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Substitution of PFOS for use in nondecorative hard chrome plating

Substitution of PFOS for use in nondecorative hard chrome plating

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estimated the <strong>use</strong> <strong>of</strong> <strong>PFOS</strong>-related substances <strong>in</strong> the metal plat<strong>in</strong>g <strong>in</strong>dustry <strong>in</strong><br />

the EU was between 8,600 and 10,000 kg.<br />

Accord<strong>in</strong>g to the European Commission (2010), the follow<strong>in</strong>g countries have<br />

reported that <strong>PFOS</strong> is “not <strong>use</strong>d <strong>in</strong> processes subject under the derogation <strong>in</strong><br />

paragraph 3 (c) <strong>of</strong> Directive 2006/122/EC”, i.e. mist suppressants <strong>for</strong> <strong>nondecorative</strong><br />

<strong>hard</strong> <strong>chrome</strong> plat<strong>in</strong>g (chromium-(VI)) and wett<strong>in</strong>g agents <strong>for</strong> <strong>use</strong><br />

<strong>in</strong> controlled electroplat<strong>in</strong>g systems: Bulgaria, Denmark (however, this is not<br />

true accord<strong>in</strong>g to the discoveries <strong>in</strong> this project), Estonia, Greece, Spa<strong>in</strong>,<br />

Ireland, Italy, Cyprus, Latvia, Lithuania, Luxembourg, Hungary, Malta,<br />

Austria, Poland, Portugal, Romania, and Slovakia.<br />

This means that the total <strong>use</strong> <strong>in</strong> the EU today is estimated to be around 2,684<br />

to 3,194 kg and probably larger, if some <strong>of</strong> the countries above have not<br />

registered a <strong>use</strong> <strong>of</strong> <strong>PFOS</strong>, although <strong>PFOS</strong> still are <strong>use</strong>d (as is the case <strong>of</strong><br />

Denmark). The sum <strong>of</strong> 2,684 to 3,194 kg is found by add<strong>in</strong>g the amounts (or<br />

ranges) reported by Germany, Belgium, Czech Republic, the UK, France,<br />

and the Netherlands together with the amounts <strong>of</strong> <strong>PFOS</strong> sold to Nordic<br />

countries (reported by suppliers <strong>in</strong> this project).<br />

However, it is clear that the <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> has decl<strong>in</strong>ed drastically beca<strong>use</strong> <strong>of</strong><br />

the restriction <strong>of</strong> the <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> <strong>in</strong> 2008. The estimated <strong>use</strong> <strong>of</strong> 10,000 kg<br />

<strong>PFOS</strong> <strong>in</strong> 2003 is there<strong>for</strong>e drastically reduced. However, this amount <strong>of</strong><br />

10,000 kg also covered the entire metal plat<strong>in</strong>g <strong>in</strong>dustry and not only <strong>nondecorative</strong><br />

<strong>hard</strong> <strong>chrome</strong> plat<strong>in</strong>g.<br />

Europe<br />

The amount listed above covers the EU countries. The amount <strong>of</strong> <strong>PFOS</strong> <strong>use</strong>d<br />

<strong>in</strong> Europe is larger. Switzerland (below) is the only non-EU European country<br />

where <strong>in</strong><strong>for</strong>mation <strong>of</strong> the <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> has been found.<br />

2.2.13 Switzerland<br />

Accord<strong>in</strong>g to the OECD (2005) survey, the <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> <strong>for</strong> metal plat<strong>in</strong>g <strong>in</strong><br />

the year 2000 was estimated to be 190 kg.<br />

A substance flow analysis <strong>of</strong> <strong>PFOS</strong> and PFOA <strong>in</strong> Switzerland has been<br />

per<strong>for</strong>med. Accord<strong>in</strong>g to that survey, the <strong>use</strong> <strong>of</strong> <strong>PFOS</strong> <strong>for</strong> metal plat<strong>in</strong>g (mist<br />

suppressant and surfactant) was estimated to be about 300 kg <strong>of</strong> <strong>PFOS</strong><br />

annually (but with<strong>in</strong> the range <strong>of</strong> 200-500 kg annually) <strong>for</strong> the year 2007<br />

(FOEN, 2009).<br />

2.2.14 Canada<br />

Canada per<strong>for</strong>med <strong>in</strong> 2005 a <strong>use</strong> pattern survey <strong>of</strong> <strong>PFOS</strong> (CEPA, 2006).<br />

Companies were required to report if they were <strong>in</strong>volved <strong>in</strong> manufacture,<br />

export, or import <strong>of</strong> <strong>PFOS</strong> <strong>in</strong> amounts exceed<strong>in</strong>g 100 kg <strong>in</strong> concentrations <strong>of</strong><br />

greater than 10 grams per kilogram <strong>for</strong> the 2004 calendar year. The survey<br />

showed that the import <strong>of</strong> <strong>PFOS</strong> related compounds have essentially ceased<br />

s<strong>in</strong>ce 2002 and showed that there are no manufactures or exporters <strong>of</strong> <strong>PFOS</strong><br />

<strong>in</strong> Canada. Only one substance was imported <strong>in</strong>to Canada represent<strong>in</strong>g a<br />

quantity <strong>of</strong> approximately 3 tons <strong>of</strong> <strong>PFOS</strong>. The imported substance was sold<br />

as a product that is <strong>use</strong>d as a surfactant <strong>in</strong> the electroplat<strong>in</strong>g sector. The<br />

survey stated that the potential does exist <strong>for</strong> <strong>PFOS</strong> and <strong>PFOS</strong> conta<strong>in</strong><strong>in</strong>g<br />

products and articles to be imported <strong>in</strong>to Canada <strong>in</strong> greater quantities <strong>in</strong> the<br />

future as some <strong>PFOS</strong> production has been identified <strong>in</strong> other countries.<br />

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