> plat<strong>in</strong>g <strong>in</strong> the Nordic countries.<br />

Norway<br />

Norway has reported <strong>in</strong> an action plan <strong>for</strong> PFAS (perfluoroalkyl substances)<br />

and <strong>PFOS</strong>-related substances that the major areas <strong>of</strong> <strong>use</strong> <strong>for</strong> <strong>PFOS</strong>-related<br />

substances <strong>in</strong> Norway are fire-fight<strong>in</strong>g foams and the <strong>chrome</strong>-plat<strong>in</strong>g <strong>in</strong>dustry<br />

(SFT, 2005). No <strong>in</strong><strong>for</strong>mation about the specific <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> is mentioned.<br />

In Carloni (2009), it is reported that Norway has submitted <strong>in</strong><strong>for</strong>mation to the<br />

Stockholm Convention on Persistent Organic Pollutants – POPs Review<br />

Committee (POPRC) that the estimated <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> <strong>in</strong> Norway <strong>for</strong> metal<br />

plat<strong>in</strong>g is 3-5 liters. It seems that is data is from 2005 or 2006.<br />

Accord<strong>in</strong>g to a document by the Stockholm Convention on Persistent<br />

Organic Pollutants (SC UNEP/POPS/POPRC.5/INF/14, 2009), the<br />

Norwegian Galvano Industry Organisation (NGLF) has reported that their<br />

suppliers no longer provide wett<strong>in</strong>g/anti-mist agent <strong>for</strong> chromium plat<strong>in</strong>g.<br />

Instead they provide <strong>PFOS</strong>-free tensides. NGLF considers the per<strong>for</strong>mance<br />

<strong>of</strong> these alternatives to be <strong>in</strong>sufficient and is currently develop<strong>in</strong>g better<br />

alternatives to <strong>PFOS</strong> and alternative technology to solve the problem with<br />

airborne loss <strong>of</strong> hexavalent chromium from the baths. Where possible the<br />

chromium-(VI) process is be<strong>in</strong>g substituted by the chromium-(III) process.<br />

This <strong>in</strong><strong>for</strong>mation seems more recent than the <strong>in</strong><strong>for</strong>mation from Carloni<br />

(2009). It is there<strong>for</strong>e assumed that the <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> <strong>in</strong> Norway is zero.<br />

Sweden<br />

In an action plan from 2004, Sweden has reported that the <strong>use</strong> <strong>of</strong> <strong>PFOS</strong>related<br />

chemicals <strong>for</strong> metal plat<strong>in</strong>g <strong>in</strong> 2002 was 3% <strong>of</strong> the total <strong>use</strong> <strong>of</strong> <strong>PFOS</strong>related<br />

chemicals i.e. 3% <strong>of</strong> 862 kg = 26 kg (KEMI, 2004). This estimate was<br />

27

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